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FT-IR study of Au/Fe2O3 catalysts for CO oxidation at low temperature

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Abstract

Coprecipitated Au/Fe2O3 catalysts used for low-temperature catalytic oxidation of carbon monoxide have been studied by FT-IR spectroscopy of adsorbed CO. The FT-IR results have shown that after preparation and exposure to a CO/O2 mixture gold is present on the surface mainly as Au1+ and Au0 species. It has been found that in the CO oxidation Au1+ is more active and less stable than Au0.

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References

  1. T. Kobayashi, M. Haruta, S. Tsubota, H. Sano and B. Delmon, Sensors and Actuators B 1 (1988) 399.

    Google Scholar 

  2. S.D. Gardner, G.B. Hoflund, B.T. Upchurch, D.R. Schryer, E.J. Kielin and J. Schryer, J. Catal. 129 (1991) 114.

    Article  CAS  Google Scholar 

  3. M. Haruta, N. Yamada, T. Kobayashi and S. Iijima, J. Catal. 115 (1989) 301.

    Article  CAS  Google Scholar 

  4. M. Haruta, S. Tsubota, T. Kobayashi, H. Kageyama, M.J. Genet and B. Delmon, J. Catal. 144 (1993) 175.

    Article  CAS  Google Scholar 

  5. S.K. Tanielyan and R.L. Augustine, Appl. Catal. A 85 (1992) 73.

    Google Scholar 

  6. D. Cunningham, S. Tsubota, N. Kamijo and M. Haruta, Res. Chem. Intermed. 19 (1993) 1.

    CAS  Google Scholar 

  7. M.A. Bollinger and M.A. Vannice, Appl. Catal. B 8 (1996) 417.

    Article  Google Scholar 

  8. A. Knell, P. Barnickel, A. Baiker and A. Wokaun, J. Catal. 137 (1992) 306.

    Article  CAS  Google Scholar 

  9. A.M. Visco, A. Donato, C. Milone and S. Galvagno, React. Kinet. Catal. Lett., in press.

  10. T.M. Salama, T. Shido, H. Minagawa and M. Ichikawa, J. Catal. 152 (1995) 322.

    Article  CAS  Google Scholar 

  11. F.E. Wagner, S. Galvagno, C. Milone, A.M. Visco, L. Stievano and S. Calogero, J. Chem. Soc. Faraday Trans. (1997), in press.

  12. S. Qiu, R. Ohnishi and M. Ichikawa, Phys. Chem. 98 (1994) 2719.

    Article  CAS  Google Scholar 

  13. S. Qiu, R. Ohnishi and M. Ichikawa, J. Chem. Soc. Chem. Commun. (1992) 1425.

  14. D. Belli Dell'Amico, F. Calderazzo, P. Robino and A. Segre, J. Chem. Soc. Dalton Trans. (1991) 3017.

  15. F. Boccuzzi, A. Chiorino, S. Tsubota and M. Haruta, J. Phys. Chem. 100 (1996) 3625.

    Article  CAS  Google Scholar 

  16. F. Boccuzzi, A. Chiorino, S. Tsubota and M. Haruta, Catal. Lett. 29 (1994) 225.

    Article  CAS  Google Scholar 

  17. C. Greffiè, M.F. Benedetti, C. Parron and M. Amouric, Geochim. Cosmochim. Acta 60 (1996) 1531.

    Article  Google Scholar 

  18. D. Belli Dell'Amico, F. Calderazzo and F. Marchetti, J. Chem. Soc. Dalton Trans. (1976) 1829.

  19. D.J.C. Yates, Colloid Interf. Sci. 29 (1969) 194.

    Article  CAS  Google Scholar 

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Authors
  1. S. Minicò
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  2. S. Scirè
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  3. C. Crisafulli
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  4. A.M. Visco
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  5. S. Galvagno
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Minicò, S., Scirè, S., Crisafulli, C. et al. FT-IR study of Au/Fe2O3 catalysts for CO oxidation at low temperature. Catalysis Letters 47, 273–276 (1997). https://doi.org/10.1023/A:1019081727173

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