Abstract
In this paper, surface modification of a natural zeolite by dielectric barrier discharge (DBD) plasma has been studied. The natural zeolite was modified by DBD plasma to enhance its adsorption capacity to strontium ions. Various conditions including the treatment time, the voltage and the effective length of plasma were optimized to achieve the best adsorption capacity of Sr2+ ions from water solution. The optimized modification parameters were obtained as; the plasma region length equal to 8 cm; a 9 kV voltage difference and the plasma treatment time of 20 min. After the plasma modification, the adsorption capacity of Sr2+ ions toward the natural zeolite increased more than 56%. The surface properties of the zeolite, before and after plasma treatment, were investigated using FT-IR, TGA, XRD and BET adsorption methods. A 35% increasing in the microporosity and several new functional groups were observed for the plasma-treated zeolite. Langmuir, Freundlich, Temkin and Sips isotherm models were applied to analyze the experimental data and Langmuir linear method showed the best fit for the strontium ions (R2 = 0.997%).
Similar content being viewed by others
References
Abd El-Rahman RO, Ibrahium HA, Yung-Tse H (2011) Liquid radioactive wastes treatment: a review. Water 3:551–565
Ahmadpour A, Zabihi M, Tahmasbi M, Rohani Bastami T (2010) Effect of adsorbents and chemical treatments on the removal of strontium from aqueous solutions. J Hazard Mater 182:552–556
Ali I, Alothman ZA, Alharbi OML (2017a) Uptake of propranolol on ionic liquid iron nano composite adsorbent: kinetic, thermodynamics and mechanism of adsorption. J Mol Liq 236:205–213
Ali I, Alothman ZA, Alharbi OML (2017b) Supra molecular mechanism of the removal of 17-β-estradiol endocrine disturbing pollutant from water on functionalized iron nano particles. J Mol Liq 441:123–129
Alvarez S, García A, Manolache S, Denes F, Riera FA, Álvarez R (2005) Plasma enhanced modification of the pore size of ceramic membranes. Desalination 184:99–104
Bahari M, Haghighat F, Rohani S, Kazemian H (2016) Impact of design parameters on the performance of non-thermal plasma air purification system. Chem Eng J 302:204–212
Basheer AA (2018) New generation nano-adsorbents for the removal of emerging contaminants in water. J Mol Liq 261:583–593
Behnamfard A, Salarirad MM (2009) Equilibrium and kinetic studies on free cyanide adsorption from aqueous solution by activated carbon. J Hazard Mater 170:127–133
Benkli YE, Can MF, Turan M, Celik MS (2005) Modification of organo-zeolite surface for the removal of reactive azo dyes in fixed-bed reactors. Water Res 39:487–493
Boudou JP, Paredes JI, Cuesta A, Martı´nez-Alonso A, Tasco´n JMD (2003) Oxygen plasma modification of pitch-based isotropic carbon fibres. Carbon 41:41–56
Chegrouche S, Mellah A, Barkat M (2009) Removal of strontium from aqueous solutions by adsorption onto activated carbon: kinetic and thermodynamic studies. Desalination 235:306–318
Cheng Z, Gao Z, Ma W, Sun Q, Wang B, Wang X (2012) Preparation of magnetic Fe3O4 particles modified sawdust as the adsorbent to remove strontium ions. Chem Eng J 209:451–457
Denton MS, Manos MJ, Kanatzidis MG (2009) Highly selective removal of cesium and strontium utilizing a new class of inorganic ion specific media. In. WM2009 Conference, vol 29, pp 1–8
El-Kamash AM (2008) Evaluation of zeolite A for the sorptive removal of Cs+ and Sr2+ ions from aqueous solutions using batch and fixed bed column operations. J Hazard Mater 151:432–445
Ghaemi A, Torab-Mostaedi M, Ghannadi-Maragheh M (2011) Characterizations of strontium(II) and barium(II) adsorption from aqueous solutions using dolomite powder. J Hazard Mater 190:12–21
Hernandez-Beltran NA, Olguin, Rosas-Aburto A (2008) Effect of acid phosphate media on the stability of clinoptilolite-rich tuff. J Incl Phenom Macrocycl Chem 61:93–100
Ho YS, Porter JF, McKay G (2002) Equilibrium isotherm studies for the sorption of divalent metal ions onto peat: copper, nickel and lead single component systems. Water Air Soil Pollut 141:1–33
Jung CK, Bae IS, Song YH, Boo JH (2005) Plasma surface modification of TiO2 photocatalysts for improvement of catalytic efficiency. Surf Coat Tech 200:1320–1324
Khan SA (2003) Sorption of the long-lived radionuclides cesium-134, strontium-85 and cobalt-60 on bentonite. J Radioanal Nucl Chem 258:3–6
Korkuna O, Leboda R, Skubiszewska-Zie_ba J, Vrublevs_ka T, Gun_ko VM, Ryczkowski J (2006) Structural and physicochemical properties of natural zeolites: clinoptilolite and mordenite. Microporous Mesoporous Mater 87:243–254
Kosinov N, Gascon J, Kapteijn N, Hensen EJM (2016) Recent developments in zeolite membranes for gas separation. J Membr Sci 499:65–79
Leroux F, Campagne C, Perwuelz A, Gengembre L (2008) Polypropylene film chemical and physical modifications by dielectric barrier discharge plasma treatment at atmospheric pressure. J Colloid Interface Sci 328:412–420
Li Y, Liu F, Xia B, Du Q, Zhang P, Wang D, Wang Z, Xia Y (2010) Removal of copper from aqueous solution by carbon nanotube/calcium alginate composites. J Hazard Mater 177:876–880
Misaelides P (2010) Separation of cesium 137, strontium 90 and actinides from waters and wastewaters: a short reviex of the materials and processes. In: Vaclavikova M, Vitale K, Gallios GP, Ivanicova L (eds) Water treatment technologies for the removal of high-toxicity pollutants. Springer, Dordrecht, pp 183–191
Mohamad ER, Louwanda L, Valentin V, Svetlana M, Frederic TS (2012) Cold plasma as environmentally benign approach for activation of zeolite nanocrystals. Microporous Mesoporous Mater 158:148–154
Naseh MV, Khodadadi AA, Mortazavi Y, Pourfayaz F, Alizadeh O, Maghrebi M (2010) Fast and clean functionalization of carbon nanotubes by dielectric barrier discharge plasma in air compared to acid treatment. Carbon 48:1369–1379
Noroozifar M, Khorasani-Motlagh M, Gorgij MN, Naderpour HR (2008) Adsorption behavior of Cr(VI) on modified natural zeolite by a new bolaform N, N, N, N_, N_, N_-hexamethyl-1,9-nonanediammonium dibromide reagent. J Hazard Mater 155:566–571
Park Y, Lee YC, Shin WS, Choi SJ (2010) Removal of cobalt, strontium and cesium from radioactive laundry wastewater by ammonium molybdophosphate–polyacrylonitrile (AMP–PAN). Chem Eng J 162:685–695
Pourfayaz F (2011) Functionalized carbon nanotubes for polymer nano composites. Chem Eng Dept Tehran Univ, Tehra
Rikhtegar N, Ahmadpanah H, Mansouri N (2013) Chemical modification and characterization of clinoptilolite by 1,3-Phenylenediamine as a sorbent for the removal of NO2. Innov Eng Manag (IJAIEM) 11:2319–4847
Saka C, Sahin Ö, Adsoy H, Akyel SM (2012) Removal of methylene blue from aqueous solutions by using cold plasma, microwave radiation and formaldehyde treated acorn shells. Sep Sci Technol 47:1542–1551
Silva MAM, Martinelli AE, Alves C, Nascimento RM, Távora MP, Vilar CD (2006) Surface modification of Ti implants by plasma oxidation in hollow cathode discharge. Surf Coat Technol 200:2618–2626
Smičiklas I, Dimović S, Plećaš I (2007) Removal of Cs1+, Sr2+ and Co2+ from aqueous solutions by adsorption on natural clinoptilolite. J Clay Sci 35:139–144
Tel H, Altas Y, Eral M, Sert S, Cetinkaya B, Inan S (2010) Preparation of ZrO2 and ZrO2–TiO2 microspheres by the sol–gel method and an experimental design approach to their strontium adsorption behaviours. Chem Eng J 161:151–160
Todd TA, Batcheller TA, Law JD, Herbst RS (2004) Cesium and strontium separation technologies literature review. INEEL/EXT-04-01895
Valsala TP, Joseph A, Sonar NL, Sonavane MS, Shah JG, Raj K, Venugopal V (2010) Separation of strontium from low level radioactive waste solutions using hydrous manganese dioxide composite materials. J Nucl Mater 404:138–143
Xie A, Dai J, Chen X, Ma P, He J, Li C, Zhou Z, Yan Y (2016) Ultrahigh adsorption of typical antibiotics onto novel hierarchical porous carbons derived from renewable lignin via halloysite nanotubes-template and in situ activation. Chem Eng J 304:609–620
Yaneva Z, Georgieva N, Pavlov A (2016) low-temperature plasma-modified zeolite vs. natural bulgarian zeolite–comparative physicochemical, spectrophotochemical and fourier transform infrared spectroscopy studies. Maced J Chem Chem Eng 35:97–105
Yavuz Ö, Saka C (2013) Surface modification with cold plasma application on kaolin and its effects on the adsorption of methylene blue. Appl Clay Sci 85:96–102
Acknowledgements
The authors would like to thank from the nuclear science and technology research institute in Tehran for providing means and support required for implementation of this study.
Author information
Authors and Affiliations
Corresponding author
Additional information
Editorial responsibility: V.K. Gupta.
Rights and permissions
About this article
Cite this article
Mirzaei, H., Almasian, M.R., Mousavian, S.M.A. et al. Plasma modification of a natural zeolite to improve its adsorption capacity of strontium ions from water samples. Int. J. Environ. Sci. Technol. 16, 6157–6166 (2019). https://doi.org/10.1007/s13762-018-2024-0
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13762-018-2024-0