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Application of zeolite titanium Beta in the rearrangement of α-pinene oxide to campholenic aldehyde

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Abstract

Zeolite titanium Beta is found to be an effective catalyst for the industrially relevant rearrangement of α-pinene oxide to campholenic aldehyde, giving selectivities of up to 89% in the liquid phase. In the gas phase, up to 94% selectivity is obtained at conversions above 95%, which exceeds the best values obtained with homogeneous Lewis acid catalysts. The selectivity obtained is profoundly influenced by the solvent or co‐adsorbate applied.

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Authors and Affiliations

  1. Laboratory of Organic Chemistry and Catalysis, Delft University of Technology, Julianalaan 136, 2628 BL, Delft, The Netherlands

    Paul J. Kunkeler, Jan C. van der Waal, Jurg Bremmer, Boudewijn J. Zuurdeeg, Roger S. Downing & Herman van Bekkum

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  1. Paul J. Kunkeler
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  2. Jan C. van der Waal
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  3. Jurg Bremmer
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  4. Boudewijn J. Zuurdeeg
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  5. Roger S. Downing
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  6. Herman van Bekkum
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Kunkeler, P.J., van der Waal, J.C., Bremmer, J. et al. Application of zeolite titanium Beta in the rearrangement of α-pinene oxide to campholenic aldehyde. Catalysis Letters 53, 135–138 (1998). https://doi.org/10.1023/A:1019049704709

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  • DOI: https://doi.org/10.1023/A:1019049704709

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