Regular paperBreakthrough volume of monoterpenes on Tenax TA: influence of temperature and concentration for α-pinene
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Quantitative and qualitative assessment of VOCs emitted from cellulose acetate movie films by PTR-ToF-MS
2021, Journal of Cultural HeritageCitation Excerpt :Other analytical approaches such as EGA-GC–MS [21], based on a thermodesorption phase have identical shortcomings and they require a sample that is not always possible with heritage objects.. The adsorbent must have a breakthrough volume adjusted to the VOCs concentration [22,23]. Ultimately, the VOCs speciation and concentration might not reflect the real ambient air composition.
Vapor pressure and vaporization enthalpy studies of (+)-longifolene, (−)-isolongifolene and Β-myrcene by correlation gas chromatography
2019, Journal of Chemical ThermodynamicsCharacterization of volatile organic compound emissions from self-bonded boards resulting from a coriander biorefinery
2018, Industrial Crops and ProductsMetal-organic frameworks as superior media for thermal desorption-gas chromatography application: A critical assessment of MOF-5 for the quantitation of airborne formaldehyde
2017, Microchemical JournalCitation Excerpt :MOF-5 has significantly greater adsorption capacity than common commercial adsorbents (surface area (m2·g− 1): (1) MOF-5 = 2833, (2) Carboxen 1000 (60/80 mesh) = 1200, (3) Carbopack X (60/80 mesh) = 240) [21–23]. It is, however, practically impossible to quantify gaseous FA using commercial adsorbents (Carbopack series, Carboxen, etc.) for sorptive collection [24–26]. FA breakthrough on commercial adsorbents can occur immediately because of their weak adsorptivities [24,27].
Characterization of quality assurance properties of biogenic volatile organic compounds with an emphasis on the breakthrough behavior, recovery, and temporal stability
2016, Microchemical JournalCitation Excerpt :Various monoterpenes (e.g., limonene and pinenes) are reported to either isomerize, dehydrogenate (e.g., to p-cymene), or produce other products (e.g., trimethylbenzene) on hot solid surfaces including common sorbent materials. Such dimerization of isoprene, if occurring, is known to yield various monoterpenes [23,33,34,36–39]. In our experiments, 1,2,3-trimethylbenzene, a decomposition product of (+)-β-pinene on Carbotrap sorbent [38] was not detected.