Colloids and Surfaces A: Physicochemical and Engineering Aspects
On the non-freezing water interlayers between ice and a silica surface
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Cited by (42)
Predicting the hydraulic conductivity of frozen coarse-grained soils
2023, Journal of HydrologySimulation of the carbon dioxide hydrate-water interfacial energy
2022, Journal of Colloid and Interface ScienceCitation Excerpt :This produces a combination of “individual” experimental dissociation curves and different definitions for d, the mean pore diameter. Finally, there exists an unfrozen layer of liquid (water), of few angstroms in thickness, between the solid phase (hydrate) and the pore wall [24–27,100–103], producing an enhancement of the interfacial free energies that is is difficult to quantify and correct, and consequently the values are slightly larger than those in absence of pores. Not only agreement between predictions from computer simulation and experimental data taken from the literature is outstanding.
Novel shape-stabilized phase change materials: Insights into the thermal energy storage of 1-octadecanol/fumed silica composites
2022, Journal of Energy StorageCitation Excerpt :Secondly, the C2, C16, C4–15, C3, and C17 peaks were together shifted upfield toward those of the pure liquid C18OH for the C18OH/FS, suggesting that the C18OH in the SSPCM formed liquid-like layers or non-freezable layers, at the interfacial regions of narrow pores. Those layers were formed due to interfacial interactions between liquids and pore walls, which caused disordered arrangement and lowered mobility of molecules in the layer; as a result, the layers were unable to crystallize even at a temperature far below the solidification point of the bulk phase [30–33]. The non-freezable layers of C18OH in the SSPCM were further estimated using XRD and DSC measurements to the SSPCMs of 10 and 20 wt% C18OH (Fig. 7(b) and (c), respectively).
Generalising the Kozeny-Carman equation to frozen soils
2021, Journal of HydrologyFreezing of partly saturated cementitious materials – Insight into properties of pore confined solution and microstructure
2020, Construction and Building MaterialsCitation Excerpt :As mentioned before CM II differentiates large gel pores (3–12 nm), small gel pores (1–3 nm), intraglobular voids (<1 nm) and interlayer spaces. However, one has to remember that due to the well-recognized non-frozen layer of liquid water remaining on pore walls even at very low temperatures [56,57], the thermal analysis does not enable one to investigate small gel pores and intraglobular voids. Such a situation is even escalated owing to the fact that pore solution confined in cement matrix contains numerous ions, which significantly decrease transformed fraction in comparison to pure water, for details see Appendix.