Skip to main content
Log in

Wear Behavior of Plasma Oxidized CoCrMo Alloy under Dry and Simulated Body Fluid Conditions

  • Published:
Journal of Bionic Engineering Aims and scope Submit manuscript

Abstract

In this study, CoCrMo alloy was oxidized in plasma environment at the temperatures of 600 °C to 800 °C for 1 h to 5 h with 100% O2 gas and its tribological behavior was investigated. After the plasma oxidizing process, the compound and diffusion layers were formed on the surface. XRD results show that Cr2O3, α-Co and ε-Co phases diffracted from the modified layers after plasma oxidizing. The untreated and treated CoCrMo samples were subjected to wear tests both in dry and simulated body fluid conditions, and normal loads of 2 N and 10 N were used. For the sliding wear test, alumina balls were used as counter materials. It was observed that the wear resistance of CoCrMo alloy was increased after the plasma oxidizing process. The lowest wear rate was obtained from the samples that were oxidized at 800 °C for 5 h. It was detected that both wear environment and load have significant effects on the wear behavior of this alloy, and the wear resistance of oxidized CoCrMo alloy is higher when oxide-based counterface is used. The wear rates of both untreated and plasma oxidized samples increase under high loads.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Gümüşderelioğlu M. Biyomalzemeler. Bilim ve Teknik Dergisi, TÜBİTAK, 2002, 7, 20–21. (in Turkish)

    Google Scholar 

  2. Liu C. Biomimetic synthesis of collagen/nano-hydro-xyapitate scaffold for tissue engineering. Journal of Bionic Engineering, 2008, 5, 1–8.

    Article  Google Scholar 

  3. Niinomi M. Recent metallic materials for biomedical applications. Metallurgical and Materials Transactions A, 2001, 32A, 477–486.

    Google Scholar 

  4. Niinomi M. Mechanical biocompatibilities of titanium alloys for biomedical applications. Journal of the Mechanical Behavior of Biomedical Materials, 2008, 1, 30–42.

    Article  Google Scholar 

  5. Lanning B R, Wei R. High intensity plasma ion nitriding of orthopedic materials: Part II. Microstructural analysis. Surface and Coatings Technology, 2004, 186, 314–319.

    Article  Google Scholar 

  6. Wei R, Brooker T, Rincon C, Arps J. High-intensity plasma ion nitriding of orthopedic materials: Part I. Tribological study. Surface and Coatings Technology, 2004, 186, 305–313.

    Article  Google Scholar 

  7. Somers M A J, Christiansen T. Kinetics of microstructure evolution during gaseous thermochecical surface treatment. Journal of Phase Equilibria and Diffusion, 2005, 26, 520–528.

    Article  Google Scholar 

  8. Chu P K, Chen J Y, Wang L P, Huang N. Plasma-surface modification of biomaterials. Material Science and Engineering R, 2002, 36, 143–206.

    Article  Google Scholar 

  9. Luo Y, Yang L, Tian M. Influence of bio-lubricants on the tribological properties of Ti6Al4V alloy. Journal of Bionic Engineering, 2013, 10, 84–89.

    Article  Google Scholar 

  10. Munoz A I, Mischler S. Effect of the environment on wear ranking and corrosion of biomedical CoCrMo alloys. Journal of Material Science-Materials in Medicine, 2011, 22, 437–450.

    Article  Google Scholar 

  11. Wang Q, Zhang L, Dong J. Effects of plasma nitriding on microstructure and tribological properties of CoCrMo alloy implant materials. Journal of Bionic Engineering, 2010, 7, 337–344.

    Article  Google Scholar 

  12. Tsai H, Lu F, Chieh Y. Plasma oxidation of Al thin films on Si substrates. Thin Solid Films, 2007, 516, 1871–1876.

    Google Scholar 

  13. Hodgson A W E, Kurz S, Virtanen S, Fervel V, Olsson C O A, Mischler S. Passive and transpassive behaviour of CoCrMo in simulated biological solutions. Electrochimica Acta, 2004, 49, 2167–2178.

    Article  Google Scholar 

  14. Lewis A C, Heard P J. The effects of calcium phosphate deposition upon corrosion of CoCr alloys and the potential for implant failure. Journal of Biomedical Materials Research Part A, 2005, 75, 365–373.

    Article  Google Scholar 

  15. Yetim A F., Yıldız F., Vangölü Y, Alsaran A, Çelik A. Several plasma diffusion processes for improving wear properties of Ti6Al4V alloy. Wear, 2009, 267, 2179–2185.

    Article  Google Scholar 

  16. Vidal C V, Munoz A I. Effect of thermal and applied potential on the electrochemical behaviour of CoCrMo biomedical alloy. Electrochimica Acta, 2009, 54, 1798–1809.

    Article  Google Scholar 

  17. Dong M, Shen B. Oxidation resistance of boronized Co-CrMo alloy. International Journal of Refractory Metals and Hard Materials, 2010, 28, 424–428.

    Article  Google Scholar 

  18. Alsaran, A, Çelik A, Efeoğlu İ, Baran, Ö, Albayrak Ç. Friction and wear properties in SBF of Ti6Al4V alloy coated with various oxidation treatments. The 5th National Biomechanics Congress, Izmir, Turkey, 2010, 57–58.

    Google Scholar 

  19. Kokubo T, Takamada H. How useful is SBF in predicting in vivo bone bioactivity? Biomaterials, 2006, 27, 2907–2915.

    Article  Google Scholar 

  20. Yilbas B S, Sahin A Z, Garni A Z, Said S A M, Ahmed Z, Abdulaleem B J, Sami M. Plasma nitriding of Ti-6Al-4V alloy to improve some tribological properties. Surface and Coatings Technology, 1996, 80, 287–282.

    Article  Google Scholar 

  21. Ribeiro R, Ingole S, Usta M, Bindal C, Ucisik A H, Liang H. Tribological investigation of tantalum boride coating under dry and simulated body fluid conditions. Wear, 2007, 262, 1380–1386.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ali Fatih Yetim.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Çelik, A., Aslan, M., Yetim, A.F. et al. Wear Behavior of Plasma Oxidized CoCrMo Alloy under Dry and Simulated Body Fluid Conditions. J Bionic Eng 11, 303–310 (2014). https://doi.org/10.1016/S1672-6529(14)60035-4

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1016/S1672-6529(14)60035-4

Keywords

Navigation