Skip to main content
Log in

High Efficiency Perovskite Solar Cells: Materials and Devices Engineering

  • Review Paper
  • Published:
Transactions on Electrical and Electronic Materials Aims and scope Submit manuscript

Abstract

Since the first report on 9.7% efficient solid-state perovskite solar cell (PSC) in 2012, perovskite photovoltaics received tremendous attentions. Efforts to increase power conversion efficiency (PCE) have been continuously made. As a result, a record PCE of 25.2% was certified in 2019, which surpassed those achieved from the conventional solar cells based on CIGS and CdTe. The superb photovoltaic performance of PSC is related to the defect-tolerant property, the long carrier lifetime, the long diffusion length of photo-generated carriers, and the high absorption coefficient. In this review, materials and devices engineering are described for achieving stability and higher PCE in PSCs. From the practical point of view, key technologies for materials, coating, and device fabrication are described, which is expected to be helpful to achieve high efficiency PSCs. Moreover, interfacial engineering methodologies toward hysteresis-less and stable PSCs are also presented to give insight into better understanding ion migration and recombination in PSCs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1

Copyright 2012 Nature Springer

Fig. 2
Fig. 3

Copyright 2014 Wiley

Fig. 4

Copyright 2015 Wiley

Fig. 5

Copyright 2015 Wiley

Fig. 6

Copyright 2014 Nature Springer

Fig. 7

Copyright 2016 American Chemical Society, and Ref [19] for (b and c), Copyright 2015, American Chemical Society

Fig. 8

Copyright 2015 The Royal Society of Chemistry

Fig. 9

Copyright 2014 The Royal Society of Chemistry

Fig. 10

Copyright 2014 The Royal Society of Chemistry, Ref [30] for (c) and (d), Copyright 20145 The Royal Society of Chemistry

Fig. 11

Copyright 2016 Wiley

Fig. 12

Copyright 2014 American Chemical Society

Fig. 13

Copyright 2017 The Royal Society of Chemistry

Fig. 14

Copyright 2018 Wiley

Fig. 15

Copyright 2015 American Chemical Society

Fig. 16

Copyright 2018 American Chemical Society

Fig. 17

Copyright 2019 Wiley

Fig. 18

Copyright 2016 Nature Springer

Fig. 19

Copyright 2019 American Chemical Society

Fig. 20

Copyright 2018 Wiley

Similar content being viewed by others

References

  1. H.-S. Kim, C.-R. Lee, J.-H. Im, K.-B. Lee, T. Moehl, A. Marchioro, S.-J. Moon, R. Humphry-Baker, J.-H. Yum, J.E. Moser, M. Grätzel, N.-G. Park, Sci. Rep. 2, 591 (2012)

    Article  CAS  Google Scholar 

  2. J.-H. Im, C.-R. Lee, J.-W. Lee, S.-W. Park, N.-G. Park, Nanoscale 3, 4088 (2011)

    Article  CAS  Google Scholar 

  3. Best Research-Cell Efficiencies (2019), https://www.nrel.gov/pv/assets/pdfs/best-research-cell-efficiencies.20190802.pdf. Accessed 27 Sept 2019

  4. C.C. Stoumpos, C.D. Malliakas, M.G. Kanatzidis, Inorg. Chem. 52, 9019 (2013)

    Article  CAS  Google Scholar 

  5. J.-W. Lee, D.-J. Seol, A.-N. Cho, N.-G. Park, Adv. Mater. 26, 4991 (2014)

    Article  CAS  Google Scholar 

  6. N.J. Jeon, J.H. Noh, W.S. Yang, Y.C. Kim, S. Ryu, J. Seo, S.I. Seok, Nature 517, 476 (2015)

    Article  CAS  Google Scholar 

  7. Q. Jiang, Y. Zhao, X. Zhang, X. Yang, Y. Chen, Z. Chu, Q. Ye, X. Li, Z. Yin, J. You, Nat. Photonics 13, 460 (2019)

    Article  CAS  Google Scholar 

  8. J.-W. Lee, D.-H. Kim, H.-S. Kim, S.-W. Seo, S.M. Cho, N.-G. Park, Adv. Energy Mater. 5, 1501310 (2015)

    Article  CAS  Google Scholar 

  9. H.S. Jung, N.-G. Park, Small 11, 10 (2015)

    Article  CAS  Google Scholar 

  10. H.-S. Kim, S.H. Im, N.-G. Park, J. Phys. Chem. C 118, 5615 (2014)

    Article  CAS  Google Scholar 

  11. N.-G. Park, Mater. Today 18, 65 (2015)

    Article  CAS  Google Scholar 

  12. N.J. Jeon, J.H. Noh, Y.C. Kim, W.S. Yang, S. Ryu, S.I. Seok, Nat. Mater. 13, 897 (2014)

    Article  CAS  Google Scholar 

  13. J.-H. Im, I.-H. Jang, N. Pellet, M. Gratzel, N.-G. Park, Nat. Nanotechnol. 9, 927 (2014)

    Article  CAS  Google Scholar 

  14. S. Mastroianni, F.D. Heinz, J.-H. Im, W. Veurman, M. Padilla, M.C. Schubert, U. Würfel, M. Grätzel, N.-G. Park, A. Hinsch, Nanoscale 7, 19653 (2015)

    Article  CAS  Google Scholar 

  15. J.-H. Im, H.-S. Kim, N.-G. Park, APL Mater. 2, 081510 (2014)

    Article  CAS  Google Scholar 

  16. J.-W. Lee, N.-G. Park, MRS Bull. 40, 654 (2015)

    Article  CAS  Google Scholar 

  17. N. Ahn, D.-Y. Son, I.-H. Jang, S.M. Kang, M. Choi, N.-G. Park, J. Am. Chem. Soc. 137, 8696 (2015)

    Article  CAS  Google Scholar 

  18. J.-W. Lee, H.-S. Kim, N.-G. Park, Acc. Chem. Res. 49, 311 (2016)

    Article  CAS  Google Scholar 

  19. N.-G. Park, Inorg. Chem. 56, 3 (2017)

    Article  CAS  Google Scholar 

  20. M.A. Afroz, R.K. Gupta, R. Garai, M. Hossain, S.P. Tripathi, P.K. Iyer, Org. Electron. 74, 172 (2019)

    Article  CAS  Google Scholar 

  21. M. Wang, F. Cao, K. Deng, L. Li, Nano Energy 63, 103867 (2019)

    Article  CAS  Google Scholar 

  22. A. Kulkarni, A.K. Jena, M. Ikegami, T. Miyasaka, Chem. Commun. 55, 4031 (2019)

    Article  CAS  Google Scholar 

  23. Y. Zong, Z. Zhou, M. Chen, N.P. Padture, Y. Zhou, Adv. Energy Mater. 8, 1800997 (2018)

    Article  CAS  Google Scholar 

  24. N. Ahn, S. Min Kang, J.-W. Lee, M. Choi, N.-G. Park, J. Mater. Chem. A 3, 19901 (2015)

    Article  CAS  Google Scholar 

  25. N.-G. Park, CrystEngComm 18, 5977 (2016)

    Article  CAS  Google Scholar 

  26. J.-W. Lee, D.-K. Lee, D.-N. Jeong, N.-G. Park, Adv. Funct. Mater. 28, 1807047 (2018)

    Google Scholar 

  27. J.-W. Lee, T.-Y. Lee, P.J. Yoo, M. Grätzel, S. Mhaisalkard, N.-G. Park, J. Mater. Chem. A 2, 9251 (2014)

    Article  CAS  Google Scholar 

  28. N.-G. Park, J.V.D. Lagemaat, A.J. Frank, J. Phys. Chem. B 104, 8989 (2000)

    Article  CAS  Google Scholar 

  29. S. Dharani, H.K. Mulmudi, N. Yantara, P.T.T. Trang, N.-G. Park, M. Graetzel, S. Mhaisalkar, N. Mathews, P.P. Boix, Nanoscale 6, 1675 (2014)

    Article  CAS  Google Scholar 

  30. J.-W. Lee, S.H. Lee, H.-S. Ko, J. Kwon, J.H. Park, S.M. Kang, N. Ahn, M. Choi, J.K. Kim, N.-G. Park, J. Mater. Chem. A 3, 9179 (2015)

    Article  CAS  Google Scholar 

  31. S.M. Kang, S. Jang, J.-K. Lee, J. Yoon, D.-E. Yoo, J.-W. Lee, M. Choi, N.-G. Park, Small 12, 2443 (2016)

    Article  CAS  Google Scholar 

  32. D.-Y. Son, J.-H. Im, H.-S. Kim, N.-G. Park, J. Phys. Chem. C 118, 16567 (2014)

    Article  CAS  Google Scholar 

  33. D.-Y. Son, K.-H. Bae, H.-S. Kim, N.-G. Park, J. Phys. Chem. C 119, 10321 (2015)

    Article  CAS  Google Scholar 

  34. K.-H. Jung, J.-Y. Seo, S. Lee, H. Shin, N.-G. Park, J. Mater. Chem. A 5, 24790 (2017)

    Article  CAS  Google Scholar 

  35. Q. Jiang, L. Zhang, H. Wang, X. Yang, J. Meng, H. Liu, Z. Yin, J. Wu, X. Zhang, J. You, Nat. Energy 2, 16177 (2016)

    Article  CAS  Google Scholar 

  36. J. Chen, N.-G. Park, J. Phys. Chem. C 122, 14039 (2018)

    Article  CAS  Google Scholar 

  37. N. Arora, M.I. Dar, A. Hinderhofer, N. Pellet, F. Schreiber, S.M. Zakeeruddin, M. Grätzel, Science 358, 768 (2017)

    Article  CAS  Google Scholar 

  38. J. Chen, J.-Y. Seo, N.-G. Park, Adv. Energy Mater. 8, 1702714 (2018)

    Article  CAS  Google Scholar 

  39. I.J. Park, M.A. Park, D.H. Kim, G.D. Park, B.J. Kim, H.J. Son, M.J. Ko, D.-K. Lee, T. Park, H. Shin, N.-G. Park, H.S. Jung, J.Y. Kim, J. Phys. Chem. C 119, 27285 (2015)

    Article  CAS  Google Scholar 

  40. S. Seo, I.J. Park, M. Kim, S. Lee, C. Bae, H.S. Jung, N.-G. Park, J.Y. Kim, H. Shin, Nanoscale 8, 11403 (2016)

    Article  CAS  Google Scholar 

  41. X. Zhao, J. Chen, N.-G. Park, Sol. RRL 3, 1800339 (2019)

    Article  CAS  Google Scholar 

  42. H.-S. Kim, I.-H. Jang, N. Ahn, M. Choi, A. Guerrero, J. Bisquert, N.-G. Park, J. Phys. Chem. Lett. 6, 4633 (2015)

    Article  CAS  Google Scholar 

  43. H.-S. Kim, N.-G. Park, J. Phys. Chem. Lett. 5, 2927 (2014)

    Article  CAS  Google Scholar 

  44. A.-N. Cho, I.-H. Jang, J.-Y. Seo, N.-G. Park, J. Mater. Chem. A 6, 18206 (2018)

    Article  CAS  Google Scholar 

  45. D.-H. Kang, N.-G. Park, Adv. Mater. 31, 1805214 (2019)

    Article  CAS  Google Scholar 

  46. D.-Y. Son, S.-G. Kim, J.-Y. Seo, S.-H. Lee, H. Shin, D. Lee, N.-G. Park, J. Am. Chem. Soc. 140, 1358 (2018)

    Article  CAS  Google Scholar 

  47. N.-G. Park, H. Segawa, ACS Photonics 58, 2970 (2018)

    Article  CAS  Google Scholar 

  48. J. Chen, N.-G. Park, Adv. Mater. 30, 1803019 (2018)

    Google Scholar 

  49. J. Chen, X. Zhao, S.-G. Kim, N.-G. Park, Adv. Mater. 31, 1902902 (2019)

    Article  CAS  Google Scholar 

  50. D.-Y. Son, J.-W. Lee, Y.J. Choi, I.-H. Jang, S. Lee, P.J. Yoo, H. Shin, N. Ahn, M. Choi, D. Kim, N.-G. Park, Nat. Energy 8, 1 (2016)

    Google Scholar 

  51. L. Xie, J. Chen, P. Vashishtha, X. Zhao, G.S. Shin, S.G. Mhaisalkar, N.-G. Park, ACS Energy Lett. 4, 2192 (2019)

    Article  CAS  Google Scholar 

  52. J. Chen, S.-G. Kim, N.-G. Park, Adv. Mater. 180, 2018 (1948)

    Google Scholar 

Download references

Acknowledgements

This work was supported by the National Research Foundation of Korea (NRF) Grants funded by the Ministry of Science, ICT Future Planning (MSIP) of Korea under contracts NRF-2012M3A6A7054861 (Global Frontier R&D Program on Center for Multiscale Energy System), NRF-2016M3D1A1027663 and NRF-2016M3D1A1027664 (Future Materials Discovery Program) and NRF-2015M1A2A2053004 (Climate Change Management Program).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Nam-Gyu Park.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Park, NG. High Efficiency Perovskite Solar Cells: Materials and Devices Engineering. Trans. Electr. Electron. Mater. 21, 1–15 (2020). https://doi.org/10.1007/s42341-019-00156-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s42341-019-00156-0

Keywords

Navigation