Skip to main content
Log in

Art of Waste to Fortune: Conversion of Redgram Stalk into Value Added Chemicals Through Fast Pyrolysis

  • Short Communication
  • Published:
National Academy Science Letters Aims and scope Submit manuscript

Abstract

Bio-oil production from redgram stalk was investigated in a fluidized bed reactor to study the influence of temperature and particle size. The maximum biooil yield of 52.8 %wt was obtained at 450 °C with a particle size of 0.25–0.50 mm. Properties of the biooil were studied and the biooil had more 5a,14a-Androstane-17a-carboxylic acid, 3a,14-dihydroxy-c-lactone, acetate (10.61 %) and phenolic compounds among them 3-pentadecyl phenol was abundant (23.15 %). This feedstock may be a better alternate source for the production of these valuable chemicals for their sustainable production.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2

References

  1. Mohan D, Pittman JCU, Steele PH (2006) Pyrolysis of wood/biomass for bio-oil: a critical review. Energy Fuels 20:848–849

    Article  Google Scholar 

  2. Scott DS (1988) Can. Patent No. 1,241,541, 1988

  3. Charles AM, Akwasi AB, Neil MG, Isabel ML, David AL, Kevin BH (2010) Biooil and biochar production from corn cobs and stover by fast pyrolysis. Biomass Bioenergy 34:67–74

    Article  Google Scholar 

  4. Heo HS, Park HJ, Yim JH, Sohn JM, Park J, Kim SS, Ryu C, Jeon JK, Park YK (2010) Influence of operation variables on fast pyrolysis of Miscanthus sinensis var. Purpurascens. Bioresour Technol 101:3672–3677

    Article  Google Scholar 

  5. Chen T, Wu C, Liu R, Fei W, Liu S (2011) Effect of hot vapor filtration on the characterization of bio-oil from rice husks with fast pyrolysis in a fluidized-bed reactor. Bioresour Technol 102:6178–6185

    Article  Google Scholar 

  6. Kim SJ, Jung SH, Kim JS (2010) Fast pyrolysis of palm kernel shells: influence of operation parameters on the bio-oil yield and the yield of phenol and phenolic compounds. Bioresour Technol 101:9294–9300

    Article  Google Scholar 

  7. Ates F, Putun E, Putun E (2004) Fast pyrolysis of sesame stalk: yields and structural analysis of bio oil. J Anal Appl Pyrolysis 71:779–790

    Article  Google Scholar 

  8. Zheng JL, Yi WM, Wang NN (2008) Bio-oil production from cotton stalk. Energy Convers Manag 49:1724–1730

    Article  Google Scholar 

  9. Antony Raja S, Robert Kennedy Z, Pillai BC, Lindon Robert Lee C (2009) Flash pyrolysis of Jatropha oil cake in fluidized bed reactor. Int Rev Mech Eng 3(6):753–757

    Google Scholar 

  10. He R, Ye XP, English BC, Satrio JA (2009) Influence of pyrolysis condition on switchgrass bio-oil yield and physicochemical properties. Bioresour Technol 100:5305–5311

    Article  Google Scholar 

  11. Park HJ, Heo HS, Park YK, Yim JH, Jeon JK, Park J, Ryu C, Kim SS (2010) Clean bio-oil production from fast pyrolysis of sewage sludge: effects of reaction conditions and metal oxide catalysts. Bioresour Technol 101:83–85

    Article  Google Scholar 

  12. Duman G, Okutucu C, Ucar S, Stahl R, Yanik J (2011) The slow and fast pyrolysis of cherry seed. Bioresour Technol 102:1869–1878

    Article  Google Scholar 

  13. Heo HS, Park HJ, Park TK, Ryu C, Suh DJ, Suh YW, Yim JH, Kim SS (2010) Bio-oil production from fast pyrolysis of waste furniture sawdust in a fluidized bed. Bioresour Technol 101:S91–S96

    Article  Google Scholar 

  14. Asadullah M, Rahman MA, Ali MM, Motin MA, Sultan MB, Alam MR, Rahman MS (2008) Jute stick pyrolysis for bio-oil production in fluidized bed reactor. Bioresour Technol 99:44–50

    Article  Google Scholar 

  15. Lee KH, Kang BS, Park YK, Kim JS (2005) Influence of reaction temperature, pretreatment, and a char removal system on the production of bio-oil from rice straw by fast pyrolysis, using a fluidized bed. Energy Fuels 19:2179–2184

    Article  Google Scholar 

  16. Sharma RK, Wooten JB, Baliga VL, Lin X, Chan WG, Hajaligol MR (2004) Characterization of chars from pyrolysis of lignin. Fuel 83:1469–1482

    Article  Google Scholar 

  17. Gani A, Naurse I (2007) Effect of cellulose and lignin content on pyrolysis of combustion characteristics for several types of biomass. Renew Energy 32:49–61

    Article  Google Scholar 

  18. Yang H, Yan R, Chen H, Lee DH, Zheng C (2007) Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel 86:1781–1788

    Article  Google Scholar 

  19. Menendz JA, Dominguez A, Fernandez Y, Pis YY (2007) Evidence of self-gasification during the micro-wave induced pyrolysis of coffee hulls. Energy Fuels 21(1):373–378

    Article  Google Scholar 

  20. Qiang L, Zhi LW, Feng ZX (2009) Overview of fuel properties of biomass fast pyrolysis oils. Energy Convers Manag 50:1376–1383

    Article  Google Scholar 

  21. Thangalazhy SG, Adhikari S, Ravindran H, Gupta RB, Fasina O, Maobing T, Fernando S (2010) Physiochemical properties of bio-oil produced at various temperatures from pine wood using an auger reactor. Bioresour Technol 101:8389–8395

    Article  Google Scholar 

Download references

Acknowledgments

The authors acknowledge the financial support from the Council of Scientific and Industrial Research, New Delhi (9/641/0165/2012). The physical and infrastructural assistance from Tamil Nadu Agricultural University, Coimbatore, India is greatly acknowledged.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. Mythili.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mythili, R., Subramanian, P. & Venkatachalam, P. Art of Waste to Fortune: Conversion of Redgram Stalk into Value Added Chemicals Through Fast Pyrolysis. Natl. Acad. Sci. Lett. 39, 151–155 (2016). https://doi.org/10.1007/s40009-016-0440-6

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40009-016-0440-6

Keywords

Navigation