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2022, Nuclear Engineering and TechnologyCitation Excerpt :The sorption isotherm of cesium ions on the obtained material (Fig. 3) was well described by the Dubinin-Astakhov model (R2 = 0.9995) and allowed to calculate the theoretical value of the maximum sorption capacity equal to 3.19 mmol/g. Treatment of biogenic potassium aluminosilicate with an aqueous CsCl solution led to the substitution of potassium for cesium by the ion exchange mechanism, as was shown in Ref. [40]. At the same time, most of the potassium was replaced with cesium, and the real sorption capacity of biogenic aluminosilicate was 2.50 mmol/g, which is consistent with the theoretical value of the maximum sorption capacity calculated above.
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