Synthese de thia-7 aza-1 bicyclo (4,3,0) nonanes par reaction radiocalaire regioselective.

doi:10.1016/S0040-4039(00)85567-7

Tetrahedron Letters

Volume 23, Issue 48, 1982, Pages 5039-5042

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Abstract

Several β-aminothiols prepared from 3-piperideine and different thiiranes react by free radical reactio chemically initiated to yield exclusively 7-thia-1-azabicyclo (4,3,0) nonane derivatives. Even when this process is in competition with a radical addition on a terminal ethylenic chain, the bicyclic thiazolidine is always the major product.

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Synthese de thia-7 aza-1 bicyclo (4,3,0) nonanes par reaction radiocalaire regioselective.

Abstract

Tetrahedron

C.R. Acad. Sci.

Bull. Soc. chim. France

Thèse de Doctorat ès Sciences

Synthesis