Challenges to improve confidence level of risk assessment of hydrogen technologies
Introduction
The perspectives for hydrogen as an energy carrier look great. The world feels a real need to reduce carbon dioxide emissions and to become less dependent on oil. There will be however a transition period of considerable duration in which perception of the hazards of hydrogen may develop one way or the other.
Hydrogen is not toxic, but its eagerness to combine with oxygen can turn into a hazard. Safety records of hydrogen processing in process industry are generally well. On the other hand, introduction of production, storage, transportation and use on the widespread scale required to replace present hydrocarbons will undoubtedly bring incidents. The large scale introduction will unavoidably bring many people in touch with the technology and standards of engineering are not everywhere at the high level of present day petrochemical complexes. The energy carrier is needed not only in industry districts but also in densely populated areas. So, in incidents people may become hurt. Experience shows that one large scale incident with fatalities can throw a new technology backwards for years. The psychological impact of risk, once shown somewhere to occur and witnessed by TV is difficult to erase. Old, misunderstood stories like the one on the Hindenburg will be remembered by the media after an accident happened and will add to fear. Such situation will be worsened if ‘experts’ contradict each other, express misbelieve in models or show uncertainty.
For adequate risk control it will pay to invest in reliable risk analysis methodology. It will help to improve operational safety by designing and installing preventive and protective measures where appropriate and economical, also embodied by standards and codes. Risk-informed standards form key to permitting hydrogen refueling stations [1]. In addition for the purpose of public safety risk analysis will help in land use planning, licensing of installations and emergency planning; the latter with respect to self rescue and effective deployment of emergency response units.
The HySafe community already has taken initiatives in drafting standards, educating and training people, performing risk studies and organizing three ICHS safety conferences. There have been numerous papers addressing an aspect of hydrogen risk but there are few attempts to perform overall risk assessments. The reports on risk assessment methods (DNV Research & Innovation, 2008 [2]), and risk studies on refueling stations e.g. IEA [3] and other facilities e.g. [4] are certainly a good step, but cannot be considered matured. Moreover, to remain critical remains necessary as quality standards for risk assessments have not become common yet. Below will be shown why vigilance is needed.
Section snippets
Risk analysis: strengths and weaknesses in general
Risk analysis of process and storage installations can be considered as a system analysis focused on defining failure scenarios with release of hazardous material. Each release will have consequences and a probability of occurrence. The release probability has to be derived from failure rates of equipment resulting in spill, the consequences are split into physical effects (severity) and damage (impact) to exposed ‘receptors’. For hydrogen the effects will be in first instance heat radiation of
Suggestions for risk analysis on hydrogen installations
Based on information published in conference papers, in particular those of the 3rd International Conference on Hydrogen Safety (ICHS-3) [15], in articles of this journal or elsewhere contributions have been made to improve and augment the expertise base to enable reliable risk assessments. A recent report by LaChance et al. [16] focused on risks of pressurized hydrogen leaks and ensuing jet flames in the setting of a refueling station which will represent a majority of incidents. This work
Conclusion
For a successful introduction of hydrogen it is crucial to control the risks and for that purpose to determine the risks with an acceptable level of confidence. Risk assessment starts with generating credible scenarios using historical data and applying structured thinking with event bowties or even more flexible with Bayesian belief nets. Uncertainty is a major stumbling block in risk analysis but it can strongly be reduced by agreeing on credible, situation specific scenarios, use of
Acknowledgement
The author acknowledges the support by Dr. M. Sam Mannan, director Mary Kay O’Connor Process Safety Center, to find continually ways to improve safety and to make it second nature.
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