Review of the recent developments in cellulose nanocomposite processing

https://doi.org/10.1016/j.compositesa.2015.10.041Get rights and content
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Abstract

This review addresses the recent developments of the processing of cellulose nanocomposites, focusing on the most used techniques, including solution casting, melt-processing of thermoplastic cellulose nanocomposites and resin impregnation of cellulose nanopapers using thermoset resins. Important techniques, such as partially dissolved cellulose nanocomposites, nanocomposite foams reinforced with nanocellulose, as well as long continuous fibers or filaments, are also addressed. It is shown how the research on cellulose nanocomposites has rapidly increased during the last 10 years, and manufacturing techniques have been developed from simple casting to these more sophisticated methods. To produce cellulose nanocomposites for commercial use, the processing of these materials must be developed from laboratory to industrially viable methods.

Abbreviations

A-CNC
acetylated cellulose nanocrystals
AFM
atomic force microscopy
BC
bacterial cellulose
CA
cellulose acetate
CAB
cellulose acetate butyrate
CMC
carboxymethyl cellulose
CNC
cellulose nanocrystals and cellulose nanowhiskers
CNF
cellulose nanofibers and nanofibrillated cellulose and microfibrillated cellulose
B-CNC
tert-butanol cellulose nanocrystals
DMAc
dimethylacetamide
EP
epoxy
GO
graphene oxide
GMA
glycidyl methacrylate
GTA
glycerol triacetate
HPC
hydroxypropyl cellulose
IL
ionic liquid
LDPE
low density polyethylene
LiCl
lithium chloride
LPEG
linear unsaturated polycondensate (oxyethylene)
MAPP
maleated polypropylene
MCC
micro crystalline cellulose
MF
melamine formaldehyde
NR
natural rubber
PA6
polyamide
PCL
polycaprolactone, PE, polyethylene
PF
phenol formaldehyde
PAH
polyallylamine hydrochloride
PAN
polyacrylonitrile
PANI
polyaniline
PDMS
polydimethyl siloxane
PEDOT
poly(3,4-ethylenedioxythiophene)
PHBV
polyhydroxy butyrate hydroxy valerate
PHO
poly-b-hydroxyoxanoate
PLA
polylactic acid
PP
polypropylene
PS
polystyrene sulfonic acid
PTFE
polytetrafluoroethylene
PVA
polyvinyl alcohol
PVAc
polyvinyl acetate
PVOH
polyvinyl alcohol
PU
polyurethane
SEM
scanning electron microscopy
S-MA
styrene maleic anhydride copolymer
THF
tetrahydrofuran
TS
thermoplastic starch
TEC
triethylene citrate
TEM
transmission electron microscopy
TOC
tempo oxidized cellulose
WF
wood fibers

Keywords

A. Cellulose
Nanocomposites
E. Casting
Extrusion
Liquid composite molding
Spinning

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