Species-strain dependence of stereoselectivity in microbial oxidation of thioethers
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Aspergillus genus as a source of new catalysts for sulfide oxidation
2012, Journal of Molecular Catalysis B: EnzymaticCitation Excerpt :At the best of our knowledge, only a few previous works have been reported dealing with Aspergillus capability to oxidize prochiral sulfides. In the 60–70s, Auret's group studied the fungal oxidation of diaryl and aryl alkyl sulfides employing mainly A. niger with certain success albeit the enantiomeric excesses (ees) and optical rotation signs resulted rather variable and substrate over-oxidation (sulfone formation) was always detected [14,22–24]. More recently, it has been studied the possibility of performing sulfoxidations using A. terreus [25,26].
7.14 Oxidation: Asymmetric Enzymatic Sulfoxidation
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