Research paperAcoustic properties in travertines and their relation to porosity and pore types
Introduction
Carbonate deposits gained interest due to their potential as reservoir rocks, e.g. the supergiant fields in the Middle East (Nurmi and Standen, 1997) and offshore Brazil (Thompson and Oftebro, 2011, Wright, 2012). The genesis of continental carbonates is associated with physico-chemical and biological precipitation that largely influences the rock texture and petrophysical properties (Toumelin et al., 2003). This causes petrophysical heterogeneity that can become even more pronounced due to diagenetic overprinting (with cementation, dissolution, recrystallisation, dolomitisation, fracturing, etc.). The studied continental carbonates in Turkey and Hungary are calcareous spring deposits, i.e. travertines (Pentecost, 2005), associated with ambient and hydrothermal fluids (El Desouky et al., 2014, Sierralta et al., 2010). Their deposition is controlled by a complex interplay of physico-chemical, biological and hydrological factors, including CO2 degassing, the dominating process for travertine precipitation (Fouke, 2011, Guo and Riding, 1998, Kele et al., 2011, Özkul et al., 2013, Özkul et al., 2014, Pentecost, 2005). Travertines can form in a thin water film in sub-aerial conditions, or in lake, marsh and fluvial environments. These precipitates have been widely studied (Alonso-Zarza and Tanner, 2010, Ford and Pedley, 1996, Pedley and Rogerson, 2010, Pentecost, 2005), however, a detailed investigation of the rock petrophysics was seldom accomplished. This paper aims to investigate the behaviour of acoustic waves in travertines.
The dependency of sonic velocities on lithology, rock texture and fabric is the key to understand acoustic logs and seismic sections in sedimentary systems. Compressional-wave velocity and bulk density are used to calculate acoustic impedance. In carbonate lithologies that consist purely of calcite, grain density variations are limited, meaning that other parameters cause variations in body wave velocity. These parameters are of importance for the interpretation of seismic reflection and geophysical data. The control that is exhibited by porosity on acoustic velocity was already reported in the late fifties (Biot, 1956; Gassmann, 1951). Causes for velocity variations in pure carbonates were part of several studies especially from the early nineties onwards. It was concluded that not only porosity, but also the entire rock fabric and its texture are of importance (Anselmetti and Eberli, 1993, Wang et al., 1991). Moreover, carbonates are prone to diagenesis, which can easily alter porosity, crystal morphology, the rigidity of the solid framework, etc. (Anselmetti and Eberli, 1993, Braaksma et al., 2003, Verwer et al., 2008).
In this study, compressional-wave velocity (Vp) and shear-wave velocity (Vs) are measured on travertine samples from three different locations, under confining pressures that approach in situ subsurface conditions. Sonic velocity measurements were done in combination with petrography, X-Ray Diffraction (XRD) and micro-Computer Tomography (μCT) analyses.
Section snippets
Geological setting
The selected dataset of Quaternary travertines is assembled from quarries near Denizli, in Turkey (Özkul et al., 2013) and from Süttő (Bakacsi et al., 1994, Sierralta et al., 2010) and Budakalász (Kele et al., 2003) in Hungary.
The Denizli Basin (Western Turkey) is a Neogene-Quaternary depression, of 70 by 50 km. The basin is the continuation of the E–W-trending Büyük Menderes Graben and the NW–SE-trending Gediz Graben (Bozkurt and Bozkurt, 2009, Gürer and Yilmaz, 2002, Kele et al., 2011, Özkul
Methodology
The petrophysical measurements are conducted on sixty 1.5-inch (3.81 cm) diameter plugs. The effective porosity in the plugs is measured by means of helium expansion porosimetry. Gas permeability, in this case with nitrogen gas (N2), is measured in a steady state permeameter.
XRD analyses were conducted on 10 representative samples to confirm that travertines in Denizli and from Süttő and Budakalász are composed for well over 90% of calcite, as previously stated in several studies (Kele, 2009,
Mineralogy
The analysed travertines consist of over 94% of calcite. Next to the dominant carbonate mineralogy, a minor presence of quartz can be deduced. Except for quartz, small amounts of amorphous phases, organic matter and clays occur in some of the samples (Fig. 2). The amorphous phase cannot be analysed with XRD and the exact mineralogy of the minor quantities of clay minerals is beyond the scope of this study. Aragonite is observed in travertines around the world (Pentecost, 2005), but is absent in
Discussion
The travertines of this study exhibit large-scale ranges for both porosity and permeability. This is in line with expectations, given the petrographically observed (both on micro- and macroscale) heterogeneity of these limestones. The travertines in this study underwent a shallow burial history. The Vp/Vs ratio for all the samples varies between 1.8 and 2, which are values corresponding to indurated carbonates (Anselmetti and Eberli, 1993). This strongly suggests that artificial compaction was
Conclusion
The travertines in this study were subjected to a multi-technique approach (porosity, permeability, acoustic velocity and computer tomography analyses) that provides a more in depth understanding of these carbonates and their petrophysical properties.
Quaternary travertines from quarries in Denizli (Turkey) and from Süttő and Budakalász (Hungary) are petrophysically heterogeneous with porosities varying from 2.8 to 34.7% and permeabilities ranging between 0.05 and 18 000 mD. The heterogeneity
Acknowledgements
My thanks goes to the owners and managers of the Alimoğlu, Új Haraszti and Budakalász quarries, for providing us with the opportunity to work in actively excavated environments. I am grateful to Mr. Tuur Smekens and Mr. Mathieu Degros for their help during the field work in Hungary and for doing their part in the acoustic property analyses. I would like to thank Herman Nijs, for the preparation of the thin sections and his aid with practical matters during the sample preparation processes. The
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