Elsevier

Advances in Catalysis

Volume 26, 1977, Pages 247-322
Advances in Catalysis

Compensation Effect in Heterogeneous Catalysis

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Publisher Summary

This chapter discusses the compensation effect in heterogeneous catalysis that expresses the existence of interrelated kinetic behavior within a group of rate processes. The chapter focuses on the interrelation between kinetic characteristics and the chemistry of the participating surface rate processes. The chapter discusses the theoretical models and statistical methods used in the recognition of compensation phenomena. The chapter illustrates reported examples of compensation behavior and describes new instances of the effect that became apparent while making the present search of published kinetic data. A semiquantitative statistical analysis of these trends has been undertaken to provide a common basis for comparisons and to attempt to define criteria that enable meaningful relationships to be recognized. The compensation effect remains largely an empirical method of classifying kinetic observations and this has not been developed into a theoretical representation capable of predicting activities and patterns of reactivity in hitherto untested catalytic processes. Development of the usefulness of the correlation necessarily requires reexamination of many of the basic tenets of heterogeneous kinetic behavior.

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