Journal of Electroanalytical Chemistry and Interfacial Electrochemistry
Electrode emersion and the double layer
References (3)
- et al.
J. Electroanal. Chem.
(1973)
Cited by (43)
X-ray photoelectron spectroscopy in electrochemistry research
2018, Encyclopedia of Interfacial Chemistry: Surface Science and ElectrochemistryElectrical double layer at the mineral-aqueous solution interface as probed by XPS with fast-frozen samples
2010, Journal of Electron Spectroscopy and Related PhenomenaXPS at solid-aqueous solution interface
2006, Advances in Colloid and Interface ScienceCitation Excerpt :In the case of an electrochemical interface, this is controlled mainly by an external potential (at least for the nearly ideally polarizable electrodes), whereas EDL formation at dielectric surfaces is caused by chemical processes: surface functional groups ionisation, specific adsorption, ion exchange, etc. In the late 1970s, Hansen's group [45,46] used XPS as an independent method to prove that the EDL that forms at the surface of thin film electrodes is not altered by the removal of the electrode from the solution. These pioneering studies resulted in the development of the “emersed electrode” sample preparation technique and the first quantitative analysis of electric double layer composition at the surface of polycrystalline gold film in aqueous solutions of 0.005 M Cs2SO4 and 0.01 M Cs halides [47,48].
A review about the surface resistance technique in electrochemistry
2004, Surface Science ReportsIn situ electron yield detection of X-ray absorption fine structure of electrodes continuously emersed from electrolyte solutions
2003, Journal of Electroanalytical ChemistryCitation Excerpt :Although ingenious methods have been reported for the acquisition of EY spectra of polarized emersed hydrophobic electrodes under stationary conditions [12], the procedure described herein is the first in which the surface of the electrode was wet and continuously emersed, providing thereby improved conditions for effective potential control. The electrochemical cell involved in these experiments is similar in design to that reported by Hansen et al. [13,14], Kolb and coworkers [15,16], and Hansen [17] for work function [18] and optical studies [15,19,20], and later implemented by Kordesch et al. for the acquisition of quasi in situ Mossbauer effect spectroscopy of passive films on metallic Fe [21]. As shown in Fig. 1, the present arrangement incorporates a rotating working electrode in the form a thin wheel attached to a dc motor, with its flat face placed in front of a small custom-made electron yield detector (EYD) (see below).
On the work function of the gas exposed electrode surfaces in solid state electrochemistry
2000, Journal of Electroanalytical Chemistry