Abstract
Interests in the use of natural fibers–fillers in composite materials are growing rapidly due to the low cost and high availability. However, poor surface adhesion and mineralization are the main drawbacks that restrict the use of natural fibers in different applications. Thus, it is essential to perform a treatment that can improve the surface properties of natural fibers before being used in the composites. Such treatments are physical (corona, plasma, etc.), chemical (alkaline, silane, acetylation, etc.), and biological (enzyme), but the benefits of each treatment considering energy consumption and effluent generation should be considered more in-depth. Via a literature review, this study investigated the mechanical performance, energy consumption, and generated effluents of chemical treatments (silane, alkaline, acetylation, and maleated coupling) as the consequence of fiber treatment to propose a more sustainable treatment at the scope of the treatment section in the factory of natural fibers–polymer composites (gate to gate). It was shown during this review study that the maleated coupling is a more sustainable method since it needs no specific energy during the treatment while produces no effluent and improves the mechanical strength performance of the composites more constantly.
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Adams RH, Cerecedo-López RA, Alejandro-Álvarez LA, Domínguez-Rodríguez VI, Nieber JL (2016) Treatment of water-repellent petroleum-contaminated soil from Bemidji, Minnesota, by alkaline desorption. Int J Environ Sci Technol 13:2249–2260
Ali A, Shaker K, Nawab Y, Jabbar M, Hussain T, Militky J, Baheti V (2018) Hydrophobic treatment of natural fibers and their composites—a review. J Ind Text 47:2153–2183
Al-Maadeed MA, Labidi S (2014) 4—Recycled polymers in natural fibre-reinforced polymer composites. In: Hodzic A, Shanks RA (eds) Natural fibre composites. Woodhead Publishing, pp 103–114
Anand P, Anbumalar V (2017) Investigation on thermal behavior of alkali and benzoyl treated hemp fiber reinforced cellulose filled epoxy hybrid green composites. Cellul Chem Technol 51:91–101
Arsène MA, Okwo A, Bilba K, Soboyejo ABO, Soboyejo WO (2007) Chemically and thermally treated vegetable fibers for reinforcement of cement-based composites. Mater Manuf Process 22:214–227
Atadana FW (2010) Catalytic pyrolysis of cellulose, hemicellulose and lignin model compounds. In: M.Sc. Thesis, Virginia Polytechnic Institute and State University, Blacksburg, Virginia
Bachtiar D, Sapuan SM, Hamdan MM (2008) The effect of alkaline treatment on tensile properties of sugar palm fibre reinforced epoxy composites. Mater Des 29:1285–1290
Bhattacharya A, Misra B (2004) Grafting: a versatile means to modify polymers: techniques, factors and applications. Prog Polym Sci 29:767–814
Biagiotti J, Puglia D, Kenny JM (2004) A review on natural fibre-based composites—part I: structure, processing and properties of vegetable fibres. J Nat Fibers 1:37–68
Bilba K, Arsene MA (2008) Silane treatment of bagasse fiber for reinforcement of cementitious composites. Compos A Appl Sci Manuf 39:1488–1495
Bisanda ETN (2000) The effect of alkali treatment on the adhesion characteristics of sisal fibres. Appl Compos Mater 7:331–339
Blankenhorn PR, Blankenhorn BD, Silsbee MR, DiCola M (2001) Effects of fiber surface treatments on mechanical properties of wood fiber–cement composites. Cem Concr Res 31:1049–1055
Bledzki AK, Gassan J (1999) Composites reinforced with cellulose based fibres. Prog Polym Sci 24:221–274
Bledzki AK, Mamun AA, Lucka-Gabor M, Gutowski VS (2008) The effects of acetylation on properties of flax fibre and its polypropylene composites. eXPRESS Polym Lett 2:413–422
Bledzki AK, Mamun AA, Jaszkiewicz A, Erdmann K (2010) Polypropylene composites with enzyme modified abaca fibre. Compos Sci Technol 70:854–860
Boland C (2014) Life cycle energy and greenhouse gas emissions of natural fiber composites for automotive applications: impacts of renewable material content and lightweighting. In: M.Sc. Thesis, University of Michigan, Ann Arbor, Michigan
Brígida AIS, Calado VMA, Gonçalves LRB, Coelho MAZ (2010) Effect of chemical treatments on properties of green coconut fiber. Carbohydr Polym 79:832–838
Buschle-Diller G, Fanter C, Loth F (1999) Structural changes in hemp fibers as a result of enzymatic hydrolysis with mixed enzyme systems. Text Res J 69:244–251
Cavaco-Paulo A, Gübitz GM (2003) Textile processing with enzymes. Woodhead Publishing Ltd, Cambridge
Chand N, Fahim M (2008) Tribology of natural fiber polymer composites. Woodhead Publishing Series in Composites Science and Engineering. Elsevier, Amsterdam
Chandramohan D, Marimuthu K (2011) A review on natural fibers. Int J Res Rev Appl Sci 8:194–206
Choy SY, Prasad KMN, Wu TY, Ramanan RN (2015) A review on common vegetables and legumes as promising plant-based natural coagulants in water clarification. Int J Environ Sci Technol 12:367–390
Chung DDL (2010) Composite material structure and processing. In: Composite materials: science and applications, 2nd edn. Springer, London, pp 1–34. ISBN 978-1-84882-830-8
Cichocki FR Jr, Thomason JL (2002) Thermoelastic anisotropy of a natural fiber. Compos Sci Technol 62:669–678
Clark JH, Macquarrie DJ (2008) Handbook of green chemistry and technology. Wiley, Hoboken
Clauß B (2008) Fibers for ceramic matrix composites. In: Krenkel W (ed) Ceramic matrix composites: fiber reinforced ceramics and their applications. Wiley, pp 1–20, ISBN: 978-3-527-62240-5
Cristaldi G, Latteri A, Recca G, Cicala G (2010) Composites based on natural fibre fabrics (Chap. 17). In: Dubrovski PD (eds) Woven Fabric Engineering, Sciyo, Rijeka, Croatia, November 2010, pp 317–342. ISBN 978-953-307-194-7
Dam JEGV (1999) Optimisation of methods of fibre preparation from agricultural raw materials. Department of Fibres and Cellulose, Agrotechnological Research Institute, Wageningen
de Camargo JSG, de Menezes AJ, da Cruz NC, Rangel EC, Delgado-Silva AO (2018) Morphological and chemical effects of plasma treatment with oxygen (O2) and sulfur hexafluoride (SF6) on cellulose surface. Mater Res 20:842–850
de Santos PA, Giriolli JC, Amarasekera J, Moraes G (2008) Natural fibers plastic composites for automotive applications. In: The 8th annual Society of Plastics Engineers’ (SPE) Automotive Composites Conference and Exhibition (ACCE), Sept. 16–18, Michigan State University, Troy, Michigan, pp 12–21
Fangueiro R (2011) Fibrous and composite materials for civil engineering applications. Elsevier, Amsterdam
Faruk O, Bledzki AK, Fink H-P, Sain M (2012) Biocomposites reinforced with natural fibers: 2000–2010. Prog Polym Sci 37:1552–1596
Frybort S, Mauritz R, Teischinger A, Müller U (2008) Cement bonded composites—a mechanical review. BioResources 3:602–626
Gassan J, Bledzki AK (1999) Possibilities for improving the mechanical properties of jute/epoxy composites by alkali treatment of fibres. Compos Sci Technol 59:1303–1309
Gassan J, Gutowski VS (2000) Effects of corona discharge and UV treatment on the properties of jute-fibre epoxy composites. Compos Sci Technol 60:2857–2863
George M, Mussone PG, Bressler DC (2014) Surface and thermal characterization of natural fibres treated with enzymes. Ind Crops Prod 53:365–373
Ghavami K (1995) Ultimate load behaviour of bamboo-reinforced lightweight concrete beams. Cement Concr Compos 17:281–288
Goda K, Sreekala MS, Gomes A, Kaji T, Ohgi J (2006) Improvement of plant based natural fibers for toughening green composites—effect of load application during mercerization of ramie fibers. Compos A Appl Sci Manuf 37:2213–2220
Gurunathan T, Mohanty S, Nayak SK (2015) A review of the recent developments in biocomposites based on natural fibres and their application perspectives. Compos A Appl Sci Manuf 77:1–25
Han G, Lei Y, Wu Q, Kojima Y, Suzuki S (2008) Bamboo–fiber filled high density polyethylene composites: effect of coupling treatment and nanoclay. J Polym Environ 16:123–130
Herrera-Franco PJ, Valadez-Gonzalez A (2004) Mechanical properties of continuous natural fibre-reinforced polymer composites. Compos A Appl Sci Manuf 35:339–345
Hill CAS (2007) Wood modification: chemical, thermal and other processes. Wiley Series in Renewable Resource. Wiley, Hoboken
Homan WJ, Jorissen AJM (2004) Wood modification developments. Heron 49:360–369
Huda MS, Drzal LT, Mohanty AK, Misra M (2008) Effect of chemical modifications of the pineapple leaf fiber surfaces on the interfacial and mechanical properties of laminated biocomposites. Compos Interfaces 15:169–191
John MJ, Anandjiwala RD (2008) Recent developments in chemical modification and characterization of natural fiber-reinforced composites. Polym Compos 29:187–207
John MJ, Thomas S (2008) Biofibres and biocomposites. Carbohydr Polym 71:343–364
Joseph K, Thomas S, Pavithran C (1996) Effect of chemical treatment on the tensile properties of short sisal fibre-reinforced polyethylene composites. Polymer 37:5139–5149
Joseph S, Koshy P, Thomas S (2005) The role of interfacial interactions on the mechanical properties of banana fibre reinforced phenol formaldehyde composites. Compos Interfaces 12:581–600
Joseph S, Oommen Z, Thomas S (2006) Environmental durability of banana-fiber-reinforced phenol formaldehyde composites. J Appl Polym Sci 100:2521–2531
Joshi SV, Drzal LT, Mohanty AK, Arora S (2004) Are natural fiber composites environmentally superior to glass fiber reinforced composites? Compos A Appl Sci Manuf 35:371–376
Kabir MM, Wang H, Lau KT, Cardona F (2012) Chemical treatments on plant-based natural fibre reinforced polymer composites: an overview. Compos B Eng 43:2883–2892
Kabir MM, Wang H, Lau KT, Cardona F (2013) Tensile properties of chemically treated hemp fibres as reinforcement for composites. Compos B Eng 53:362–368
Keener TJ, Stuart RK, Brown TK (2004) Maleated coupling agents for natural fibre composites. Compos A Appl Sci Manuf 35:357–362
Keijzer MR, van Bommel I, Joosten A, Hartl AN, Proaño Gaibor AG, Heiss R, Kralofsky R, Erlach S (2013) The colours and dyeing techniques of prehistoric textiles from the salt mines of Hallstatt. In: Grömer K, Kern A, Reschreiter H, Rösel-Mautendorfer H (eds) Budapest, Hungaria, pp 135–162
Kim JT, Netravali AN (2010) Mercerization of sisal fibers: effect of tension on mechanical properties of sisal fiber and fiber-reinforced composites. Compos A Appl Sci Manuf 41:1245–1252
Konczewicz W, Kozłowski RM (2012) Enzymatic treatment of natural fibres. In: Kozłowski R (ed) Handbook of natural fibres, 1st edn. Woodhead Publishing, pp 168–184. https://doi.org/10.1533/9780857095510.1.168
Koohestani B (2017) Effect of saline admixtures on mechanical and microstructural properties of cementitious matrices containing tailings. Constr Build Mater 156:1019–1027
Koohestani B, Belem T, Koubaa A, Bussière B (2013) Investigation of natural fibres reinforced cemented paste backfill (NFR-CPB). In: Proceedings of the 66th canadian geotechnical conference and the 11th Joint CGS/IAH-CNC groundwater conference, Montreal, Quebec, Canada, September 29 to Thursday October 3, pp 1–8
Koohestani B, Koubaa A, Belem T, Bussière B, Bouzahzah H (2016) Experimental investigation of mechanical and microstructural properties of cemented paste backfill containing maple-wood filler. Constr Build Mater 121:222–228
Koohestani B, Bussière B, Belem T, Koubaa A (2017a) Influence of polymer powder on properties of cemented paste backfill. Int J Miner Process 167:1–8
Koohestani B, Ganetri I, Yilmaz E (2017b) Effects of silane modified minerals on mechanical, microstructural, thermal, and rheological properties of wood plastic composites. Compos B Eng 111:103–111
Koohestani B, Darban AK, Darezereshki E, Mokhtari P, Yilmaz E, Yilmaz E (2018a) The influence of sodium and sulfate ions on total solidification and encapsulation potential of iron-rich acid mine drainage in silica gel. J Environ Chem Eng 6:3520–3527
Koohestani B, Khodadadi Darban A, Mokhtari P (2018b) A comparison between the influence of superplasticizer and organosilanes on different properties of cemented paste backfill. Constr Build Mater 173:180–188
Koohestani B, Khodadadi Darban A, Yilmaz E, Mokhtari P, Ganetri I (2018c) Influence of amine and vinyl functional groups of silanes on total performance of thermoplastic-based composites. Constr Build Mater 172:98–105
Li X, Tabil LG, Panigrahi S (2007) Chemical treatments of natural fiber for use in natural fiber-reinforced composites: a review. J Polym Environ 15:25–33
Lopsik K (2013) Life cycle assessment of small-scale constructed wetland and extended aeration activated sludge wastewater treatment system. Int J Environ Sci Technol 10:1295–1308
Lu JZ, Wu Q, Negulescu II (2005) Wood-fiber/high-density-polyethylene composites: coupling agent performance. Appl Polym Sci 96:93–102
Lu T et al (2014) Effects of modifications of bamboo cellulose fibers on the improved mechanical properties of cellulose reinforced poly (lactic acid) composites. Compos B Eng 62:191–197
Luz SM, Del Tio J, Rocha GJM, Gonçalves AR, Del’Arco AP (2008) Cellulose and cellulignin from sugarcane bagasse reinforced polypropylene composites: effect of acetylation on mechanical and thermal properties. Compos A Appl Sci Manuf 39:1362–1369
Malkapuram R, Kumar V, Negi YS (2009) Recent development in natural fiber reinforced polypropylene composites. J Reinf Plast Compos 28:1169–1189
Mallick PK (2007) Fiber-reinforced composites: materials, manufacturing, and design, 3rd edn (Mechanical Engineering). CRC Press, Boca Raton
Marais S, Gouanvé F, Bonnesoeur A, Grenet J, Poncin-Epaillard F, Morvan C, Métayer M (2005) Unsaturated polyester composites reinforced with flax fibers: effect of cold plasma and autoclave treatments on mechanical and permeation properties. Compos A Appl Sci Manuf 36:975–986
Martin AR, Manolache S, Mattoso LHC, Rowell RM, Denes F (2000) Plasma modification of sisal on high density polyethylene composites: effect on mechanical properties. In: Proceedings of the 3rd international symposium on natural polymers and composites, May 14–17, Sao Pedro, SP, Brazil, pp 431–436
Mohammed L, Ansari MN, Pua G, Jawaid M, Islam MS (2015) A review on natural fiber reinforced polymer composite and its applications. Int J Polym Sci 2015:243947. https://doi.org/10.1155/2015/243947
Mohanty S, Nayak S, Verma S, Tripathy S (2004) Effect of MAPP as a coupling agent on the performance of jute–PP composites. Reinf Plast Compos 23:625–637
Mohr BJ, Biernacki JJ, Kurtis KE (2007) Supplementary cementitious materials for mitigating degradation of kraft pulp fiber–cement composites. Cem Concr Res 37:1531–1543
Motta LAC, John VM, Agopyan V (2010) Thermo-mechanical treatment to improve properties of sisal fibres for composites. Mater Sci Forum 636–637:253–259. https://doi.org/10.4028/www.scientific.net/MSF.636-637.253
Müller K et al (2017) Review on the processing and properties of polymer nanocomposites and nanocoatings and their applications in the packaging, automotive and solar energy fields. Nanomaterials 7:74
Mutje P, Vallejos ME, Girones J, Vilaseca F, Lopez A, Lopez JP, Mendez JA (2006) Effect of maleated polypropylene as coupling agent for polypropylene composites reinforced with hemp strands. Appl Polym Sci 102:833–840
Nam TH, Ogihara S, Tung NH, Kobayashi S (2011) Effect of alkali treatment on interfacial and mechanical properties of coir fiber reinforced poly (butylene succinate) biodegradable composites. Compos B Eng 42:1648–1656
Nishino T, Hirao K, Kotera M (2006) X-ray diffraction studies on stress transfer of kenaf reinforced poly (l-lactic acid) composite. Compos A Appl Sci Manuf 37:2269–2273
Nouri J, Nouri N, Moeeni M (2012) Development of industrial waste disposal scenarios using life-cycle assessment approach. Int J Environ Sci Technol 9:417–424
Pehanich JL, Blankenhorn PR, Silsbee MR (2004) Wood fiber surface treatment level effects on selected mechanical properties of wood fiber–cement composites. Cem Concr Res 34:59–65
Pickering K (2008) Properties and performance of natural-fibre composites. Elsevier, Amsterdam
Pickering KL, Efendy MGA, Le TM (2016) A review of recent developments in natural fibre composites and their mechanical performance. Compos A Appl Sci Manuf 83:98–112
Ragoubi M, Bienaimé D, Molina S, George B, Merlin A (2010) Impact of corona treated hemp fibres onto mechanical properties of polypropylene composites made thereof. Ind Crops Prod 31:344–349
Ragoubi M, George B, Molina S, Bienaimé D, Merlin A, Hiver JM, Dahoun A (2012) Effect of corona discharge treatment on mechanical and thermal properties of composites based on miscanthus fibres and polylactic acid or polypropylene matrix. Compos A Appl Sci Manuf 43:675–685
Ray D, Sarkar BK, Rana AK, Bose NR (2001) The mechanical properties of vinylester resin matrix composites reinforced with alkali-treated jute fibres. Compos A Appl Sci Manuf 32:119–127
Rout J, Misra M, Tripathy SS, Nayak SK, Mohanty AK (2001) The influence of fibre treatment on the performance of coir-polyester composites. Compos Sci Technol 61:1303–1310
Saba N, Tahir PM, Jawaid M (2014) A review on potentiality of nano filler/natural fiber filled polymer hybrid composites. Polymers 6:2247–2273
Seki Y, Sever K, Sarikanat M, Gulec HA, Tavman IH (2009) The influence of oxygen plasma treatment of jute fibres on mechanical properties of jute fibre reinforced thermoplastic composites. Paper presented at the 5th international advanced technologies symposium Turkey
Shishoo R (2007) Plasma technologies for textiles. Elsevier, Amsterdam
Sobral HS (2004) Vegetable plants and their fibres as building materials. In: Proceedings of the second international RILEM symposium. Routledge
Sreekala M, Kumaran M, Joseph S, Jacob M, Thomas S (2000) Oil palm fibre reinforced phenol formaldehyde composites: influence of fibre surface modifications on the mechanical performance. Appl Compos Mater 7:295–329
Švegl F, Šuput-Strupi J, Škrlep L, Kalcher K (2008) The influence of aminosilanes on macroscopic properties of cement paste. Cem Concr Res 38:945–954
Toledo Filho RD, Ghavami K, England GL, Scrivener K (2003) Development of vegetable fibre–mortar composites of improved durability. Cement Concr Compos 25:185–196
Valadez-Gonzalez A, Cervantes-Uc JM, Olayo R, Herrera-Franco PJ (1999a) Chemical modification of henequen fibers with an organosilane coupling agent. Compos B Eng 30:321–331
Valadez-Gonzalez A, Cervantes-Uc JM, Olayo R, Herrera-Franco PJ (1999b) Effect of fiber surface treatment on the fiber–matrix bond strength of natural fiber reinforced composites. Compos B Eng 30:309–320
Van de Weyenberg I, Truong TC, Vangrimde B, Verpoest I (2006) Improving the properties of UD flax fibre reinforced composites by applying an alkaline fibre treatment. Compos A Appl Sci Manuf 37:1368–1376
van Vuure A (2008) Natural fibre composites; recent developments. Katholieke Universiteit Leuven, Leuven
Verma D, Jain S, Zhang X, Gope PC (2016) Green approaches to biocomposite materials science and engineering. IGI Global, Hershey
Vuure V et al (2013) Natural fibre composites: recent developments. In: 5th Eucass-European conference for aerospace sciences, Munich, Germany
Williams T, Hosur M, Theodore M, Netravali A, Rangari V, Jeelani S (2011) Time effects on morphology and bonding ability in mercerized natural fibers for composite reinforcement. Int J Polym Sci. https://doi.org/10.1155/2011/192865
Xiaowen Y, Jayaraman K, Bhattacharyya D (2004) Mechanical properties of plasma-treated sisal fibre-reinforced polypropylene composites. J Adhes Sci Technol 18:1027–1045
Xie Y, Hill CAS, Xiao Z, Militz H, Mai C (2010) Silane coupling agents used for natural fiber/polymer composites: a review. Compos A Appl Sci Manuf 41:806–819
Xu X, Jayaraman K, Morin C, Pecqueux N (2008) Life cycle assessment of wood-fibre-reinforced polypropylene composites. J Mater Process Technol 198:168–177
Xu A, Wang J, Wang H (2010) Effects of anionic structure and lithium salts addition on the dissolution of cellulose in 1-butyl-3-methylimidazolium-based ionic liquid solvent systems. Green Chem 12:268–275
Xue Y, Veazie DR, Glinsey C, Horstemeyer MF, Rowell RM (2007) Environmental effects on the mechanical and thermomechanical properties of aspen fiber–polypropylene composites. Compos B Eng 38:152–158
Yi X-S, Du S, Zhang L (2017) Composite materials engineering, Volume 1: Fundamentals of composite materials. Springer, Berlin
Yu S, Yang S, Cho M (2009) Multi-scale modeling of cross-linked epoxy nanocomposites. Polymer 50:945–952
Yuan X, Jayaraman K, Bhattacharyya D (2004) Effects of plasma treatment in enhancing the performance of woodfibre-polypropylene composites. Compos A Appl Sci Manuf 35:1363–1374
Zafeiropoulos NE (2011) Interface engineering of natural fibre composites for maximum performance. Woodhead Publishing, Philadelphia
Zafeiropoulos NE, Baillie CA, Hodgkinson JM (2002a) Engineering and characterisation of the interface in flax fibre/polypropylene composite materials. Part II. The effect of surface treatments on the interface. Compos A Appl Sci Manuf 33:1185–1190
Zafeiropoulos NE, Williams DR, Baillie CA, Matthews FL (2002b) Engineering and characterisation of the interface in flax fibre/polypropylene composite materials. Part I. Development and investigation of surface treatments. Compos A Appl Sci Manuf 33:1083–1093
Zaman AU (2013) Identification of waste management development drivers and potential emerging waste treatment technologies. Int J Environ Sci Technol 10:455–464
Zhou Y, Fan M, Chen L (2016) Interface and bonding mechanisms of plant fibre composites: an overview. Compos B Eng 101:31–45
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The authors of this work want to appreciate the UQAT professional and technical staffs for their helpful support and assistance. This study was accomplished by Elite Iranian Organization Research Grant (No. 316/5603).
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Koohestani, B., Darban, A.K., Mokhtari, P. et al. Comparison of different natural fiber treatments: a literature review. Int. J. Environ. Sci. Technol. 16, 629–642 (2019). https://doi.org/10.1007/s13762-018-1890-9
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DOI: https://doi.org/10.1007/s13762-018-1890-9