Spatial variability of submarine groundwater discharge, Ubatuba, Brazil

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Abstract

Submarine groundwater discharge (SGD) is delivered into the oceans at various hydrogeological settings. Where coastal aquifers have spatial heterogeneous properties such as preferential flowpaths, SGD is also commonly heterogeneously distributed along the coast. SGD from a heterogeneous, fractured rock aquifer on the Ubatuba coast, Brazil has been investigated by depth profiling of ground conductivity. On spatial scales of <10 m, a significant variation in sub-surface conductivity and associated discharge rate is documented. These geophysical observations were used to identify preferential flowpaths, and to explain significant differences in average discharge rates observed in seepage meter records placed only a few metres apart from each other. This paper illustrates the utility of sub-surface conductivity measurements for accurate investigations of SGD fluxes.

Introduction

Rivers are obvious and visible pathways for terrestrial runoff. In contrast, submarine groundwater discharge (SGD) is a poorly understood process hidden from view. Moreover, SGD as a source of freshwater and dissolved constituents is the least studied element of water, salt and nutrient budgets of the coastal oceans (e.g. Zektser, 2000). According to Johannes (1980), “SGD should occur anywhere that an aquifer is hydraulically connected with the sea through permeable rocks or bottom sediments and where the [density-corrected] head is above sea level”. These conditions are met in many, if not most coastal areas. Surprisingly, SGD has only recently been a focus of research, particularly where human activities at the coast might influence sensitive marine environments. Within the coastal plain and seafloor sediments, a complex mixing zone of freshwater and seawater exists. This zone has been termed a “subterranean estuary” (Moore, 1999), in recognition of the similarities of the physical and chemical processes occurring in such interfaces and surface estuaries.

A prime reason for the lack of scientific understanding of SGD is the logistical complications of measuring a subterranean flux of water at the coastal interface. Parallel to hydrological modelling, various experimental methods have been developed in recent years. Direct flux measurements are commonly obtained with benthic chambers or seepage meters deployed on the seafloor, based on a design by Lee (1977). In such studies, total fluxes are inferred by multiplying direct point measurements of flux per unit area with the total expected discharge area. Indirect water-borne tracer approaches estimate groundwater fluxes integrated along a coastline, whereby a mass balance for a tracer is closed (e.g. Burnett et al., 2002). Commonly used natural tracers are Radon, Radium, nutrients and trace elements, and occasionally, injected tracers such as SF6 are used (Clark and Stieglitz, in press). Where flow paths are simple and flow patterns homogenous, directly and indirectly measured total flow rates compare well with modelled total flow (Burnett et al., 2002). However, where aquifer confinement or preferential flow paths exist, care has to be taken with inferring total fluxes from direct point measurements of SGD fluxes. In such cases, spatial variability of SGD could be significant, and therefore, a more detailed understanding of the spatial distribution of fresh and saltwater fluxes across the sediment-water interface is required to more accurately estimate total flow rates. Here we demonstrate the utility of a simple geoelectric method to identify spatial heterogeneity and preferential flow paths.

As part of an initiative developed by the International Atomic Energy Agency (IAEA) and UNESCO to assess methodologies and importance of SGD for coastal zone management, multidisciplinary studies of SGD were carried out in various hydrogeological settings, i.e. coastal plain aquifers in Western Australia, glacial aquifers on Long Island (USA), karstic aquifers in Sicily, fractured rock aquifers in Ubatuba, Brazil and lava tube aquifers on the island of Mauritius (e.g. Burnett et al., 2006). In order to characterise the spatial distribution of SGD at these study sites, the electrical conductivity of groundwater was mapped. Here we report geophysical investigations of the bulk ground conductivity at Ubatuba, Brazil carried out in November 2003, and discuss the utility of such quantitative investigations to improving flux estimates of SGD by conventional methods, e.g. with seepage meters.

Section snippets

Study area

The study area is situated at approximately 23.5° S latitude in the northern part of São Paulo Bight, southeastern Brazil (Fig. 1a). Numerous small bays comprised of Pleistocene and Holocene unconsolidated sediments consisting mainly of sands are separated from each other by headlands of outcropping pre-Cambrian basement rock of granitic and metamorphic origin, which are seaward-dipping. The headlands mark the seaward extension of the 1000-m high coastal mountain range Serra do Mar

Methods

In marine sediments, the electrical bulk ground conductivity, or its inverse resistivity, is a measure for how much (conducting) salt is present in the ground. This is a function of two variables: (a) porewater fraction and (b) porewater conductivity, which in turn is a function of porewater salinity and temperature. In the presented study, two principal standard geophysical methods were employed. The electrical properties of the beach sediments were investigated with in situ conductivity

Spatial variations of in situ bulk ground conductivity in Flamengo Bay

Contour plots of the interpolated distribution of conductivity of the beach sediments along the shore-normal transect, recorded at three different dates, are shown in Fig. 2. From stations 0 to 4, the sediment layer was only a few centimetres thick above bedrock, and thus no in situ profiles could be recorded. The slope of the beach and the tidal water level at the time of recording are shown, together with the average flux and salinity of SGD measured in seepage meters S1, S8 and S2 which were

Spatial heterogeneities of fresh SGD in Flamengo Bay: Conductivity considerations

Commonly, marine sediment saturated with water of conductivity C have a bulk ground conductivity reduced by a factor of 2 to 4 compared to C, resulting from the presence of non-conducting particles (Kermabon et al., 1969). Sediments with an apparent bulk ground conductivity of greater than 18 mS cm−1 can be assumed to be saturated with seawater because seawater has a typical conductivity of 55 mS cm−1. Similarly, sediments of similar type with a bulk ground conductivity of significantly less than 18

Conclusions

Geophysical investigations of the discharge zone can significantly contribute to the understanding of the hydrogeological and sedimentological setting of SGD, and thus help to explain the response of SGD to sedimentary heterogeneities and to driving forces. Sub-surface conductivity and resistivity investigations helped to identify the structure of the flow pattern and paths of the freshwater component of SGD to the coast at Flamengo Bay. Such measurements allow for predictions of ocean entry

Acknowledgements

Joselene de Oliveira (Instituto de Pesquisas Energéticas e Nucleares, University of Sao Paulo) is thanked for organising the experiments at Ubatuba, and for negotiating with Brazilian customs to make equipment available on time. Bill Burnett and Pavel Povinec carried out the bulk of the organisation of the IOC and IAEA working groups. June Oberdorfer helped with the collection of porewater salinity data. Support by and discussion with Henry Bokuniewicz and other members of the working group is

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