Le diagramme des phases solides du systeme Bi2O3CaO

doi:10.1016/0022-4596(76)90087-6

Journal of Solid State Chemistry

Volume 18, Issue 2, June 1976, Pages 133-140

https://doi.org/10.1016/0022-4596(76)90087-6 Get rights and content

The phase diagram Bi₂O₃ single bond CaO has been investigated in the solid state by high temperature X-ray analysis and D.T.A. methods. Four compounds (Bi₁₄Ca ₅O₂₆, Bi₂CaO₄, Bi₁₀Ca ₇O₂₂, and Bi₆Ca ₇O₁₆), which melt incongruently, and four solid solutions (fcc, bcc, and two rhombohedral) have been characterized. Quenchings of the fcc solid solution lead to several metastable fluorite-type ss. These, as well as the quenched forms of the rhombohedral and bcc solid solutions, have defect oxygen lattice consistent with the formula Bi_(2−2n)Ca _(2n−1)O_(2−n)□_n.

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Le diagramme des phases solides du systeme Bi2O3CaO

Thèse

C. R. Acad. Sci.

Thèse

Thèse

C. R. Acad. Sci.

Bull. Soc. Fr. Mineral. Cristallogr.

Le diagramme des phases solides du systeme Bi₂O₃CaO