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Study of Molarity Concentration Variation Over Optical, Structural and Gas Sensing Response for ZnO Thin Film Based NOx Gas Sensor

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Abstract

Zinc oxide (ZnO) thin films as sensing layer with different molarity concentration are obtained by the sol–gel method using spin coating technique. Zinc acetate dihydrate (Zn(CH3COO)2·2H2O) was taken as starting material. For desired molarity weighed Zinc Acetated dihydrate is dissolved in particular amount of Ethanol. The solution is put on hot plate with Magnetic stirrer at a temperature of 60 °C while stirring 400 rpm to 600 rpm procedure continued for 45 min to 60 min. After that the solution was kept at room temperature for 24 h for ageing effect. By using spin coating method the prepared solution was coated on silicon substrate and then annealed for preparing highly crystalline ZnO thin films. The optical surface morphological and structural studies were done for the synthesized ZnO thin films. The important parameter considered for the gas sensing behavior are operating temperature and sensor response The reported study provides a significant development towards ZnO thin film thickness variations with a very high sensitivity, rapid response and recovery times. The UV–Vis transmittance spectra of ZnO thin films has been studied over quartz substrate under similar deposition parameters. The single coated samples were prepared with different molarities of 1 M, 0.7 M, 0.5 M, 0.33 M, 0.1 M, 0.05 M. Energy band gap of each sample is calculated by using Tauc plot and studied for the varying band gap & the gas sensitivity for the samples.

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References

  1. D. Bagnall, Y. Chen, Z. Zhu, T. Yao, S. Koyama, M.Y. Shen et al., Optically pumped lasing of ZnO at room temperature. Appl. Phys. Lett. 70, 2230–2232 (1997)

    Article  Google Scholar 

  2. V. Srikant, V. Sergo, D.R. Clarke, Epitaxial aluminum-doped zinc oxide thin films on sapphire: I, effect of substrate orientation. J. Am. Ceram. Soc. 78, 1931–1934 (1995)

    Article  Google Scholar 

  3. G. Carlotti, G. Socino, A. Petri, E. Verona, Acoustic investigation of the elastic properties of ZnO films. Appl. Phys. Lett. 51, 1889–1891 (1987)

    Article  Google Scholar 

  4. W. Jeong, S. Kim, G. Park, Preparation and characteristic of ZnO thin film with high and low resistivity for an application of solar cell. Thin Solid Films 506, 180–183 (2006)

    Article  Google Scholar 

  5. G.S. Devi, V.B. Subrahmanyam, S. Gadkari, S. Gupta, NH3 gas sensing properties of nanocrystalline ZnO based thick films. Anal. Chim. Acta 568, 41–46 (2006)

    Article  Google Scholar 

  6. T. Pauporté, D. Lincot, Electrodeposition of semiconductors for optoelectronic devices: results on zinc oxide. Electrochim. Acta 45, 3345–3353 (2000)

    Article  Google Scholar 

  7. J.-H. Lee, K.-H. Ko, B.-O. Park, Electrical and optical properties of ZnO transparent conducting films by the sol–gel method. J. Cryst. Growth 247, 119–125 (2003)

    Article  Google Scholar 

  8. V. Kumar, N. Singh, R. Mehra, A. Kapoor, L. Purohit, H. Swart, Role of film thickness on the properties of ZnO thin films grown by sol–gel method. Thin Solid Films 539, 161–165 (2013)

    Article  Google Scholar 

  9. J. Chen, T. Fujita, Effects of annealing on photoluminescence of ZnO thin film prepared by vapor phase growth. Jpn. J. Appl. Phys. 42, 602 (2003)

    Article  Google Scholar 

  10. R. Herberholz, M. Igalson, H. Schock, Distinction between bulk and interface states in CuInSe2/CdS/ZnO by space charge spectroscopy. J. Appl. Phys. 83, 318–325 (1998)

    Article  Google Scholar 

  11. S. Trolier-McKinstry, P. Muralt, Thin film piezoelectrics for MEMS. J. Electroceram. 12, 7–17 (2004)

    Article  Google Scholar 

  12. H. Zheng, X. Du, Q. Luo, J. Jia, C. Gu, Q. Xue, Wet chemical etching of ZnO film using aqueous acidic salt. Thin Solid Films 515, 3967–3970 (2007)

    Article  Google Scholar 

  13. S. Christoulakis, M. Suchea, M. Katharakis, N. Katsarakis, E. Koudoumas, G. Kiriakidis, ZnO nanostructured transparent thin films by PLD. Rev. Adv. Mater. Sci. 10, 331–334 (2005)

    Google Scholar 

  14. P. Tyagi, A. Sharma, M. Tomar, V. Gupta, Metal oxide catalyst assisted SnO2 thin film based SO2 gas sensor. Sens. Actuators B Chem. 224, 282–289 (2016)

    Article  Google Scholar 

  15. M. Deshwal, A. Arora, Enhanced acetone detection using Au doped ZnO thin film sensor. J. Mater. Sci. Mater. Electron. 29, 1–6 (2018)

    Article  Google Scholar 

  16. P. Tyagi, S. Sharma, M. Tomar, F. Singh, V. Gupta, Swift heavy ion irradiated SnO2 thin film sensor for efficient detection of SO2 gas. Nucl. Instrum. Methods Phys. Res. Sect. B 379, 219–223 (2016)

    Article  Google Scholar 

  17. A. Arora, M. Deshwal, Enhanced sensitivity with thickness optimization of ZnO based acetone sensor. Indian J. Pure Appl. Phys. (IJPAP) 56, 367–372 (2018)

    Google Scholar 

  18. V. Gupta, A. Mansingh, Influence of postdeposition annealing on the structural and optical properties of sputtered zinc oxide film. J. Appl. Phys. 80, 1063–1073 (1996)

    Article  Google Scholar 

  19. A. Singh, A. Sharma, M. Tomar, V. Gupta, Reduced graphene oxide-SnO2 nanocomposite thin film based CNG/PNG sensor. Sens. Actuators B Chem. 245, 590–598 (2017)

    Article  Google Scholar 

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Correspondence to Manish Deshwal.

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Kaur, S., Deshwal, M. Study of Molarity Concentration Variation Over Optical, Structural and Gas Sensing Response for ZnO Thin Film Based NOx Gas Sensor. Trans. Electr. Electron. Mater. 20, 309–314 (2019). https://doi.org/10.1007/s42341-019-00113-x

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