Elsevier

Solid State Communications

Volume 9, Issue 3, 1 February 1971, Pages 175-180
Solid State Communications

Donor-acceptor pair recombination in GaN

https://doi.org/10.1016/0038-1098(71)90112-8Get rights and content

Abstract

Photoluminescence arising from distant donor-acceptor pair recombination in GaN has been identified and analyzed. Impurity binding energies of ED = 42 ± 1 meV and EA ∼ 200 meV are proposed. The recombination rate constant, W(O) = (3 ± 2) x 107 sec is consistent with a direct, fundamental energy gap in GaN.

Résumé

La photoluminescence provenant de recombinaisons entre paires distnates du type donneur-accepteur a été identifiée et analysée dans le nitrure de gallium. Des énergies de liaison d'impuretés En = 42 ± 1 meV et EA = 200 meV sont proposées. La valeur du taux de recombinaison W(O) = (3 ± 2) x 10-7 sec-1 est en accord avec l'existence d'une bande fondamentale directe dans le GaN.

References (20)

  • J.I. Pankove et al.

    Solid State Commun.

    (1970)
  • D.A. Manchon et al.

    Solid State Commun

    (1970)
  • H.G. Grimmeiss et al.

    Z. Naturf.

    (1959)
  • H.G. Grimmeiss et al.

    Z. Naturf.

    (1960)
  • M.R. Lorenz et al.

    J. Electrochem. Soc.

    (1962)
  • V.A. Krasnoperov et al.

    Optics and Spectrosc.

    (1969)
  • To be...
  • J.I. Pankove et al.
  • H. Grimmeiss et al.

    J. appl. Phys.

    (1970)
  • ZETTERSTROM R.B., J. Mat. Sci., in...
There are more references available in the full text version of this article.

Cited by (255)

  • Understanding photoelectrocatalytic degradation of tetracycline over three-dimensional coral-like ZnO/BiVO<inf>4</inf> nanocomposite

    2021, Materials Chemistry and Physics
    Citation Excerpt :

    Steady-state fluorescence spectra of BiVO4 exhibited a prominent band located at 500 nm and a low-energy tail band that is broadly extended to 650 nm. The latter involves charge trapping at defect states that lie within the band gap, and radiative recombination of these trapped charges produced additional emission band that is of lower energy than the band edge emission [50–52]. Both PL spectra of BiVO4 and ZnO/BiVO4 exhibited distinct luminescent peak at c. a. 640 nm.

  • Anomalous emission from oxygen incorporated GaN nanowires

    2018, Physica E: Low-Dimensional Systems and Nanostructures
    Citation Excerpt :

    Generally, gallium-vacancy is regarded as shallow acceptor and nitrogen-vacancy is regarded as shallow donor in GaN. PL emission around ∼`3.26 eV in GaN has been well reported as a result of donor-acceptor pair (DAP) recombination [34,35]. Further, Reshchikov and Morkoc [34] also studied the unusual line emission from GaN as Yi where the most common peak near 3.21–3.23 eV is provided by Y7.

  • Growth study of self-assembled GaN nanocolumns on silica glass by plasma assisted molecular beam epitaxy

    2017, Journal of Crystal Growth
    Citation Excerpt :

    The NC sample demonstrates a strong band edge emission from the GaN wurtzite crystal observed at 357 nm. In addition, the emission peak at 378 nm (3.28 eV) comes from donor-acceptor pairs (DAP) recombinations, while the weaker peak at 388 nm (3.19 eV) is 1-longitudinal optical (LO) phonon replica [64–66]. The DAP recombinations can be observed despite only Si (donor) atoms were used as dopant and probably involve acceptor levels related to carbon impurities, specifically CN [67].

  • Yellow luminescence band in undoped GaN revealed by two-wavelength excited photoluminescence

    2016, Optical Materials
    Citation Excerpt :

    The below-gap emission bands dominated by a donor acceptor pair (DAP) transition at 3.28 eV with several LO phonon replicas. Dingle et al. [62] firstly observed the characteristic DAP emission at 3.26 eV with several LO phonon replicas which were also reported by others [63–65]. The emission band at 3.41 eV is due to the shallow donor (oxygen impurities) to the valence band transition [65–67], hereafter it is mentioned as IOX.

View all citing articles on Scopus
View full text