Skip to main content
Log in

Microstructure and Electrochemical Properties of CoCrCuFeNiNb High-Entropy Alloys Coatings

  • Published:
Acta Metallurgica Sinica (English Letters) Aims and scope

Abstract

The CoCrCuFeNiNb high-entropy alloys coatings were prepared by using plasma-transferred arc cladding process. The microstructure and electrochemical behaviors of the coating were investigated in detail. The experimental results indicated that the coating consists of a simple fcc solid solution phase and an order (CoCr)Nb-type Laves phase. The polarization curves, obtained in 1 and 6 mol/L hydrochloric acid solutions, clearly indicated that the general corrosion resistance of the coating at ambient temperature was better than that of 304 stainless steel. The coating displayed a lower corrosion current and lower corrosion rate. Electrochemical impedance spectroscopy demonstrated that the impedance of the coating was significantly higher than that of the 304 stainless steel.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. J.W. Yeh, S.K. Chen, S.J. Lin, J.T. Gan, T.S. Chin, T.T. Shun, C.H. Tsau, S.Y. Chang, Adv. Eng. Mater. 6, 299 (2004)

    Article  Google Scholar 

  2. J.M. Zhu, H.M. Fu, H.F. Zhang, A.M. Wang, H. Li, Z.Q. Hu, Mater. Sci. Eng. A 527, 6975 (2010)

    Article  Google Scholar 

  3. M.H. Chuang, M.H. Tsai, W.R. Wang, S.J. Lin, J.W. Yeh, Acta Mater. 59, 6308 (2011)

    Article  Google Scholar 

  4. C.Y. Hsu, C.C. Juan, W.R. Wang, T.S. Sheu, J.W. Yeh, S.K. Chen, Mater. Sci. Eng. A 528, 3581 (2011)

    Article  Google Scholar 

  5. O.N. Senkov, G.B. Wilks, J.M. Scott, D.B. Miracle, Intermetallics 19, 698 (2011)

    Article  Google Scholar 

  6. M.H. Tsai, C.W. Wang, C.W. Tsai, W.J. Shen, J.W. Yeh, J.Y. Gan, J. Electrochem. Soc. 158, H1161 (2011)

    Article  Google Scholar 

  7. Y. Chen, T. Duval, U.D. Hung, J.W. Yeh, H.C. Shih, Corros. Sci. 47, 2257 (2005)

    Article  Google Scholar 

  8. T.K. Chen, T.T. Shun, J.W. Yeh, M.S. Wong, Surf. Coat. Technol. 188–189, 193 (2004)

    Article  Google Scholar 

  9. S.Y. Chang, S.Y. Lin, Y.C. Huang, Thin Solid Films 519, 4865 (2011)

    Article  Google Scholar 

  10. C.H. Lai, M.H. Tsai, S.J. Lin, J.W. Yeh, Surf. Coat. Technol. 201, 6993 (2007)

    Article  Google Scholar 

  11. C.H. Lin, J.G. Duh, J.W. Yeh, Surf. Coat. Technol. 201, 6304 (2007)

    Article  Google Scholar 

  12. H.W. Chang, P.K. Huang, A. Davison, J.W. Yeh, C.H. Tsau, C.C. Yang, Thin Solid Films 516, 6402 (2008)

    Article  Google Scholar 

  13. M.H. Tsai, C.H. Lai, J.W. Yeh, J.Y. Gan, J. Phys. D 41, 235402 (2008)

    Article  Google Scholar 

  14. P.K. Huang, J.W. Yeh, Scr. Mater. 62, 105 (2010)

    Article  Google Scholar 

  15. M.I. Lin, M.H. Tsai, W.J. Shen, J.W. Yeh, Thin Solid Films 518, 2732 (2010)

    Article  Google Scholar 

  16. P.K. Huang, J.W. Yeh, T.T. Shun, S.K. Chen, Adv. Eng. Mater. 6, 74 (2004)

    Article  Google Scholar 

  17. L.M. Wang, C.C. Chen, J.W. Yeh, S.T. Ke, Mater. Chem. Phys. 126, 880 (2011)

    Article  Google Scholar 

  18. J.H. Chen, P.N. Chen, C.M. Lin, C.M. Chang, Y.Y. Chang, WWu Surf, Coat. Technol. 203, 2983 (2009)

    Article  Google Scholar 

  19. H. Zhang, Y. Pan, Y.Z. He, H.S. Jiao, Appl. Surf. Sci. 257, 2259 (2011)

    Article  Google Scholar 

  20. H. Zhang, Y. Pan, Y.Z. He, Mater. Des. 32, 1910 (2011)

    Article  Google Scholar 

  21. X.Y. Ye, M.X. Ma, Y.X. Cao, W.J. Liu, X.H. Ye, Y. Gu, Phys. Proc. 12, 303 (2011)

    Article  Google Scholar 

  22. Y.J. Hsu, W.C. Chiang, J.K. Wu, Mater. Chem. Phys. 92, 112 (2005)

    Article  Google Scholar 

  23. J.B. Cheng, X.B. Liang, Z.H. Wang, B.S. Xu, Plasma Chem. Plasma Process. 33, 979 (2013)

    Article  Google Scholar 

  24. S. Kou, Welding Metallurgy, 2nd edn. (Wiley, Hoboken, 2003)

    Google Scholar 

  25. F.R. De Boer, R. Boom, W.C.M. Mattens, A.R. Miedema, A.K. Niessen, Cohesion in Metals: Transition Metal Alloys (Elsevier Science Publishing Company. Inc., Amsterdam, 1989), pp. 65–225

    Google Scholar 

  26. X. Yang, Y. Zhang, Mater. Chem. Phys. 132, 233 (2012)

    Article  Google Scholar 

  27. D.A. Jones, Principles and Prevention of Corrosion, 2nd edn. (Prentice Hall, Upper Saddle River, 1996)

    Google Scholar 

  28. N. Pebere, C. Riera, F. Dabosi, Electrochim. Acta 35, 555 (1990)

    Article  Google Scholar 

  29. C. Cao, Electrochim. Acta 35, 837 (1990)

    Article  Google Scholar 

  30. C. Cao, Electrochim. Acta 35, 831 (1990)

    Article  Google Scholar 

  31. W.R. Osório, C. Brito, L.C. Peixoto, A. Garcia, Electrochim. Acta 76, 218 (2012)

    Article  Google Scholar 

  32. M.R.F. Hurtado, P.T.A. Sumodjo, A.V. Benedetti, Electrochim. Acta 48, 2791 (2003)

    Article  Google Scholar 

  33. B.X. Huang, K. Wang, J.S. Church, Y.S. Li, Electrochim. Acta 44, 2571 (1999)

    Article  Google Scholar 

  34. M. Pourbaix, Atlas of Electrochemical Equilibria in Aqueous Solutions (Pergamon Press, Oxford, 1966)

    Google Scholar 

Download references

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (No. 51105129).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jiangbo Cheng.

Additional information

Available online at http://link.springer.com/journal/40195

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Cheng, J., Liu, D., Liang, X. et al. Microstructure and Electrochemical Properties of CoCrCuFeNiNb High-Entropy Alloys Coatings. Acta Metall. Sin. (Engl. Lett.) 27, 1031–1037 (2014). https://doi.org/10.1007/s40195-014-0117-4

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40195-014-0117-4

Keywords

Navigation