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Synthesis and Electrical Properties of Solid Solutions Based on Bismuth Vanadates

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Abstract

The phase-formation processes in the Bi2O3–V2O5 and Bi2O3–MO–V2O5 (M = Zn, Pb, Cu, Co, Ni) systems were investigated. The associated sequence of phase transformations and the conditions for preparing single-phase Bi4V2O11 (Bi2VO5.5) and Bi2V1 – x Me x O5.5 – 3x/2 solid solutions were established. The lattice parameters of the solid solutions were determined, and their conductivity was measured as a function of temperature and composition.

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Buyanova, E.S., Zhukovskii, V.M., Lopatina, E.S. et al. Synthesis and Electrical Properties of Solid Solutions Based on Bismuth Vanadates. Inorganic Materials 38, 256–260 (2002). https://doi.org/10.1023/A:1014722800626

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