Invited reviewSpectral remote sensing for onshore seepage characterization: A critical overview
Introduction
A large portion of hydrocarbon (HC) traps is not perfectly sealed and thus, their accumulations leak to the surface over time. When the surface manifestation of oil and gas is clearly visible by naked eye, it is termed as macroseepage, whereas the traces of invisible light HCs in near-surface soils and sedimentary rocks (sediments henceforth), which are only detectable by analytical methods and careful geochemical sampling, is called microseepage (Horvitz, 1985, Tedesco, 1995). Historically, seepage and HC accumulations have been tied together and, as a result, a large number of the world's oil and gas fields have been explored by drilling in the immediate area of a seep (Hunt, 1996, Yergin, 1992). In modern exploration programs, macroseeps are typically regarded as direct clues for the existence of mature source rock(s) and a compelling evidence for the formation of a petroleum system in a given sedimentary basin (Magoon and Beaumont, 1999, Schumacher, 2010), whereas microseeps, which are argued to occur in a near vertical fashion over accumulations, are employed as a targeting tool for petroleum exploration.
Recent investigations have also revealed that seeps are a potent source of methane (with ethane and propane) greenhouse gasses to the atmosphere. It has been estimated that in the natural methane budget, seeps are the second most important source of emissions after wetlands. The estimates also reveal that onshore seepages are a more significant emitter of CH4 than their offshore counterparts (Etiope, 2015, Etiope and Ciccioli, 2009, Etiope and Klusman, 2010, Etiope et al., 2008).
Over the years, a diverse range of techniques, including remote sensing, has been employed for detecting the indications of seepage systems. The remote sensing approach holds a great promise for this aim because it is a fast and cost-effective tool that can be applied to different operational scales for both direct and indirect seepage mapping. In the marine environment, this technology already provides a variety of sensing methods comprising laser florescence, synthetic aperture radar (SAR), and thermal infrared, to name a few (Leifer et al., 2012a). Terrestrial seepage detection, however, has relied heavily on spectral data collected by multi-, and hyperspectral instruments in the visible-near infrared (VNIR; 0.4–1.0 μm), the short-wave infrared (SWIR; 1.0–2.5 μm), and very occasionally in the longwave infrared (LWIR; 8–14 μm) wavelengths. This methodology has been employed to detect oil and gas seeps in a direct manner and the footprints of HC leakage in sediments indirectly.
Whereas direct detection of HCs is a new research topic conducted mainly by airborne imaging spectroscopy, indirect HC prospecting commenced with the launch of the first Landsat multispectral scanner (ERTS) nearly four decades ago (Simpson, 1978). The advent of the hazy anomaly over some productive/prospective fields derived from Landsat imagery was simultaneous to a renewed interest in microseepage concept (Donovan, 1974) and thereupon led onto several research studies, including a NASA-Geosat joint project, to evaluate the use of satellite technology for HC prospecting (Abrams et al., 1985). Since then, sporadic case studies have appeared in the literature demonstrating the potentials and premises of the approach for oil and gas exploration (see van Der Meer et al. (2002) and Yang et al. (2000) and references therein), albeit in comparison to extensively studied offshore cases are almost negligible (Fingas and Brown, 2014, Leifer et al., 2012a).
Despite all the merits of spectral remote sensing, the technique does not yet hold a good place among unconventional exploration methods for oil and gas resources nor does it acknowledged as a mature exploration tool by explorationists. In this article, we set out to discover the full potential of this state-of-the-art technology for seepage characterization and understand the reasons for which the approach is underutilized by the petroleum industry. To fulfill this aim, we provide a systematic and critical overview of the subject based on well-described and reliable remote sensing case studies reported in the literature and thereupon attempt to address methodological shortcomings and inadequacies in data gathering, processing, and interpretations. In addition, we go through the seminal papers published on microseepage theory and interrelated geochemical and geophysical techniques from a remote sensing standpoint to enrich the discussion and highlight the unexplored capabilities of the technique in accomplishing the objectives of the exploration sector. We also attempt to engage the attention of the community to useful case studies conducted over exhumed HC reservoirs as an analogy to depleted reservoirs. In the case of direct seepage detection, we review the few present case studies and contrast them with the findings of interrelated disciplines to underline a wide range of possibilities from spectral products. Lastly, we accentuate the uncertainties about the role of natural seepage in greenhouse gas emission and the possible strategies to reduce it. This paper benefits from illustrative products generated over two case studies located in the Ventura Basin, California, USA and the Tucano Basin in the Bahia state, Brazil known to host distinctive macro-, and microseepage systems, respectively.
Section snippets
Petroleum seepage
Surface manifestation of oil and gas can be divided into two broad categories namely macro- and microseepage (Fig. 1). Macroseepage is the surface expression of a leakage pathway, typically related to tectonic discontinuities, along which natural liquid or gaseous HCs is (has been) flowing from subsurface source(s) (Clarke and Cleverly, 1991, Link, 1952, Macgregor, 1993). Microseepage, in contrast, refers to the slow, invisible, but pervasive migration of light alkanes (C1–C5) and volatiles
Spectroscopy of petroleum
A number of structural bonds in petroleum including CH, CH2, CH3, and C C give rise to several fundamental absorption bands between 3000 and 9000 nm wavelengths (Cloutis, 1989, Coates, 2006, Lammoglia and Souza Filho, 2011) (Table 2). Within the VNIR–SWIR window, petroleum also retains a series of absorption bands due to overtones and combinations of stretching fundamentals. The most notable feature in this range includes a triplet between 1700 and 1750 nm and a doublet between 2290 and 2360 nm (
Microseepage remote sensing
Because the majority of the microseepage-induced mineralogical assemblages (Section 2.2) show diagnostic spectral features within VNIR–SWIR wavelengths (Hunt, 1977), they have been the focus of several remote sensing investigations. In this section we firstly attempt to overview the case studies available on the subject and then summarize some of the closely related surveys on exhumed HC reservoirs.
Demonstration datasets
Within this article, examples of remote sensing data over two study areas with distinctive macro-, and microseepage systems are presented as illustrative products. The first area located in the Ventura Basin (CA, USA) hosts a typical oil seepage system (e.g. Ellis et al., 2001, Prelat et al., 2013, van Der Meer et al., 2002) among outcrops of sandstone, conglomerate, mudstone, and shale units belonging to Pico, Sisquoc, and Monterey Formations (Fig. 5b). The data covering this test site were
Direct sensing methods
The capability of remote sensing to detect and map oil and gas seeps can be used to: (i) screen frontier basins for any seepage manifestations, (ii) record the size, type, and possibly the likely replenishment of a leakage; (iii) update/map the seepage activity in mature/productive basins; (iv) assess the instant and long-term flux of the known seeps; and (v) compile global thematic databases for natural HC seeps.
Gas-plume sensing capability depends heavily on the seepage flux, wind speed, the
Seepages and the environment
Although seeps have been a topic of concern to explorationists for a long time, until recently, there was little understanding of their role in carbon emission to the atmosphere. Based on recent assessments, macro-, and microseeps in total constitute the second most important sources of natural methane (and also ethane/propane) emissions to the air (Etiope and Ciccioli, 2009, Etiope and Klusman, 2010, Etiope et al., 2008). It has been estimated that between 21 and 36% of the geologic methane
Conclusion
Whereas oil production from offshore basins is rapidly growing, in terms of yet-to-find reserves, it has been estimated that around half of the world's total conventional oil would still come from onshore basins, of which about half is expected to be new discoveries (USGS, 2000, Schenk, 2012). The macro-, and microseepage systems associated with these unexplored (and explored) onshore accumulations have been proven to contribute substantially towards natural methane emission and global warming.
Acknowledgement
We are thankful to Edward Cloutis (University of Winnipeg) and Celio Pasquini (University of Campinas) for their helpful discussion on petroleum spectroscopy. Rosa E. Pabón is acknowledged for providing the petroleum spectrum used for spectral deconvolution. We also appreciate the USGS and NASA for facilitating our access to the datasets used in the demonstration case studies. The authors would like to thank FAPESP for the research grant No. 2015/06663-7. C. R. Souza Filho thanks CNPq for
References (181)
Significance of hydrocarbon seepage relative to petroleum generation and entrapment
Mar. Pet. Geol.
(2005)- et al.
Investigating the capability of WorldView-3 superspectral data for direct hydrocarbon detection
Remote Sens. Environ.
(2016) - et al.
A review on spectral processing methods for geological remote sensing
Int. J. Appl. Earth Obs. Geoinf.
(2016) - et al.
Imaging spectroscopy of jarosite cement in the Jurassic Navajo Sandstone
Remote Sens. Environ.
(2010) - et al.
Development of a hybrid proximal sensing method for rapid identification of petroleum contaminated soils
Sci. Total Environ.
(2015) - et al.
Characterization of minerals in oil sands by reflectance spectroscopy
(1995) - et al.
Spectroscopic characterization of red latosols contaminated by petroleum-hydrocarbon and empirical model to estimate pollutant content and type
Remote Sens. Environ.
(2016) - et al.
Microseepage in drylands: flux and implications in the global atmospheric source/sink budget of methane
Glob. Planet. Chang.
(2010) - et al.
Migration of carrier and trace gases in the geosphere: an overview
Phys. Earth Planet. Inter.
(2002) - et al.
Diagenetic alteration of Permian strata at oil fields of south central Oklahoma, USA
Mar. Pet. Geol.
(1995)
Spectroscopic remote sensing of the distribution and persistence of oil from the Deepwater Horizon spill in Barataria Bay marshes
Remote Sens. Environ.
Spectroscopic characterization of oils yielded from Brazilian offshore basins: potential applications of remote sensing
Remote Sens. Environ.
Mapping and characterization of the API gravity of offshore hydrocarbon seepages using multispectral ASTER data
Remote Sens. Environ.
State of the art satellite and airborne marine oil spill remote sensing: application to the BP Deepwater Horizon oil spill
Remote Sens. Environ.
Remote bitumen content estimation of Athabasca oil sand from hyperspectral infrared reflectance spectra using Gaussian singlets and derivative of Gaussian wavelets
Fuel
Relationships between seepage, tectonics and subsurface petroleum reserves
Mar. Pet. Geol.
The Joint NASA/Geosat Test Case Project: Final Report
Spectral and Mineralogical Characterisation of Alteration Associated With Hydrocarbon Seepage Using Geoscan AMSS MKII Data Over Palm Valley Thirteenth International Conference and Workshops on Applied Geologic Remote Sensing
Hydrocarbon-induced diagenetic aureoles: indicators of deeper, leaky reservoirs
Association of Petroleum Geochemical Explorationists Bulletin
Remote detection of a tonal anomaly in an area of hydrocarbon microseepage, Tucano basin, north-eastern Brazil
Int. J. Remote Sens.
Terrain characteristics of a tonal anomaly remotely detected in an area of hydrocarbon microseepage, Tucano Basin, north-eastern Brazil
Int. J. Remote Sens.
Using gas chimneys as an exploration tool
World Oil
Determination of saturate, aromatic, resin, and asphaltenic (SARA) components in crude oils by means of infrared and near-infrared spectroscopy
Energy Fuel
Application of X-band radar to sense hydrocarbon seepage
Oil Gas J.
Drilling confirms radar-mapped atmospheric seepage anomalies
Oil Gas J.
Science behind sensing hydrocarbon seepage using X-band radar
Oil Gas J.
Bleaching of Jurassic Navajo sandstone on Colorado Plateau Laramide highs: evidence of exhumed hydrocarbon supergiants?
Geology
Fingerprints of fluid flow: chemical diagenetic history of the Jurassic Navajo Sandstone, Southern Utah, U.S.A
J. Sediment. Res.
Petrology of Sedimentary Rocks
Reflectance spectroscopic mapping of diagenetic heterogeneities and fluid-flow pathways in the Jurassic Navajo Sandstone
AAPG Bull.
Detection of marine methane emissions with AVIRIS band ratios
Geophys. Res. Lett.
Evaluation of possible gas microseepage mechanisms
AAPG Bull.
How 12 geochemical methods fared in GERT project in Permian
Oil Gas J.
Rapid identification of oil-contaminated soils using visible near-infrared diffuse reflectance spectroscopy
J. Environ. Qual.
Diagenetic hematite and manganese oxides and fault-related fluid flow in Jurassic sandstones, southeastern Utah
AAPG Bull.
Hydrocarbon micro-seepage detection by altered minerals mapping from airborne hyper-spectral data in Xifeng Oilfield, China
J. Earth Sci.
Reflectance spectroscopy of organic compounds: 1. Alkanes
Journal of Geophysical Research: Planets
A method for quantitative mapping of thick oil spills using imaging spectroscopy
Petroleum seepage and post-accumulation migration
Geol. Soc. Lond., Spec. Publ.
Spectral reflectance properties of hydrocarbons: remote-sensing implications
Science
Identification, detection and characterization of individual tar sand phases using diffuse reflectance spectroscopy (0.35–2.6 μm)
AOSTRA Journal of Research
Interpretation of Infrared Spectra, A Practical Approach, Encyclopedia of Analytical Chemistry
Detection of subsurface hydrocarbon seepage in seismic data: implications for charge, seal, overpressure, and gas-hydrate assessment
Spectral reflectance properties (0.4–2.5 μm) of secondary Fe-oxide, Fe-hydroxide, and Fe-sulphate-hydrate minerals associated with sulphide-bearing mine wastes
Geochemistry: Exploration, Environment, Analysis
Strategies for detecting hydrocarbon microseepages using airborne geophysics integrated with remote sensing data
Evolution of scientific surface geochemical exploration
Oil Gas J.
Remote sensing and petroleum seepage: a review and case study
Terra Nova
Petroleum microseepage at cement, Oklahoma; evidence and mechanism
AAPG Bull.
Recognition of petroleum-bearing traps by unusual isotopic compositions of carbonate-cemented surface rocks
Geology
A possible petroleum related geochemical anomaly in surface rocks
Cited by (65)
A rapid approach to evaluating ground surface conditions for shale gas extraction in mountainous areas
2023, Gas Science and EngineeringDetecting hydrocarbon micro-seepage and related contamination, probable prospect areas, deduced from a comparative analysis of multispectral and hyperspectral satellite images
2022, Journal of King Saud University - ScienceA multi-temporal method for detection of underground natural gas leakage using hyperspectral imaging
2022, International Journal of Greenhouse Gas ControlUAV-based remote sensing for the petroleum industry and environmental monitoring: State-of-the-art and perspectives
2022, Journal of Petroleum Science and EngineeringCitation Excerpt :A practical solution could be to use a combination of OGI and laser-based systems onboard drones for gas emission detection and quantification (Al-Walaie et al., 2021). The hyperspectral imaging systems onboard airplanes are shown to detect methane plumes at the level of 4–5 kg/h in the LWIR, and of 2–5 kg/h in the SWIR spectral range (see (Asadzadeh and Souza Filho, 2017) and references therein). In a ground-based setting, hyperspectral thermal imaging is demonstrated capable of detecting and quantifying methane fluxes at the flow rate of 0.023 kg/h in controlled release experiments (Gålfalk et al., 2015).