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TPU/PCL/nanomagnetite ternary shape memory composites: studies on their thermal, dynamic-mechanical, rheological and electrical properties

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Abstract

Shape memory polymer composites based on a blend of thermoplastic polyurethane (TPU) segmented block copolymer and poly(ε-caprolactone) (PCL) with weight ratio of 70/30 and various nanomagnetite contents (0–5 wt%) were prepared by melt blending of TPU and PCL, together with a masterbatch of TPU/nanomagnetite. The samples were compounded for 10 min at 200 °C using an internal mixer. Synthesized nanomagnetite powder was introduced to the masterbatch via a solution mixing method using a high-intensity ultrasonic horn. Subsequently, thermal, mechanical, rheological and electrical properties of the TPU/PCL/nanomagnetite shape memory composites were investigated through various tests. The degree of crystallization of the PCL component in the composite structure was inspected by differential scanning calorimetry (DSC) and X-ray diffraction measurements. The results revealed that the percentage of crystallinity and the melting temperature of the PCL component changed in the presence of magnetite nanoparticles, which was related to the nanoparticles acting as nucleants. Observing a single glass transition temperature (T g) in DSC thermograms of the samples was indicative of good compatibility of the TPU and PCL components in the composite structure. This was also confirmed by dynamic-mechanical analysis in which the loss modulus curves showed a single glass transition temperature. Moreover, the loss modulus peak at glass transition was lowered and broadened by addition of nanomagnetite, by which it was assumed that introducing nanoparticles into the system changed the mechanism of glass transition due to particle–matrix interactions. The dynamic rheological and electrical resistivity experiments verified the existence of a low percolation threshold at about 2 wt% nanomagnetite. The state of nanomagnetite dispersion in the masterbatch and the microstructure of the ternary composites were characterized by scanning electron microscopy. Finally, adding nanomagnetite led to weakening of shape recovery of the polymer blend, with shape recovery dropping to 70 % at 5 % of nanomagnetite.

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Abbreviations

TPU:

Thermoplastic polyurethane

PCL:

Poly(ε-caprolactone)

DSC:

Dynamic scanning calorimetry

XRD:

X-ray diffraction

DMA:

Dynamic mechanical analysis

SEM:

Scanning electron microscopy

SMP:

Shape memory polymer

THF:

Tetrahydrofuran

T g :

Glass transition temperature

T m :

Melting point

T trans :

Transition temperature

M n :

Number average molecular weight

ΔH f :

Heat of fusion

ΔH 100 :

Heat of fusion of 100 % crystalline material

E′:

Storage modulus

E″:

Loss modulus

WAXS:

Wide angle X-ray scattering

G′:

Storage shear modulus

χ c :

Degree of crystallinity

ω PCL :

Poly(ε-caprolactone) weight fraction

ω :

Frequency

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Acknowledgments

We wish to express our gratitude to the Iran National Science Foundation (INSF) for financial support of this work (Grant # 85076/27). Also the kind assistance of Tarbiat Modares University and Iran Polymer and Petrochemical Institute (IPPI) is greatly acknowledged. We acknowledge the contribution of Mrs. Mahnaz Shahzamani to the DMTA results of the polymer blend. Special thanks to Dr. Aart Willem Van Vuure for his help in editing this paper.

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Authors and Affiliations

  1. Department of Chemical Engineering, Tarbiat Modares University, P.O. Box 14115-114, Tehran, Iran

    Yasmine Mosleh & Nadereh Golshan Ebrahimi

  2. Polymer Science Department, Iran Polymer and Petrochemical Institute, P.O. Box 14965/115, Tehran, Iran

    Alireza Mahdavian & Mohsen Ashjari

Authors
  1. Yasmine Mosleh
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  2. Nadereh Golshan Ebrahimi
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  3. Alireza Mahdavian
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  4. Mohsen Ashjari
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Correspondence to Nadereh Golshan Ebrahimi.

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Mosleh, Y., Ebrahimi, N.G., Mahdavian, A. et al. TPU/PCL/nanomagnetite ternary shape memory composites: studies on their thermal, dynamic-mechanical, rheological and electrical properties. Iran Polym J 23, 137–145 (2014). https://doi.org/10.1007/s13726-013-0209-4

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  • DOI: https://doi.org/10.1007/s13726-013-0209-4

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