Analysing nitrate losses from an artificially drained lowland catchment (North-Eastern Germany) with a mixing model

https://doi.org/10.1016/j.agee.2007.05.006Get rights and content

Abstract

Tile drainage shortens the residence time of water in the soil and may therefore aggravate the diffuse pollution of adjacent surface water bodies. To assess the environmental impacts of tile drainage on surface water bodies, it is important to assess how the drainage discharge and its solute signal translate from the frequently studied plot scale to the catchment scale. We used results from the automated hydrograph separation method ‘recursive digital filter’ in combination with a two-component mixing model to quantify the role of the different flow components and flow paths for the nitrate-nitrogen losses at three different scales – collector drain outlet (4.2 ha), ditch (179 ha) and brook catchment (15.5 km2) – in a pleistocene lowland area in North-Eastern Germany. Measured and modelled NO3-N concentrations of three 6-months winter seasons agreed reasonably well. At the tile drainage plot, the fast flow component was responsible for 63–91% of the total simulated nitrate-nitrogen losses. The stated ranges were derived from all accepted model runs. This flow component was interpreted as a fast component bearing nitrate from the nutrient-enriched topsoil. Tile drainage itself delivered 89–95% of the total nitrate losses in the ditch catchment. In the brook catchment, at most 25% of the area was responsible for 54–85% of the NO3-N losses. Although the mixing model is limited by the assumption of constant component concentrations and conservative behaviour of the solutes, it has shown to be a useful tool for hydrochemical studies. Overall, the results emphasise the importance of tile drainage for the catchments’ hydrochemistry and its environmental impact on the larger scale. Consequently, it will be difficult to significantly reduce diffuse pollution in an artificially drained lowland landscape on the catchment scale without addressing the issue of tile drainage. As a next step for model validation, other solutes such as sulphate and chloride could be added to reduce the uncertainty, and grassland should be explicitly included into the mixing model.

Introduction

Tile drainage is a common agricultural practice which is used to improve moisture and aeration conditions especially in lowland areas, but shortens the residence time of water in the soil and therefore aggravates diffuse pollution of adjacent surface water bodies with nutrients and pesticides (e.g. David et al., 1997, Heppell and Chapman, 2006, Tomer et al., 2003). For example, Behrendt and Bachor (1998) estimated that 47% of the nitrogen and 12% of the phosphorus emissions from the federal state Mecklenburg-Vorpommern (North-Eastern Germany) to the Baltic Sea originated from tile drainage.

However, given that the area contributing to the tile drain discharge can be defined and an impermeable layer underlies the tile drains, tile-drained fields can be considered as large lysimeters and are therefore ideal for the quantification of solute transport at the plot and field scale (Lennartz et al., 1999, Richard and Steenhuis, 1988). Numerous investigations (e.g. Heppell and Chapman, 2006, Kohler et al., 2003, Lennartz et al., 1999, Stamm et al., 1998) on tile drainage have been conducted at the field scale, from where the diffuse pollution originates. However, there are only a few catchment scale studies on this subject (Tomer et al., 2003) although this is frequently the relevant management scale, as, for example, for the European Water Framework Directive (European Parliament and European Council, 2000). To assess the environmental impacts of tile drainage on surface water bodies, it is therefore a matter of particular interest how the tile drain discharge and its solute signal translate from the field to higher scales.

Frequently, tile drainage is accompanied by flow anomalies causing a further acceleration of water and solute fluxes (Kohler et al., 2003, Lennartz et al., 1999). This combination of tile drainage and preferential flow may therefore create a ‘short circuit’ between contaminated topsoils and receiving water bodies (Laubel et al., 1999, Stamm et al., 1998). In catchment hydrology, hydrograph separation is carried out to split the total streamflow into a baseflow component and a surface runoff component. When transferring hydrograph separation methods to tile drain discharge data, it is generally assumed that the fast component originates from ‘preferential flow’ (Everts and Kanwar, 1990, Richard and Steenhuis, 1988), from ‘event water’ (Heppell and Chapman, 2006) or, more generally, from a ‘rapid flow component’ (Laubel et al., 1999), while the baseflow is thought to correspond to matrix flow. To our knowledge, only manual linear baseflow separation methods (Laubel et al., 1999), often combined with mixing models (Everts and Kanwar, 1990, Kohler et al., 2003, Richard and Steenhuis, 1988), have been applied for tile drain discharge data so far. For larger catchments, in contrast, automated methods are widespread (e.g. Arnold et al., 1995, Müller et al., 2003), which also do not have a real physical basis, but have a better reproducibility and are more objective than manual methods (Chapman, 1999, Müller et al., 2003). Another approach to split the hydrograph into different components or origins is the use of isotopic and tracer data for mixing models (Heppell and Chapman, 2006, Joerin et al., 2002, Ladouche et al., 2001, Uhlenbrook and Hoeg, 2003). A simple, yet frequently used method is the end-member mixing approach (EMMA, Hooper et al., 1990), which assumes that the solute concentrations in a stream are the result of the mixing of two or more constant sources (‘end members’) (e.g. Durand and Torres, 1996, Soulsby et al., 2003, Wade et al., 1999).

In this paper, we aim to quantify the role of different flow components and flow paths for the NO3-N losses at the different spatial scales using data of a hierarchical monitoring program. This program was set up in an agriculturally dominated lowland area in North-Eastern Germany, and high nutrient concentrations have been measured at a collector drain outlet, in ditches and in a brook (Tiemeyer et al., 2006). For this purpose, we utilise the automated hydrograph separation method ‘recursive digital filter’ (Nathan and McMahon, 1990) in combination with a simple two-component mixing model.

Section snippets

The field site ‘Dummerstorf’

The experimental field site ‘Dummerstorf’ (Fig. 1) in the federal state Mecklenburg-Vorpommern is located around 10 km southeast of the city of Rostock in a pleistocene lowland landscape (latitude 54°01′N, longitude 12°13′E). A hierarchical measurement program was initiated in November 2003 in the rural catchment of the brook Zarnow. Long-term mean annual precipitation, potential (reference crop) evapotranspiration and temperature are 665 mm, 490 mm and 8.2 °C, respectively. Due to a precipitation

Sensitivity analysis

Fig. 2 shows some examples of the sensitivity analysis: the baseflow concentration c-NO3-Nbase,II of the ditch in 2003 (Fig. 2a), the fast flow concentration c-NO3-Nfast,I of the collector drain in 2005 (Fig. 2b), the proportion Adrained,III of tile-drained fields in the brook catchment (Fig. 2c) and the recursive digital filter parameter β (Fig. 2d).

For c-NO3-Nbase,II, no clear distinction between the behavioural and non-behavioural model runs can be detected (Fig. 2a). Neither for the other

Conclusions

To quantify the role of the different flow components and flow paths for the NO3-N concentrations and losses at different scales, we utilised results from the automatic hydrograph separation method ‘recursive digital filter’ in combination with a stochastic two-component mixing model at the three spatial scales collector drain, ditch and brook. The application of a regional sensitivity analysis showed that most of the model parameters can be classified as ‘sensitive’. All in all, the modelling

Acknowledgements

We thank M. Kietzmann for the extensive chemical analysis and T. Hartwig for his assistance with the field work. The funding of B. Tiemeyer by the Landesgraduiertenförderung Mecklenburg-Vorpommern is gratefully acknowledged. Furthermore, we would like to thank three anonymous reviewers for their efforts and helpful comments.

References (48)

  • J.G. Arnold et al.

    Automated base flow separation and recession analysis techniques

    Ground Water

    (1995)
  • H. Behrendt et al.

    Point and diffuse load of nutrients to the Baltic Sea by river basins of North East Germany (Mecklenburg-Vorpommern)

    Water Sci. Technol.

    (1998)
  • K.J. Beven

    Changing ideas in hydrology—the case of physically-based models

    J. Hydrol.

    (1989)
  • K.J. Beven

    Rainfall-Runoff Modelling—The Primer

    (2001)
  • K.J. Beven

    A manifesto for the equifinality thesis

    J. Hydrol.

    (2006)
  • K.J. Beven et al.

    The future of distributed models: model calibration and uncertainty prediction

    Hydrol. Processes

    (1992)
  • N. Chahinian et al.

    Comparison of infiltration models to simulate flood events at the field scale

    J. Hydrol.

    (2005)
  • T. Chapman

    A comparison of algorithms for stream recession and baseflow separation

    Hydrol. Processes

    (1999)
  • N. Coles et al.

    The movement of nitrate fertiliser from the soil surface to drainage waters by preferential flow in weakly structured soils, Slapton, S. Devon

    Agric. Ecosyst. Environ.

    (1985)
  • M.B. David et al.

    Nitrogen balance in and export from an agricultural watershed

    J. Environ. Qual.

    (1997)
  • P. Durand et al.

    Solute transfer in agricultural catchments: the interest and limits of mixing models

    J. Hydrol.

    (1996)
  • European Parliament & European Council, 1998. Council Directive 98/83/EC of 3 November 1998 on the quality of water...
  • European Parliament & European Council, 2000. Directive 2000/60/EC of the European Parliament and of the Council of...
  • C.J. Everts et al.

    Estimating preferential flow to a subsurface drain with tracers

    Trans. ASAE

    (1990)
  • FAO, 1998. World reference base for soil resources. World Soil Resources Reports 84,...
  • R. Gächter et al.

    Nutrient transfer from soil to surface waters: differences between nitrate and phosphate

    Aquat. Sci.

    (2004)
  • C.M. Heppell et al.

    Analysis of a two-component hydrograph separation model to predict herbicide runoff in drained soils

    Agric. Water Manage.

    (2006)
  • D. Hesterberg et al.

    Chemistry of subsurface drain discharge from an agricultural polder soil

    Agric. Water Manage.

    (2006)
  • R.P. Hooper et al.

    Modelling stream water chemistry as a mixture of soil water end members: an application to the Panola Mountain catchment, Georgia, USA

    J. Hydrol.

    (1990)
  • C. Joerin et al.

    Uncertainty in hydrograph separation based on geochemical mixing models

    J. Hydrol.

    (2002)
  • P. Kahle et al.

    Untersuchungen zum Stickstoffaustrag über Dränung in einem nordostdeutschen Tieflandeinzugsgebiet

    WasserWirtschaft

    (2007)
  • A. Kohler et al.

    Using simple bucket models to analyse solute export to subsurface drains by preferential flow

    Vadose Zone J.

    (2003)
  • B. Ladouche et al.

    Hydrograph separation using isotopic, chemical and hydrological approaches (Strengbach catchment, France)

    J. Hydrol.

    (2001)
  • A. Laubel et al.

    Subsurface drainage loss of particles and phosphorus from field plot experiments and a tile-drained catchment

    J. Environ. Qual.

    (1999)
  • Cited by (45)

    • Effect of grass buffer strips on nitrate export from a tile-drained field site

      2018, Agricultural Water Management
      Citation Excerpt :

      This coherence implies that whenever nitrate concentrations are high, part of the contaminated groundwater is discharged directly to the ditch via the tile drains, thus bypassing the buffer strip. The higher nitrate concentrations observed in the tile-drain compared with the ditch at the study site (Tiemeyer et al., 2008) are the consequence. A long-term accumulation of nitrogen in the study site’s soil, which is available for leaching, is indicated by the field nitrogen balance (Tiemeyer et al., 2006).

    View all citing articles on Scopus
    View full text