The solubility of gases in liquids 6. Solubility of N2, O2, CO, CO2, CH4, and CF4 in methylcyclohexane and toluene at 283 to 313 K☆
References (36)
- et al.
J. Chem. Thermodynamics
(1971) - et al.
J. Chem. Thermodynamics
(1971) - et al.
J. Chem. Thermodynamics
(1971) - et al.
J. Chem. Thermodynamics
(1971) - et al.
J. Chem. Thermodynamics
(1973) - et al.
Chem. Phys. Lett.
(1971) - et al.
J. Chem. Phys.
(1972) - et al.
J. Chem. Phys.
(1959) - et al.
J. Chem. Phys.
(1960) - et al.
Anal. Chem.
(1971)
Chem. Rev.
A.I.Ch.E. Journal
A.I.Ch..E. Journal
J. Phys. Chem.
Chem. Rev.
Acta Chem. Scand.
Zh. Prikl. Khim. (Leningrad)
Sci. Pap. Inst. Phys. Chem. Res. (Tokyo)
Cited by (72)
The impressive impact of including enthalpy and heat capacity of mixing data when parameterising equations of state. Application to the development of the E-PPR78 (Enhanced-Predictive-Peng-Robinson-78) model.
2022, Fluid Phase EquilibriaCitation Excerpt :Table S1 in the Supporting Information presents the list of the 204 pure components involved in the development of the E-PPR78 model. For each binary system considered in the development of the E-PPR78 model, Table S2 contains the main features of collected experimental data, extracted from references [38–2068]. Bibliographic references are reported in Table S3.
Modeling of nitrogen solubility in unsaturated, cyclic, and aromatic hydrocarbons: Deep learning methods and SAFT equation of state
2022, Journal of the Taiwan Institute of Chemical EngineersCitation Excerpt :The general sketch of the problem under study and the steps of conducting this research is depicted in Fig. 1. To model nitrogen solubility in unsaturated, cyclic, and aromatic hydrocarbons, 673 data points of experimental nitrogen’ solubilities for 23 various hydrocarbons were accumulated from the various sources [24,27-48]. Table 1 listed the hydrocarbons' properties utilized in the present study for modeling.
Solubility and mass transfer of H<inf>2</inf>, CH<inf>4</inf>, and their mixtures in vacuum gas oil: An experimental and modeling study
2019, Chinese Journal of Chemical EngineeringCitation Excerpt :Florusse et al. measured the solubility of H2 in heavy n-alkanes up to 30 mol% and described the GLE of these mixtures through a molecular-based equation of state based on the statistical associating fluid theory (SAFT), with the result that the calculated values agree with experimental data [10]. On the other hand, Field et al. measured the solubility of CH4 in methylcyclohexane and toluene from 283 to 313 K, and compared the experimental data with the results obtained through the scaled particle theory (SPT), indicating that both agree well [11]. Hesse et al. measured the solubility of CH4 in n-alkanes at 298.15 K [12].
Phase equilibrium of CCS mixtures: Equation of state modeling and Monte Carlo simulation
2017, Journal of Supercritical FluidsCitation Excerpt :The pure fluid physical properties (Tc, Pc and ω) that were used in this study, originate from Poling et al. [57] . Table 2 details the sources of the binary reference data [7,58–353] used in our evaluations, along with the temperature, pressure and composition ranges for each binary system. To the best of our knowledge, most of the data available in the open literature were collected, except some very old data which were excluded.
Carbon dioxide and water: An effective multiphase medium for selective hydrogenation of nitriles with a Pd/Al2O3 catalyst
2016, Journal of CO2 UtilizationCitation Excerpt :The comparative reaction was also tested in the presence of N2 instead of 1 MPa CO2. A higher N2 pressure of 4 MPa was used because the solubility of N2 in organic liquids is smaller than that of CO2 [22,23]. The reaction results were observed to be little influenced by the presence of 4 MPa N2 as compared to the results in the absence of CO2 (entry 1).
Interfacial and bulk properties of vapor-liquid equilibria in the system toluene + hydrogen chloride + carbon dioxide by molecular simulation and density gradient theory + PC-SAFT
2016, Fluid Phase EquilibriaCitation Excerpt :For HCl, these experimental data are only available at low temperatures [100–103]. The Henry's law constant from the present MD simulations is in very good agreement with the experimental data for both systems in the entire temperature range in which experimental data are available, which is narrow for HCl [81,100–111]. For low temperatures the PC-SAFT results for the Henry's law constant of HCl in toluene are higher than the experimental values, which have not been used for the adjustment of the binary interaction parameter.
- ☆
This work was supported by Public Health Service Grant No. 14710-05.
- a
Senior Fulbright Research Scholar, on leave from the University of Vienna, Austria.