Skip to main content
SpringerLink
Log in

Controllable Synthesis of Hollow Multishell Structured Co3O4 with Improved Rate Performance and Cyclic Stability for Supercapacitors

  • Article
  • Published:
Chemical Research in Chinese Universities Aims and scope

Abstract

Hollow multishelled structures(HoMSs) Co3O4 with specially appointed shell number(double-, triple- and quadruple-) were accurately prepared by a sequential templating approach. Due to the superiorities of inimitable porous multishelled structure, triple-HoMSs Co3O4 achieved the best performance among all the samples with a specific capacitance of 1028.9 F/g at 10 mV/s and 688.2 F/g at 0.5 A/g, respectively. Furthermore, the electrode delivered a high rate performance(89.8% retention at 10 A/g) and excellent cycle stability(6.8% loss over 2000 cycles), showing a great promise for practical application in the future.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. AraveLeela M. R., Gowda S. R., Shaijumon M. M., Ajayan P. M., Adv. Mater., 2012, 24, 5045

    Google Scholar 

  2. Xu Y., Wang X., An C., Wang Y., Jiao L., Yuan H., J. Mater. Chem. A, 2014, 2, 16480

    CAS  Google Scholar 

  3. Ke Q., Tang C., Yang Z., Zheng M., Mao L., Liu H., Wang J., Electrochim. Acta, 2015, 163, 9

    CAS  Google Scholar 

  4. Peng S., Li L., Tan H., Cai R., Shi W., Li C., Mhaisalkar S. G., Srinivasan S., Ramakrishna S., Yan Q., Adv. Funct. Mater., 2014, 24, 2155

    CAS  Google Scholar 

  5. Wang G., Zhang L., Zhang J., Chem. Soc. Rev., 2012, 41, 797

    CAS  PubMed  Google Scholar 

  6. Tang H., Wang J., Yin H., Zhao H., Wang D., Tang Z., Adv. Mater., 2015, 27, 1117

    CAS  PubMed  Google Scholar 

  7. Zhang L., Zhao X., Chem. Soc. Rev., 2009, 38, 2520

    CAS  PubMed  Google Scholar 

  8. Chen S., Ramachandran R., Mani V., Sarawathi R., Int. J. Electrochem. Sci., 2014, 9, 4072

    Google Scholar 

  9. Rakhi R. B., Chen W., Cha D., Alshareef H. N., Nano Lett., 2012, 12, 2559

    CAS  Google Scholar 

  10. Yuan C., Yang L., Hou L., Shen L., Zhang X., Lou X., Energy Environ. Sci., 2012, 5, 7883

    CAS  Google Scholar 

  11. Fan H., Quan L., Yuan M., Zhu S., Wang K., Zhong Y., Chang L., Shao H., Wang J., Zhang J., Cao C., Electrochim. Acta, 2016, 188, 222

    CAS  Google Scholar 

  12. Yan J., Wang Q., Wei T., Fan Z., Adv. Energy Mater., 2013, 4, 1

    Google Scholar 

  13. Simon P., Gogotsi Y., Nat. Mater., 2008, 7, 845

    CAS  PubMed  Google Scholar 

  14. Wang D., Wang Q., Wang T., Inorg. Chem., 2011, 50, 6482

    CAS  PubMed  Google Scholar 

  15. Wang X., Li M., Chang Z., Yang Y., Wu Y., Liu X., ACS Appl. Mater. Inter., 2015, 7, 2280

    CAS  Google Scholar 

  16. Yu X., Yu L., Wu H., Lou X., Angew. Chem., Int. Ed., 2015, 54, 5331

    CAS  Google Scholar 

  17. Xia X., Tu J., Mai Y., Wang X., Gu C., Zhao X., J. Mater. Chem., 2011, 21, 9319

    CAS  Google Scholar 

  18. Zhang Y., Wang Y., Xie Y., Cheng T., Lai W., Pang H., Huang W., Nanoscale, 2014, 6, 14354

    CAS  PubMed  Google Scholar 

  19. Du H., Jiao L., Wang Q., Yang J., Guo L., Si Y., Wang Y., Yuan H., Nano Res., 2013, 6, 87

    CAS  Google Scholar 

  20. Chen Y., Li Z., Lou X., Angew. Chem., Int. Ed., 2015, 54, 10521

    CAS  Google Scholar 

  21. Wang J., Tang H., Ren H., Yu R., Qian J., Mao D., Zhao H., Wang D., Adv. Sci., 2014, 1, 1400011

    Google Scholar 

  22. Guo J., Yin Z., Zang X., Dai Z., Zhang Y., Huang W., Dong X., Nano Res., 2017, 10, 405

    CAS  Google Scholar 

  23. Zhao X., Yu R., Tang H., Mao D., Qi J., Wang B., Zhang Y., Zhao H., Hu W., Wang D., Adv. Mater., 2017, 29, 1700550

    Google Scholar 

  24. Chen M., Wang J., Tang H., Yang Y., Wang B., Zhao H., Wang D., Inorg. Chem. Front., 2016, 3, 1065

    CAS  Google Scholar 

  25. Park G. D., Lee J. H., Lee J. K., Kang Y. C., Nano Res., 2014, 7, 1738

    CAS  Google Scholar 

  26. Lai X., Halpert J. E., Wang D., Energy Environ. Sci., 2012, 5, 5604

    CAS  Google Scholar 

  27. Wang J., Yang N., Tang H., Dong Z., Jin Q., Yang M., Kiisailus D., Zhao H., Tang Z., Wang D., Angew. Chem., Int. Ed., 2013, 125, 6545

    Google Scholar 

  28. Dong Z., Ren H., Hessel C. M., Wang J., Yu R., Jin Q., Yang M., Hu Z., Chen Y., Tang Z., Zhao H., Wang D., Adv. Mater., 2014, 26, 905

    CAS  PubMed  Google Scholar 

  29. Wang J., Wan J., Wang D., Acc. Chem. Res., 2019, 52, 2169

    CAS  PubMed  Google Scholar 

  30. Xu S., Hessel C. M., Ren H., Yu R., Jin Q., Yang M., Zhao H., Wang D., Energy Environ. Sci., 2014, 7, 632

    CAS  Google Scholar 

  31. Salhabi E., Zhao L., Wang J., Yang M., Wang B., Wang D., 2019, 58, 9078

  32. Lai X., Li J., Korgel B. A., Dong Z., Li Z., Su F., Du J., Wang D., Angew. Chem., Int. Ed., 2011, 123, 2790

    Google Scholar 

  33. Lou X., Deng D., Lee J., Feng J., Archer L., Adv. Mater., 2008, 20, 258

    CAS  Google Scholar 

  34. Kinsinger N. M., Dudchenko A., Wong A., Kisailus D., ACS Appl. Mater. Interfaces, 2013, 5, 6247

    CAS  PubMed  Google Scholar 

  35. Xiong S., Yuan C., Zhang X., Xi B., Qian Y., Chem. Eur. J., 2009, 15, 5320

    CAS  PubMed  Google Scholar 

  36. Deng S., Xiao X., Xing X., Wu J., Wen W., Wang Y., J. Mol. Catal. A: Chem., 2015, 398, 79

    CAS  Google Scholar 

  37. Xu J., Gao P., Zhao T., Energy Environ. Sci., 2012, 5, 5333

    CAS  Google Scholar 

  38. Wang L., Liu X., Wang X., Yang X., Lu L., Curr. Appl. Phys., 2010, 10, 1422

    Google Scholar 

  39. Zhang F., Yuan C., Lu X., Zhang L., Che Q., Zhang X., J. Power Sources, 2012, 203, 250

    CAS  Google Scholar 

  40. Pal M., Rakshit R., Singh A. K., Mandal K., Energy, 2016, 103, 481

    CAS  Google Scholar 

  41. Fan M., Ren B., Yu L., Song D., Liu Q., Liu J., Wang J., Jing X., Liu L., Electrochim. Acta, 2015, 166, 168

    CAS  Google Scholar 

  42. Liu X., Gao Y., Yang G., Nanoscale, 2016, 8, 4227

    CAS  PubMed  Google Scholar 

  43. Wang Y., Pan A., Zhu Q., Nie Z., Zhang Y., Tang Y., Liang S., Cao G., J. Power Sources, 2014, 272, 107

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. State Key Laboratory of Biochemical Engineering Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, P. R. China

    Cong Wang, Jiangyan Wang & Dan Wang

  2. Department of Chemistry, School of Science & Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, Tianjin, 300072, P. R. China

    Cong Wang & Wenping Hu

Authors
  1. Cong Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jiangyan Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Wenping Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Dan Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Dan Wang.

Additional information

Supported by the National Natural Science Foundation of China(Nos.21590795, 21821005, 51772296, 51772294, 51702321, 51972306, 51802306).

Electronic Supplementary Information

40242_2019_40_MOESM1_ESM.pdf

Controllable Synthesis of Hollow Multishell Structured Co3O4 with Improved Rate Performance and Cyclic Stability for Supercapacitors

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, C., Wang, J., Hu, W. et al. Controllable Synthesis of Hollow Multishell Structured Co3O4 with Improved Rate Performance and Cyclic Stability for Supercapacitors. Chem. Res. Chin. Univ. 36, 68–73 (2020). https://doi.org/10.1007/s40242-019-0040-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40242-019-0040-3

Keywords

Search

Navigation