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Experimental investigation of strength, durability, and microstructure of red-mud concrete

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Abstract

Recent trends in the construction industry involve the use of industrial by-products as building materials to improve waste management and reduce excessive CO2 emissions from the cement industry. Red mud (RM) is a by-product of alumina refinery plants. When improperly disposed, red mud harms the surrounding area, owing to its highly alkaline nature. In the current work, up to 15% of the cement in concrete was replaced with red mud, in increments of 2.5%. In addition, to enhance the pozzolanic reaction, metakaolin was used as a ternary mineral; it replaces 10% of the cement. A slump cone test was conducted to evaluate the workability. Compressive, flexural, and split tensile strength tests were conducted to observe the mechanical properties. A rapid chloride penetration test and water absorption tests were conducted to determine the durability properties of the concrete. X-ray fluorescence analysis was conducted to determine the chemical composition of both the red mud and the metakaolin. A scanning electron microscope analysis was conducted to characterize the microstructure of the RM concrete. The 12.5% red-mud replacement mix showed the greatest improvement in mechanical properties among all the mixes. As the red-mud replacement increased, the chloride-ion passage was reduced. Moreover, a denser microstructure formation was observed with the red-mud replacement, as compared to standard concrete.

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References

  1. M.A. Raheem, S.L.M. Gómez, C.M.A. Piñeiro, M.B. Olazaran, Uses of red mud as a construction material. AEI. (2017). https://doi.org/10.1061/9780784480502.032

    Article  Google Scholar 

  2. I.M. Nikbin, M. Aliaghazadeh, S. Charkhtab, A. Fathollahpour, Environmental impacts and mechanical properties of lightweight concrete containing bauxite residue (red mud). J. Clean. Prod. 172, 2683–2694 (2018). https://doi.org/10.1016/j.jclepro.2017.11.143

    Article  CAS  Google Scholar 

  3. C. Venkatesh, M.S.R. Chand, N. Ruben, A state of the art on red mud as a substitutional cementitious material. Ann. Chim. Sci. Mater. 43(2), 99–106 (2019). https://doi.org/10.18280/acsm.430206

    Article  Google Scholar 

  4. Y. Liu, R. Naidu, Hidden values in bauxite residue (red mud): recovery of metals. Waste Manag. 34(12), 2662–2673 (2014). https://doi.org/10.1016/j.wasman.2014.09.003

    Article  CAS  Google Scholar 

  5. V. Mymrin, K. Alekseev, O.M. Fortini, Y.K. Aibuldinov, C.L. Pedroso, A. Nagalli, E.B. Costa, Environmentally clean materials from hazardous red mud, ground cooled ferrous slag and lime production waste. J. Clean. Prod. 161, 376–381 (2017). https://doi.org/10.1016/j.jclepro.2017.05.109

    Article  CAS  Google Scholar 

  6. P.E. Tsakiridis, S.A. Leonardou, P. Oustadakis, Red mud addition in the raw meal for the production of Portland cement clinker. J. Hazard. Mater. 116(1–2), 103–110 (2004). https://doi.org/10.1016/j.jhazmat.2004.08.002

    Article  CAS  Google Scholar 

  7. S. Samal, A.K. Ray, A. Bandopadhyay, Proposal for resources, utilization and processes of red mud in India—a review. Int. J. Miner. Process. 118, 43–55 (2013). https://doi.org/10.1016/j.minpro.2012.11.001

    Article  CAS  Google Scholar 

  8. D.V. Ribeiro, J.A. Labrincha, M.R. Morelli, Effect of red mud addition on the corrosion parameters of reinforced concrete evaluated by electrochemical methods. RevistaIBRACON de Estruturas e Materiais 5(4), 451–467 (2012). https://doi.org/10.1590/S1983-41952012000400004

    Article  Google Scholar 

  9. Ć.G. Topličić, V. Mitic, D. Grdić, N. Ristić, Z. Grdić Environmental aspects of red mud and its utilization as a component of building materials. in Proceedings of the IV advanced ceramics and applications conference (Atlantis Press, Paris, 2017), pp. 447–474. https://doi.org/10.2991/978-94-6239-213-7_31

    Google Scholar 

  10. V. Dentoni, B. Grosso, G. Massacci, Environmental sustainability of the alumina industry in Western Europe. Sustainability 6(12), 9477–9493 (2014). https://doi.org/10.3390/su6129477

    Article  Google Scholar 

  11. R.B. Rao, L. Besra, B.R. Reddy, G.N. Banerjee, The effect of pretreatment on magnetic separation of ferruginous minerals in bauxite. Phys. Sep. Sci. Eng. 8(2), 115–123 (1997). https://doi.org/10.1155/1997/53574

    Article  CAS  Google Scholar 

  12. K.K. Shetty, G. Nayak, V. Vijayan, Effect of red mud and iron ore tailings on the strength of self compacting concrete. Eur. Sci. J. (2014). https://doi.org/10.19044/esj.2014.v10n21p%25p

    Article  Google Scholar 

  13. J.A. Rossignolo, Interfacial interactions in concretes with silica fume and SBR latex. Constr. Build. Mater. 23(2), 817–821 (2009). https://doi.org/10.1016/j.conbuildmat.2008.03.005

    Article  Google Scholar 

  14. S. Bhasin, N. Chandra, Studies on sintering behavior of pyrophyllite based ceramic tiles using di-potassium phosphatic binder. Silic. Ind. 69(1–2), 14–18 (2004)

    Google Scholar 

  15. D.L. Metilda, C. Selvamony, R. Anandakumar, A. Seeni, Investigations on optimum possibility of replacing cement partially by red mud in concrete. Sci. Res. Essays 10(4), 137–143 (2015). https://doi.org/10.5897/SRE2015.6166

    Article  Google Scholar 

  16. R.R. Raj, E.P. Pillai, A.R. Santhakumar, Strength and corrosion properties of concrete incorporating metakaolin and red mud. Eur. J. Sci. Res. 91(4), 569–579 (2012)

    Google Scholar 

  17. S. Nenadovic, G. Mucsi, L. Kljajevic, M. Mirkovic, M. Nenadovic, F. Kristaly, I. Vukanac, Physicochemical, mineralogical and radiological properties of red mud samples as secondary raw materials. Nucl. Technol. Radiat. Prot. 32(3), 261–266 (2017). https://doi.org/10.2298/ntrp1703261n

    Article  CAS  Google Scholar 

  18. D.V. Ribeiro, J.A. Labrincha, M.R. Morelli, Potential use of natural red mud as pozzolan for Portland cement. Mater. Res. 14(1), 60–66 (2011). https://doi.org/10.1590/S1516-1439201100500000

    Article  CAS  Google Scholar 

  19. C. Venkatesh, S.K. Mohiddin, N. Ruben, Corrosion inhibitors behaviour on reinforced concrete—a review. In Sustainable Construction and Building Materials (Springer, Singapore, 2019), pp. 127–134. https://doi.org/10.1007/978-981-13-3317-0

    Google Scholar 

  20. L. Senff, D. Hotza, J.A. Labrincha, Effect of red mud addition on the rheological behaviour and on hardened state characteristics of cement mortars. Constr. Build. Mater. 25(1), 163–170 (2011)

    Article  Google Scholar 

  21. A. Al Menhosh, Y. Wang, Y. Wang, N.L. Augusthus, Long term durability properties of concrete modified with metakaolin and polymer admixture. Constr. Build. Mater. 172, 41–51 (2018). https://doi.org/10.1016/j.conbuildmat.2018.03.215

    Article  CAS  Google Scholar 

  22. G. Dhinakaran, S. Thilgavathi, J. Venkataramana, Compressive strength and chloride resistance of metakaolin concrete. KSCE J. Civ. Eng. 16(7), 1209–1217 (2012). https://doi.org/10.1007/s12205-012-1235-z

    Article  Google Scholar 

  23. R.R. Rajendran, E.P. Pillai, Regression analysis of OPC-MK-RM-based ternary-blended concrete based on its experimental results. In Global Civil Engineering Conference (Springer, Singapore, 2017), pp. 323–332. https://doi.org/10.1007/978-981-10-8016-6_26

    Google Scholar 

  24. BIS, IS 12269-1987: Specifications for 53 Grade Ordinary Portland Cement (Bureau of Indian Standards, New Delhi, 1987)

    Google Scholar 

  25. BIS, IS 4031-I (1996) Specifications for Method of Physical Tests for Hydraulic Cement (Bureau of Indian Standards, New Delhi, 1996)

    Google Scholar 

  26. BIS, IS 383-2016: Specification for Coarse and Fine Aggregates from Natural Sources for Concrete (Bureau of Indian Standards, New Delhi, 2016)

    Google Scholar 

  27. BIS, IS2386-1963 Specification for Method of Tests for Aggregates for Concrete (Bureau of Indian Standards, New Delhi, 1963)

    Google Scholar 

  28. ASTM, ASTM C494: Standard Specification for Chemical Admixtures for Concrete (ASTM, West Conshohocken, 2005)

    Google Scholar 

  29. BIS, IS 10262-2019 Specification for Method of Preparation of Mix Calculations of Concrete (Bureau of Indian Standards, New Delhi, 2019)

    Google Scholar 

  30. BIS, IS: 516-2013 Specification for Method of Tests for Concrete (Bureau of Indian Standards, New Delhi, 2013)

    Google Scholar 

  31. BIS, IS: 516-1959 Specification for Flexural Strength of Concrete—Method of Test (Bureau of Indian Standards, New Delhi, 1959)

    Google Scholar 

  32. BIS, IS 5816-1999 Specification for Splitting Tensile Strength of Concrete—Method of Test (Bureau of Indian Standards, New Delhi, 1999)

    Google Scholar 

  33. BIS, IS 1124-1974 Specification for Water Absorption for Concrete (Bureau of Indian Standards, New Delhi, 1974)

    Google Scholar 

  34. BIS, IS: 9013-1978 Specification for Method of Curing of Concrete (Bureau of Indian Standards, New Delhi, 1978)

    Google Scholar 

  35. ASTM C1202: Standard Specification for Rapid Chloride Penetrable Test ASTM, West Conshohocken

  36. X. Cheng, X. Yang, C. Zhang, X. Gao, Y. Yu, K. Mei, X. Guo, C. Zhang, Effect of red mud addition on oil well cement at high temperatures. Adv. Cem. Res. (2019). https://doi.org/10.1680/jadcr.18.00224

    Article  Google Scholar 

  37. W.C. Tang, Z. Wang, Y. Liu, H.Z. Cui, Influence of red mud on fresh and hardened properties of self-compacting concrete. Constr. Build. Mater. 178, 288–300 (2018). https://doi.org/10.1016/j.conbuildmat.2018.05.171

    Article  CAS  Google Scholar 

  38. D.V. Ribeiro, A.S. Silva, J.A. Labrincha, M.R. Morelli, Rheological properties and hydration behavior of portland cement mortars containing calcined red mud. Can. J. Civ. Eng. 40(6), 557–566 (2013). https://doi.org/10.1139/cjce-2012-0230

    Article  CAS  Google Scholar 

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Acknowledgements

We thank Dr. P.K. Pattajoshi and V. Krishna Kumari, AGM (Chemical) R&D, Nalco, India, for providing the red mud.

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  1. Department of Civil Engineering, Vignan’s Foundation for Science, Technology and Research, Guntur, Andhra Pradesh, India

    Chava Venkatesh, Ruben Nerella & Madduru Sri Rama Chand

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  1. Chava Venkatesh
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  2. Ruben Nerella
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  3. Madduru Sri Rama Chand
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Correspondence to Chava Venkatesh.

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Venkatesh, C., Nerella, R. & Chand, M.S.R. Experimental investigation of strength, durability, and microstructure of red-mud concrete. J. Korean Ceram. Soc. 57, 167–174 (2020). https://doi.org/10.1007/s43207-019-00014-y

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