Elsevier

Earth-Science Reviews

Volume 168, May 2017, Pages 48-72
Earth-Science Reviews

Invited review
Spectral remote sensing for onshore seepage characterization: A critical overview

https://doi.org/10.1016/j.earscirev.2017.03.004Get rights and content

Abstract

In this article, we overview the application of spectral remote sensing data collected by multi-, and hyperspectral instruments in the visible-near infrared (VNIR), short-wave infrared (SWIR), and longwave infrared (LWIR) wavelengths for characterization of seepage systems as an exploration indicator of subsurface hydrocarbon (HC) accumulations. Two seepage systems namely macro-, and microseepage are recognized. A macroseepage is defined as visible indications of oil and gas on the surface and in the air detectable directly by a remote sensing approach. A microseepage is defined as invisible traces of light HCs in soils and sediments that are detectable by its secondary footprints in the strata, hence an indirect remote sensing target. Based on these broad categories, firstly, a comprehensive set of well-described and reliable remote sensing case studies available in the literature are thoroughly reviewed and then systematically assessed as regards the methodological shortcomings and scantiness in data gathering, processing, and interpretation. The work subsequently attempts to go through seminal papers published on microseepage concept and interrelated geochemical and geophysical techniques, exhumed HC reservoirs, lab-based spectroscopic analysis of petroleum and other related disciplines from a remote sensing standpoint. The aim is to enrich the discussion and highlight the still unexplored capabilities of this technique in accomplishing exploration objectives using the concept of seepage system. Aspects of seepage phenomenon in environmental pollution and uncertainties associated with their role in global warming are also underlined. This work benefits from illustrative products generated over two study areas located in the Ventura Basin, State of California, USA and the Tucano Basin, State of Bahia, Brazil known to host distinctive macro-, and microseepage systems, respectively. In conclusion, we recommend further research over a diverse range of seepage systems and advocate for a mature conceptual model for microseepage phenomenon.

Introduction

A large portion of hydrocarbon (HC) traps is not perfectly sealed and thus, their accumulations leak to the surface over time. When the surface manifestation of oil and gas is clearly visible by naked eye, it is termed as macroseepage, whereas the traces of invisible light HCs in near-surface soils and sedimentary rocks (sediments henceforth), which are only detectable by analytical methods and careful geochemical sampling, is called microseepage (Horvitz, 1985, Tedesco, 1995). Historically, seepage and HC accumulations have been tied together and, as a result, a large number of the world's oil and gas fields have been explored by drilling in the immediate area of a seep (Hunt, 1996, Yergin, 1992). In modern exploration programs, macroseeps are typically regarded as direct clues for the existence of mature source rock(s) and a compelling evidence for the formation of a petroleum system in a given sedimentary basin (Magoon and Beaumont, 1999, Schumacher, 2010), whereas microseeps, which are argued to occur in a near vertical fashion over accumulations, are employed as a targeting tool for petroleum exploration.

Recent investigations have also revealed that seeps are a potent source of methane (with ethane and propane) greenhouse gasses to the atmosphere. It has been estimated that in the natural methane budget, seeps are the second most important source of emissions after wetlands. The estimates also reveal that onshore seepages are a more significant emitter of CH4 than their offshore counterparts (Etiope, 2015, Etiope and Ciccioli, 2009, Etiope and Klusman, 2010, Etiope et al., 2008).

Over the years, a diverse range of techniques, including remote sensing, has been employed for detecting the indications of seepage systems. The remote sensing approach holds a great promise for this aim because it is a fast and cost-effective tool that can be applied to different operational scales for both direct and indirect seepage mapping. In the marine environment, this technology already provides a variety of sensing methods comprising laser florescence, synthetic aperture radar (SAR), and thermal infrared, to name a few (Leifer et al., 2012a). Terrestrial seepage detection, however, has relied heavily on spectral data collected by multi-, and hyperspectral instruments in the visible-near infrared (VNIR; 0.4–1.0 μm), the short-wave infrared (SWIR; 1.0–2.5 μm), and very occasionally in the longwave infrared (LWIR; 8–14 μm) wavelengths. This methodology has been employed to detect oil and gas seeps in a direct manner and the footprints of HC leakage in sediments indirectly.

Whereas direct detection of HCs is a new research topic conducted mainly by airborne imaging spectroscopy, indirect HC prospecting commenced with the launch of the first Landsat multispectral scanner (ERTS) nearly four decades ago (Simpson, 1978). The advent of the hazy anomaly over some productive/prospective fields derived from Landsat imagery was simultaneous to a renewed interest in microseepage concept (Donovan, 1974) and thereupon led onto several research studies, including a NASA-Geosat joint project, to evaluate the use of satellite technology for HC prospecting (Abrams et al., 1985). Since then, sporadic case studies have appeared in the literature demonstrating the potentials and premises of the approach for oil and gas exploration (see van Der Meer et al. (2002) and Yang et al. (2000) and references therein), albeit in comparison to extensively studied offshore cases are almost negligible (Fingas and Brown, 2014, Leifer et al., 2012a).

Despite all the merits of spectral remote sensing, the technique does not yet hold a good place among unconventional exploration methods for oil and gas resources nor does it acknowledged as a mature exploration tool by explorationists. In this article, we set out to discover the full potential of this state-of-the-art technology for seepage characterization and understand the reasons for which the approach is underutilized by the petroleum industry. To fulfill this aim, we provide a systematic and critical overview of the subject based on well-described and reliable remote sensing case studies reported in the literature and thereupon attempt to address methodological shortcomings and inadequacies in data gathering, processing, and interpretations. In addition, we go through the seminal papers published on microseepage theory and interrelated geochemical and geophysical techniques from a remote sensing standpoint to enrich the discussion and highlight the unexplored capabilities of the technique in accomplishing the objectives of the exploration sector. We also attempt to engage the attention of the community to useful case studies conducted over exhumed HC reservoirs as an analogy to depleted reservoirs. In the case of direct seepage detection, we review the few present case studies and contrast them with the findings of interrelated disciplines to underline a wide range of possibilities from spectral products. Lastly, we accentuate the uncertainties about the role of natural seepage in greenhouse gas emission and the possible strategies to reduce it. This paper benefits from illustrative products generated over two case studies located in the Ventura Basin, California, USA and the Tucano Basin in the Bahia state, Brazil known to host distinctive macro-, and microseepage systems, respectively.

Section snippets

Petroleum seepage

Surface manifestation of oil and gas can be divided into two broad categories namely macro- and microseepage (Fig. 1). Macroseepage is the surface expression of a leakage pathway, typically related to tectonic discontinuities, along which natural liquid or gaseous HCs is (has been) flowing from subsurface source(s) (Clarke and Cleverly, 1991, Link, 1952, Macgregor, 1993). Microseepage, in contrast, refers to the slow, invisible, but pervasive migration of light alkanes (C1–C5) and volatiles

Spectroscopy of petroleum

A number of structural bonds in petroleum including CH, CH2, CH3, and C double bond C give rise to several fundamental absorption bands between 3000 and 9000 nm wavelengths (Cloutis, 1989, Coates, 2006, Lammoglia and Souza Filho, 2011) (Table 2). Within the VNIR–SWIR window, petroleum also retains a series of absorption bands due to overtones and combinations of stretching fundamentals. The most notable feature in this range includes a triplet between 1700 and 1750 nm and a doublet between 2290 and 2360 nm (

Microseepage remote sensing

Because the majority of the microseepage-induced mineralogical assemblages (Section 2.2) show diagnostic spectral features within VNIR–SWIR wavelengths (Hunt, 1977), they have been the focus of several remote sensing investigations. In this section we firstly attempt to overview the case studies available on the subject and then summarize some of the closely related surveys on exhumed HC reservoirs.

Demonstration datasets

Within this article, examples of remote sensing data over two study areas with distinctive macro-, and microseepage systems are presented as illustrative products. The first area located in the Ventura Basin (CA, USA) hosts a typical oil seepage system (e.g. Ellis et al., 2001, Prelat et al., 2013, van Der Meer et al., 2002) among outcrops of sandstone, conglomerate, mudstone, and shale units belonging to Pico, Sisquoc, and Monterey Formations (Fig. 5b). The data covering this test site were

Direct sensing methods

The capability of remote sensing to detect and map oil and gas seeps can be used to: (i) screen frontier basins for any seepage manifestations, (ii) record the size, type, and possibly the likely replenishment of a leakage; (iii) update/map the seepage activity in mature/productive basins; (iv) assess the instant and long-term flux of the known seeps; and (v) compile global thematic databases for natural HC seeps.

Gas-plume sensing capability depends heavily on the seepage flux, wind speed, the

Seepages and the environment

Although seeps have been a topic of concern to explorationists for a long time, until recently, there was little understanding of their role in carbon emission to the atmosphere. Based on recent assessments, macro-, and microseeps in total constitute the second most important sources of natural methane (and also ethane/propane) emissions to the air (Etiope and Ciccioli, 2009, Etiope and Klusman, 2010, Etiope et al., 2008). It has been estimated that between 21 and 36% of the geologic methane

Conclusion

Whereas oil production from offshore basins is rapidly growing, in terms of yet-to-find reserves, it has been estimated that around half of the world's total conventional oil would still come from onshore basins, of which about half is expected to be new discoveries (USGS, 2000, Schenk, 2012). The macro-, and microseepage systems associated with these unexplored (and explored) onshore accumulations have been proven to contribute substantially towards natural methane emission and global warming.

Acknowledgement

We are thankful to Edward Cloutis (University of Winnipeg) and Celio Pasquini (University of Campinas) for their helpful discussion on petroleum spectroscopy. Rosa E. Pabón is acknowledged for providing the petroleum spectrum used for spectral deconvolution. We also appreciate the USGS and NASA for facilitating our access to the datasets used in the demonstration case studies. The authors would like to thank FAPESP for the research grant No. 2015/06663-7. C. R. Souza Filho thanks CNPq for

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