Recent development in rare earth doped phosphors for white light emitting diodes

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Abstract

As new light sources for next-generation illumination, white light-emitting diodes (WLEDs) have been extensively developed and are commercially available due to their excellent advantages, such as high efficiency, energy-saving, compactness, long operational lifetime and environmental friendliness. Currently, WLEDs with high color rendering are mainly based on wavelength conversion by one or more phosphor materials. In this review, the recent developments of phosphors for WLEDs were introduced combined with the relative work of our group. The common methods for generating white light for blue/ultraviolet (UV) WLEDs were summarized, including: (1) optimizing the commercially used phosphors; (2) developing some new phosphors based on UV LEDs chips; (3) realizing white light emission based on single host. Moreover, some typical new developed phosphors and their luminescence properties were introduced.

The recent advances in optimizing commercially used phosphors and developing new phosphors for generating white light emission

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References (77)

  • H Yokota et al.

    Cathodoluminescence of Ce-doped Gd2SiO5 and Gd9.33(SiO4)6O2 phosphor under continuous electron irradiation

    J. Alloys Compd.

    (2011)
  • P D Rack et al.

    The structure, device physics, and material properties of thin film electroluminescent displays

    Mater. Sci. Eng., R.

    (1998)
  • X Yu et al.

    Optical properties of Eu-activated calcium aluminosilicates synthesized in different atmospheres

    Opt. Mater.

    (2012)
  • L G Van Uitert

    An empirical relation fitting the position in energy of the lower-band edge for Eu2+ or Ce3+ in various compounds

    J. Lumin.

    (1984)
  • Y R Shi et al.

    Color-tunable LaCaAl3O7:Ce3+,Tb3+ phosphors for UV light-emitting diodes

    Mater. Res. Bull.

    (2013)
  • Y R Shi et al.

    Photoluminescence of green-emitting Ca7(PO4)2(SiO4)2: Eu2+ phosphor for white light emitting diodes

    Opt. Mater. Express.

    (2013)
  • G Zhu et al.

    Observation, identification and characterization of strong self-reduction process in a orthophosphate phosphor CaZr4(PO4)6:Eu

    Mater. Res. Bull.

    (2014)
  • R J Xie et al.

    Silicon-based oxynitride and nitride phosphors for white LEDs—A review

    Sci. Technol. Adv. Mater.

    (2007)
  • W J Park et al.

    Synthesis and luminescent properties of Eu2+ doped nitrogen-rich Ca-α-SiAlON phosphor for white light-emitting diodes

    Solid State Sci.

    (2010)
  • G Zhu et al.

    Warm white light generation from Dy3+ doped NaSr2Nb5O15 for white LEDs

    Mater. Lett.

    (2013)
  • X Ding et al.

    Synthesis and luminescent properties of a white light phosphor KBa2Nb5O15:Na+,Dy3+ for light-emitting-devices

    Mater. Res. Bull.

    (2013)
  • W Y Geng et al.

    Luminescent characteristics of Dy3+ doped calcium zirconium phosphate CaZr4(PO4)6 (CZP) phosphor for warm-white LEDs

    J. Lumin.

    (2014)
  • X L Zhang et al.

    Photoluminescence studies on Eu2+ and Ce3+-doped Li2SrSiO4

    J. Lumin.

    (2008)
  • Y Li et al.

    Warm-white-light emission from Eu2+/Mn2+-coactivated NaSrPO4 phosphor through energy transfer

    J. Phys. Chem. Solids

    (2013)
  • S Pimputkar et al.

    Prospects for LED lighting

    Nature Photon

    (2009)
  • Yamamoto H. White LED Phosphors: the Next Step. Proc. SPIE 7598, Optical Components and Materials VII 2010,...
  • A A Setlur et al.

    Incorporation of Si4+–N3– into Ce3+-doped garnets for warm white LED phosphors

    Chem. Mater.

    (2008)
  • R J Xie et al.

    2-phosphor-converted white light-emitting diodes using oxynitride/nitride phosphors

    Appl. Phys. Lett.

    (2007)
  • N Pfaff Brinkley et al.

    Robust thermal performance of Sr2Si5N8:Eu2+: an efficient red emitting phosphor for light emitting diode based white lighting

    Appl. Phys. Lett.

    (2011)
  • M H Crawford

    LEDs for solid-state lighting: performance challenges and recent advances

    IEEE J. Sel. Top. Quantum Electron.

    (2009)
  • M Zeuner et al.

    Low temperature precursor route for highly efficient spherically shaped LED-phosphors M2Si5N8:Eu2+(M=Eu, Sr, Ba)

    Chem. Mater.

    (2009)
  • L Wang et al.

    Enriching red emission of Y3Al5O12:Ce3+ by codoping Pr3+ and Cr3+ for improving color rendering of white LEDs

    Opt. Express

    (2010)
  • Y R Shi et al.

    Tunable luminescence of Y3Al5O12:0.06Ce3+,xMn2+ phosphors with different charge compensators for warm white light emitting diodes

    Opt. Express

    (2012)
  • Shen C Y, Li K, Yang Y. Asia-Pacific Optical Fiber Communication and Optoelectronic International Conference, November...
  • Z P Ci et al.

    Enhanced photoluminescence and thermal properties of size mismatch in Sr2.97–xyEu0.03MgxBaySiO5 for high-power white light-emitting diodes

    Inorg. Chem.

    (2014)
  • M H Crawford

    LEDs for solid-state lighting: performance challenges and recent advances

    IEEE J. Sel. Top. Quantum Electron.

    (2009)
  • W Ki et al.

    A semiconductor bulk material that emits direct white light

    J. Am. Chem. Soc.

    (2008)
  • P F Smet et al.

    Selecting conversion phosphors for white light-emitting diodes

    J. Electrochem. Soc.

    (2011)
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    Foundation item: Project supported by the National Science Foundation for Distinguished Young Scholars (50925206), the Specialized Research Fund for the Doctoral Program of Higher Education (20120211130003), the National Natural Science Foundation of China (51372105) and the Fundamental Research Funds for the Central Universities (lzujbky-2014-231)

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