ACS Publications. Most Trusted. Most Cited. Most Read

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Phys. Chem. A 2009, 113, 2, 411-416
RETURN TO ISSUEPREVArticleNEXT

Studies of the Kinetics of Two Parallel Reactions: Ammonia Decomposition and Nitriding of Iron Catalyst

View Author Information
Szczecin University of Technology, Institute of Chemical and Environment Engineering, Puaskiego 10, 70-322 Szczecin, Poland
* Corresponding author. Telephone: +48 91 449 47 30. Fax +48 91 449 46 86. E-mail address: [email protected]
Cite this: J. Phys. Chem. A 2009, 113, 2, 411–416
Publication Date (Web):December 16, 2008
https://doi.org/10.1021/jp8079759
Copyright © 2008 American Chemical Society
Request reuse permissions

    Article Views

    1631

    Altmetric

    -

    Citations

    36
    LEARN ABOUT THESE METRICS
    Other access options
    Get e-Alerts
    SUBJECTS:

    Abstract

    The reaction of ammonia decomposition and nitriding reaction as an example of the parallel reactions were studied. A surface reaction was assumed as the rate limiting step. The experiments were carried out in the range of temperatures from 623 to 723 K. Mixtures of different iron nitrides (γ′-Fe4N, ϵ-Fe3−2N) were obtained. Differential tubular reactor with thermogravimetric (TG) measurement and analysis of the gas phase composition in the reaction volume was used. Reacting gases flowing through the reactor were mixed. Effective reactor volume was determined. The rate constants for ammonia decomposition and ammonia adsorption process at critical point between α-Fe and γ′-Fe4N phases were estimated. The number of collisions and the sticking coefficient of ammonia over α-Fe phase were also assessed.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Cited By

    This article is cited by 36 publications.

    1. Genwei Chen, Jing Qu, Pohlee Cheah, Dongmei Cao, Yongfeng Zhao, Yizhi Xiang. Size-Dependent Activity of Iron Nanoparticles in Both Thermal and Plasma Driven Catalytic Ammonia Decomposition. Industrial & Engineering Chemistry Research 2022, 61 (31) , 11436-11443. https://doi.org/10.1021/acs.iecr.2c02092
    2. Walerian Arabczyk, Rafał Pelka, Ireneusz Kocemba, Agnieszka Brzoza-Kos, Andrzej Wyszkowski, Zofia Lendzion-Bieluń. Study of Phase Transformation Processes Occurring in the Nanocrystalline Iron/Ammonia/Hydrogen System by the Magnetic Permeability Measurement Method. The Journal of Physical Chemistry C 2022, 126 (17) , 7704-7710. https://doi.org/10.1021/acs.jpcc.2c00807
    3. Ilaria Lucentini, Xènia Garcia, Xavier Vendrell, Jordi Llorca. Review of the Decomposition of Ammonia to Generate Hydrogen. Industrial & Engineering Chemistry Research 2021, 60 (51) , 18560-18611. https://doi.org/10.1021/acs.iecr.1c00843
    4. Huijeong Hwang, Taehyun Kim, Hyunchae Cynn, Thomas Vogt, Rachel J. Husband, Karen Appel, Carsten Baehtz, Orianna B. Ball, Marzena A. Baron, Richard Briggs, Maxim Bykov, Elena Bykova, Valerio Cerantola, Julien Chantel, Amy L. Coleman, Dana Dattlebaum, Leora E. Dresselhaus-Marais, Jon H. Eggert, Lars Ehm, William J. Evans, Guillaume Fiquet, Mungo Frost, Konstantin Glazyrin, Alexander F. Goncharov, Zsolt Jenei, Jaeyong Kim, Zuzana Konôpková, Jona Mainberger, Mikako Makita, Hauke Marquardt, Emma E. McBride, James D. McHardy, Sébastien Merkel, Guillaume Morard, Earl F. O’Bannon, III, Christoph Otzen, Edward J. Pace, Alexander Pelka, Charles M. Pépin, Jeffrey S. Pigott, Vitali B. Prakapenka, Clemens Prescher, Ronald Redmer, Sergio Speziale, Georg Spiekermann, Cornelius Strohm, Blake T. Sturtevant, Nenad Velisavljevic, Max Wilke, Choong-Shik Yoo, Ulf Zastrau, Hanns-Peter Liermann, Malcolm I. McMahon, R. Stewart McWilliams, Yongjae Lee. X-ray Free Electron Laser-Induced Synthesis of ε-Iron Nitride at High Pressures. The Journal of Physical Chemistry Letters 2021, 12 (12) , 3246-3252. https://doi.org/10.1021/acs.jpclett.1c00150
    5. Katarzyna Skulmowska, Rafał Pelka, and Walerian Arabczyk . Oscillatory Kinetics in the Process of Reduction of Nanocrystalline Iron Nitride γ′-Fe4N. The Journal of Physical Chemistry C 2017, 121 (27) , 14712-14716. https://doi.org/10.1021/acs.jpcc.7b04418
    6. Sayan Bhattacharyya . Iron Nitride Family at Reduced Dimensions: A Review of Their Synthesis Protocols and Structural and Magnetic Properties. The Journal of Physical Chemistry C 2015, 119 (4) , 1601-1622. https://doi.org/10.1021/jp510606z
    7. Rafał Pelka, Karolina Kiełbasa, and Walerian Arabczyk . Catalytic Ammonia Decomposition during Nanocrystalline Iron Nitriding at 475 °C with NH3/H2 Mixtures of Different Nitriding Potentials. The Journal of Physical Chemistry C 2014, 118 (12) , 6178-6185. https://doi.org/10.1021/jp4087283
    8. Daotong Liang, Chao Feng, Li Xu, Da Wang, Yuanshuai Liu, Xuebing Li, Zhong Wang. Promotion effects of different methods in CO x -free hydrogen production from ammonia decomposition. Catalysis Science & Technology 2023, 13 (12) , 3614-3628. https://doi.org/10.1039/D3CY00042G
    9. Petra Martinović, Lars Barnewitz, Markus Rohdenburg, Petra Swiderek. Controlling electron beam induced deposition of iron from Fe(CO)5: Inhibition of autocatalytic growth by NH3 and reactivation by electron irradiation. Journal of Vacuum Science & Technology A 2023, 41 (3) https://doi.org/10.1116/6.0002306
    10. Meng Du, Lingling Guo, Hongju Ren, Xin Tao, Yunan Li, Bing Nan, Rui Si, Chongqi Chen, Lina Li. Non-Noble FeCrOx Bimetallic Nanoparticles for Efficient NH3 Decomposition. Nanomaterials 2023, 13 (7) , 1280. https://doi.org/10.3390/nano13071280
    11. Stefan Peters, Ali M. Abdel‐Mageed, Sebastian Wohlrab. Thermocatalytic Ammonia Decomposition – Status and Current Research Demands for a Carbon‐Free Hydrogen Fuel Technology. ChemCatChem 2023, 15 (2) https://doi.org/10.1002/cctc.202201185
    12. Yuxin Pan, Hua Zhang, Kang Xu, Yucun Zhou, Bote Zhao, Wei Yuan, Kotaro Sasaki, YongMan Choi, Yu Chen, Meilin Liu. A high-performance and durable direct NH3 tubular protonic ceramic fuel cell integrated with an internal catalyst layer. Applied Catalysis B: Environmental 2022, 306 , 121071. https://doi.org/10.1016/j.apcatb.2022.121071
    13. Walerian Arabczyk, Katarzyna Skulmowska, Rafał Pelka, Zofia Lendzion-Bieluń. Oscillatory Mechanism of α-Fe(N) ↔ γ’-Fe4N Phase Transformations during Nanocrystalline Iron Nitriding. Materials 2022, 15 (3) , 1006. https://doi.org/10.3390/ma15031006
    14. Walerian Arabczyk, Rafał Pelka, Izabella Jasińska, Zofia Lendzion-Bieluń. Reaction Model Taking into Account the Catalyst Morphology and Its Active Specific Surface in the Process of Catalytic Ammonia Decomposition. Materials 2021, 14 (23) , 7229. https://doi.org/10.3390/ma14237229
    15. Zhijian Wan, Youkun Tao, Jing Shao, Yinghui Zhang, Hengzhi You. Ammonia as an effective hydrogen carrier and a clean fuel for solid oxide fuel cells. Energy Conversion and Management 2021, 228 , 113729. https://doi.org/10.1016/j.enconman.2020.113729
    16. Bin Ma, Jinming Liu, Guannan Guo, Jian-Ping Wang. Critical thickness of α″-Fe16N2 layer prepared in low-temperature nitriding. Journal of Applied Physics 2020, 128 (22) https://doi.org/10.1063/5.0033577
    17. Yongjie Liu, Yue Wang, Zhixiong You, Xuewei Lv. Reduction and Nitridation of Iron/Vanadium Oxides by Ammonia Gas: Mechanism and Preparation of FeV45N Alloy. Metals 2020, 10 (3) , 356. https://doi.org/10.3390/met10030356
    18. Seetharamulu Podila, Hafedh Driss, Sharif F. Zaman, Arshid M. Ali, Abdulrahim A. Al-Zahrani, Muhammad A. Daous, Lachezar A. Petrov. MgFe and Mg–Co–Fe mixed oxides derived from hydrotalcites: Highly efficient catalysts for COx free hydrogen production from NH3. International Journal of Hydrogen Energy 2020, 45 (1) , 873-890. https://doi.org/10.1016/j.ijhydene.2019.10.107
    19. Ireneusz Kocemba, Jacek Rynkowski, Walerian Arabczyk. The thermoelectric sensor for controlling the gas nitriding process. Sensors and Actuators A: Physical 2019, 288 , 144-148. https://doi.org/10.1016/j.sna.2019.02.005
    20. Yanhui Yi, Li Wang, Hongchen Guo. Plasma-Catalytic Decomposition of Ammonia for Hydrogen Energy. 2019, 181-230. https://doi.org/10.1007/978-3-030-05189-1_7
    21. Samira Fatma Kurtoğlu, Sezen Soyer-Uzun, Alper Uzun. Modifying the structure of red mud by simple treatments for high and stable performance in COx-free hydrogen production from ammonia. International Journal of Hydrogen Energy 2018, 43 (45) , 20525-20537. https://doi.org/10.1016/j.ijhydene.2018.09.032
    22. Jo‐Chi Tseng, Dong Gu, Claudio Pistidda, Christian Horstmann, Martin Dornheim, Jan Ternieden, Claudia Weidenthaler. Tracking the Active Catalyst for Iron‐Based Ammonia Decomposition by In Situ Synchrotron Diffraction Studies. ChemCatChem 2018, 10 (19) , 4465-4472. https://doi.org/10.1002/cctc.201800398
    23. Aydin Şelte, Burak Özkal, Koray Arslan, Sakine Ülker, Aziz Hatman. Effect of Nitriding on the Wear Resistance of Tool Powder Steels with Different Contents of V, Cr and Mo. Metal Science and Heat Treatment 2018, 59 (11-12) , 729-734. https://doi.org/10.1007/s11041-018-0218-1
    24. Ye Wu, Cheng Wen, Xiaoping Chen, Guodong Jiang, Guannan Liu, Dong Liu. Catalytic pyrolysis and gasification of waste textile under carbon dioxide atmosphere with composite Zn-Fe catalyst. Fuel Processing Technology 2017, 166 , 115-123. https://doi.org/10.1016/j.fuproc.2017.05.025
    25. Thomas J. Wood, Joshua W. Makepeace, William I. F. David. Neutron diffraction and gravimetric study of the iron nitriding reaction under ammonia decomposition conditions. Phys. Chem. Chem. Phys. 2017, 19 (40) , 27859-27865. https://doi.org/10.1039/C7CP04494A
    26. T. E. Bell, L. Torrente-Murciano. H2 Production via Ammonia Decomposition Using Non-Noble Metal Catalysts: A Review. Topics in Catalysis 2016, 59 (15-16) , 1438-1457. https://doi.org/10.1007/s11244-016-0653-4
    27. K. Rohith Vinod, P. Saravanan, M. Sakar, S. Balakumar. Insights into the nitridation of zero-valent iron nanoparticles for the facile synthesis of iron nitride nanoparticles. RSC Advances 2016, 6 (51) , 45850-45857. https://doi.org/10.1039/C6RA04935D
    28. Bo Wang, Wantang Fu, Fan Dong, Guofeng Jin, Weiwei Feng, Zhenhua Wang, Shuhua Sun. Significant acceleration of nitriding kinetics in pure iron by pressurized gas treatment. Materials & Design 2015, 85 , 91-96. https://doi.org/10.1016/j.matdes.2015.07.013
    29. Jian Ji, Xuezhi Duan, Gang Qian, Xinggui Zhou, Gangsheng Tong, Weikang Yuan. Towards an efficient CoMo/γ-Al 2 O 3 catalyst using metal amine metallate as an active phase precursor: Enhanced hydrogen production by ammonia decomposition. International Journal of Hydrogen Energy 2014, 39 (24) , 12490-12498. https://doi.org/10.1016/j.ijhydene.2014.06.081
    30. Jian Ji, Xuezhi Duan, Gang Qian, Ping Li, Xinggui Zhou, De Chen, Weikang Yuan. Fe particles on the tops of carbon nanofibers immobilized on structured carbon microfibers for ammonia decomposition. Catalysis Today 2013, 216 , 254-260. https://doi.org/10.1016/j.cattod.2013.06.008
    31. Xuezhi Duan, Xinggui Zhou, De Chen. Structural manipulation of the catalysts for ammonia decomposition. 2013, 118-140. https://doi.org/10.1039/9781849737203-00118
    32. Rafał Pelka, Walerian Arabczyk. A New Method for Determining the Nanocrystallite Size Distribution in Systems Where Chemical Reaction between Solid and a Gas Phase Occurs. Journal of Nanomaterials 2013, 2013 , 1-6. https://doi.org/10.1155/2013/645050
    33. F. Schüth, R. Palkovits, R. Schlögl, D. S. Su. Ammonia as a possible element in an energy infrastructure: catalysts for ammonia decomposition. Energy Environ. Sci. 2012, 5 (4) , 6278-6289. https://doi.org/10.1039/C2EE02865D
    34. Rafał Pelka, Karolina Kiełbasa, Walerian Arabczyk. The effect of iron nanocrystallites’ size in catalysts for ammonia synthesis on nitriding reaction and catalytic ammonia decomposition. Open Chemistry 2011, 9 (2) , 240-244. https://doi.org/10.2478/s11532-010-0145-5
    35. Mathias Feyen, Claudia Weidenthaler, Robert Güttel, Klaus Schlichte, Ulrich Holle, An‐Hui Lu, Ferdi Schüth. High‐Temperature Stable, Iron‐Based Core–Shell Catalysts for Ammonia Decomposition. Chemistry – A European Journal 2011, 17 (2) , 598-605. https://doi.org/10.1002/chem.201001827
    36. Jin-Quan Sun, Zi-Feng Yan, Hong-Zhi Cui, Jie Li, Ji-Sen Wang, Yun-Bo Chen. Surface catalysis gaseous nitriding of alloy cast iron at lower temperature. Catalysis Today 2010, 158 (3-4) , 205-208. https://doi.org/10.1016/j.cattod.2010.03.028
    Download PDF

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect