Skip to main content
SpringerLink
Log in

Degradation of Polyacrylamide and Its Derivatives in Aqueous Solutions

  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

General features of degradation of polyacrylamide and its anionic and cationic derivatives under the action of radical degradative agents are considered. The molecular weight of these polymers can be controlled by varying the structure and concentration of the degradative agent and salt additions, the concentration, molecular weight, and composition of the initial (co)polymer, and the process temperature and time.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Halverson, F. and Panzer, H.P., in Kirk-Othmer Encyclopedia of Chemical Technology, New York: Wiley, 1980, 3rd ed., vol. 10, pp. 489-505.

    Google Scholar 

  2. Poliakrilamid (Polyacruylamide), Kurenkov, V.F., Ed., Moscow: Khimiya, 1992.

  3. Kurenkov, V.F. and Myagchenkov, V.A., in Polymeric Materials Encyclopedia, Boca Raton, FL: CRC, 1996, vol. 1, pp. 47-54.

    Google Scholar 

  4. Kurenkov, V.F., in Handbook of Engineering Polymeric Materials, Morganville, NJ: Dekker, 1997, ch. 3, pp. 61-72.

    Google Scholar 

  5. Berlin, A.A., Vol'fson, S.A., and Enikolopyan, N.S., Kinetika polimerizatsionnykh protsessov (Polymerization Kinetics), Moscow: Khimiya, 1978.

    Google Scholar 

  6. Grassie, N. and Scott, G., Polymer Degradation and Stabilisation, Cambridge: Cambridge Univ., 1985.

    Google Scholar 

  7. Plate, N.A., Litmanovich, A.D., and Noa, O.V., Makromolekulyarnye reaktsii (Macromolecular Reactions), Moscow: Khimiya, 1977.

    Google Scholar 

  8. MacWilliams, D.C., Functional Monomers, Vacum, R.H. and Nyguist, E.B., Eds., New York: Dekker, 1973, vol. 1, pp. 1-197.

    Google Scholar 

  9. Narkis, N. and Rebhuhn, M., Polymer, 1966, vol. 10, no. 6, pp. 507-514.

    Google Scholar 

  10. Shyluk, W.P. and Stow, F.S., J. Appl. Polym. Sci., 1969, vol. 13, pp. 1023-1034.

    Google Scholar 

  11. Gardner, K.L., Murphy, W.R., and Geehan, T.G., J. Appl. Polym. Sci., 1978, vol. 22, pp. 881-893.

    Google Scholar 

  12. Haas, H.C. and MacDonald, R.L., J. Polym. Sci., Polym. Lett. Ed., 1972, vol. 10, pp. 461-467.

    Google Scholar 

  13. Recasens, F. and Subirana, J.A., in IUPAC Int. Symp. on Macromolecular Chemistry, Madrid, 1974, vol. 1, pp. 466-475.

    Google Scholar 

  14. Darscus, R.L., Jordan, D.O., Kurucsev, T., et al., J. Polym. Sci., Part A-3, 1965, pp. 1941-1954.

  15. Alfrey, T., Fuoss, R.M., Morawetz, H., et al., J. Am. Chem. Soc., 1952, vol. 74, pp. 438-442.

    Google Scholar 

  16. Chemelir, M., Kunschner, A., and Barthell, E., Angew. Makromol. Chem., 1980, vol. 89, pp. 145-153.

    Google Scholar 

  17. McNeill, I.C. and Zulfigar, M., J. Polym. Sci., Polym. Chem. Ed., 1978, vol. 16, pp. 2465-2474.

    Google Scholar 

  18. Montgomery, W.H., Water Soluble Resins, Davidson, R.L. and Sittig, M., Eds., New York: Reinhold, 1968, pp. 175-184.

    Google Scholar 

  19. Korotkina, O.Z., Magdinets, V.V., Savitskaya, M.N., et al., Zh. Prikl. Khim., 1965, vol. 38, no. 11, pp. 2533-2537.

    Google Scholar 

  20. Kulicke, W.-M. and Klein, J., Angew. Makromol. Chem., 1978, vol. 69, pp. 189-195.

    Google Scholar 

  21. Kulicke, W.-M. and Kniewske, R., Makromol. Chem., 1980, vol. 181, pp. 823-836.

    Google Scholar 

  22. Kulicke, W.-M., Kniewske, R., and Klein, J., Prog. Polym. Sci., 1982, vol. 8, no. 4, pp. 373-468.

    Google Scholar 

  23. Nakonechnyi, I.I., Baiburdov, T.A., and Kurenkov, V.F., Zh. Prikl. Khim., 1991, vol. 64, no. 5, pp. 1062-1065.

    Google Scholar 

  24. Catherin, G. and Marchal, Y., Rev. Inst. Franc Petrole, 1979, vol. 34, no. 5, pp. 719-732.

    Google Scholar 

  25. Voigt, J., Die Stabilisierung der Kunststoffe gegenä Licht und Wärme, Berlin: Springer, 1966.

    Google Scholar 

  26. Haas, H.C., MacDonald, R.L., and Schuler, A.N., J. Polym. Sci., Part A-1, 1970, vol. 8, pp. 3405-3414.

    Google Scholar 

  27. Alexander, P. and Charlesby, A., J. Polym. Sci., 1957, vol. 23, pp. 355-362.

    Google Scholar 

  28. Gareishina, A.Z., Yayus, L.I., Gazizov, A.Sh., et al., Neftepromysl. Delo Transport. Nefti, 1984, no. 8, pp. 17-19.

  29. Prazdnikov, Z.F., Veber, V.I., and Kostyuk, T.V., Neftepromysl. Delo Transport. Nefti, 1985, no. 6, pp. 61-63.

  30. Nagashiro, W. and Tsunoda, T., J. Appl. Polym. Sci., 1977, vol. 21, no. 4, pp. 1149-1153.

    Google Scholar 

  31. Povkh, I.L., Makogon, B.P., Stupnikova, T.V., et al., Dopov. Akad. Nauk Ukr. RSR, Ser. B: Geol., Khim. Biol. Nauki, 1986, no. 10, pp. 31-33.

  32. Makogon, B.P. and Smetankina, V.I., Vysokomol. Soedin., 1988, vol. 30, no. 7, pp. 542-545.

    Google Scholar 

  33. Makogon, B.P., Smetankina, V.I., and Bondarenko, T.A., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1989, vol. 32, no. 4, pp. 92-95.

    Google Scholar 

  34. Klenin, S.I., Lyubina, S.Ya., Baranovskaya, I.A., et al., Vysokomol. Soedin., Ser. A, 1990, vol. 32, no. 2, pp. 439-444.

    Google Scholar 

  35. Farinato, R. and Yen Wei, S., J. Appl. Polym. Sci., 1987, vol. 33, no. 7, pp. 2353-2368.

    Google Scholar 

  36. Henglein, A., Makromol. Chem., 1954, vol. 14, pp. 15-24.

    Google Scholar 

  37. Myagchenkov, V.A., Krikunenko, O.V., and Churikov, F.I., Ul'trazvukovaya destruktsiya vodorastvorimykh (so)polimerov (Ultrasonic Degradation of Water-Soluble (Co)polymers), Kazan: Kazan. Gos. Tekhnol. Univ., 1998.

    Google Scholar 

  38. Hashemzadeh, A. and Kulicke, W.-M., Chem. Eng. Technol., 1986, vol. 58, no. 4, pp. 325-327.

    Google Scholar 

  39. Klein, J. and Westerkamp, A., J. Polym. Sci., Polym. Chem. Ed., 1981, vol. 19, pp. 507-512.

    Google Scholar 

  40. Knight, B.L., Am. Inst. Chem. Eng. Symp. Ser., 1973, vol. 69, no. 127, pp. 40-42.

    Google Scholar 

  41. Muller, G., Polym. Bull., 1981, vol. 5, pp. 31-38.

    Google Scholar 

  42. Muller, G., Polym. Bull., 1981, vol. 5, pp. 39-45.

    Google Scholar 

  43. Suzuki, J., Iizuka, S., and Suzuki, S., J. Polym. Sci., 1978, vol. 22, pp. 2109-2117.

    Google Scholar 

  44. Morooka, S., Ikemizu, K., and Kato, Y., in Proc. 3rd Pacific Chemical Engineering Congr., Seoul, May 83 11, 1983, vol. 4, pp. 289-294.

    Google Scholar 

  45. Martischius, F.-D. and Heide, W., Abstracts of Papers, Drug Reduction: 3rd Int. Conf., Bristol, July 235, 1984, part D9, pp. 1-3.

  46. Knight, B.L., J. Pet. Technol., 1973, vol. 25, pp. 618-623.

    Google Scholar 

  47. Bhuiyan, A.L., Polymer, 1984, vol. 25, no. 12, pp. 1699-1710.

    Google Scholar 

  48. Myagchenkov, V.A., Kurenkov, V.F., and Akhmed'-yanova, R.A., Vysokomol. Soedin., Ser. B, 1984, vol. 26, no. 15, pp. 340-344.

    Google Scholar 

  49. Kurenkov, V.F. and Tazieva, E.D., Zh. Prikl. Khim., 1994, vol. 67, no. 7, pp. 1162-1166.

    Google Scholar 

  50. Praktikum po khimii i fizike polimerov (Practical Course of Polymer Physics and Chemistry), Kurenkov, V.F., Ed., Moscow: Khimiya, 1995, pp. 117-121.

  51. Klein, J. and Conrad, K.-D., Macromol. Chem., 1980, vol. 181, pp. 227-234.

    Google Scholar 

  52. Arcus, C.L., J. Chem. Soc., 1949, no. 3, pp. 2732-2736.

  53. Bresler, S.E., Dolgoplosk, B.A., Krol', V.A., et al., Zh. Obshch. Khim., 1956, vol. 26, no. 8, pp. 2201-2209.

    Google Scholar 

  54. Dolgoplosk, B.A., Erusalimskii, B.L., Kuren'gina, T.N., and Tinyakova, E.I., Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1960, no. 2, pp. 311-316.

  55. Berlin, A.A. and Enikolopyan, N.S., Vysokomol. Soedin., Ser. A, 1968, vol. 10, no. 7, pp. 1475-1478.

    Google Scholar 

  56. Berlin, A.A., Khakimdzhanova, M.A., Karmilova, L.V., and Enikolopyan, N.S., Vysokomol. Soedin., Ser. A, 1968, vol. 10, no. 7, pp. 1496-1504.

    Google Scholar 

  57. Eskin, V.E., Rasseyanie sveta rastvorami polimerov (Light Scattering in Polymer Solutions), Moscow: Nauka, 1973.

    Google Scholar 

  58. Myagchenkov, V.A., Kuznetsov, E.V., and Kurenkov, V.F., Tr. Kazan. Khim.-Tekhnol. Inst., 1967, no. 36, pp. 336-340.

  59. Kurenkov, V.F., Nagel', M.A., Kosterina, E.N., and Myagchenkov, V.A., in Khimiya i tekhnologiya elementoorganicheskikh soedinenii i polimerov (Chemistry and Technology of Organoelement Compounds and Polymers), Kazan: Kazan. Khim.-Tekhnol. Inst., 1984, pp. 34-38.

    Google Scholar 

  60. Kurenkov, V.F., Trifonova, M.N., Terent'eva, G.I., and Myagchenkov, V.A., in Fiziko-khimicheskie osnovy sinteza i pererabotki polimerov (Physicochemical Principles of Polymer Synthesis and Processing), Gor'kii: Gor'k. Gos. Univ., 1987, pp. 74-78.

    Google Scholar 

  61. Kurenkov, V.F., Trifonova, M.N., Kropotova, N.A., and Myagchenkov, V.A., in Khimiya i tekhnologiya elementoorganicheskikh soedinenii i polimerov (Chemistry and Technology of Organoelement Compounds and Polymers), Kazan: Kazan. Khim.-Tekhnol. Inst., 1987, pp. 106-112.

    Google Scholar 

  62. Kurenkov, V.F., Hartan, H.-G., and Lobanov, F.I., Zh. Prikl. Khim., 2001, vol. 74, no. 4, pp. 529-540.

    Google Scholar 

  63. Klein, J. and Conrad, K.-D., Macromol. Chem., 1978, vol. 179, no. 6, pp. 1635-1639.

    Google Scholar 

  64. Kurenkov, V.F., Baiburdov, T.A., and Stupen'kova, L.L., in Fiziko-khimicheskie osnovy sinteza i pererabotki polimerov (Physicochemical Principles of Polymer Synthesis and Processing), Gor'kii: Gor'k. Gos. Univ., 1985, pp. 79-86.

    Google Scholar 

  65. Churikov, F.I., Snigirev, S.V., and Kurenkov, V.F., Zavod. Lab., Diagn. Mater., 1998, no. 6, pp. 9-10.

  66. Wall, F.T. and Doremus, R.H., J. Am. Chem. Soc., 1954, vol. 76, pp. 1557-1561.

    Google Scholar 

  67. Crescenzi, V., De Chirico, A., and Ripamonti, A., Ricenca Sci., 1959, vol. 29, no. 7, pp. 1424-1430.

    Google Scholar 

  68. Crescenzi, V., De Rosa, V., and Mandarella, D., Ricenca Sci., 1960, vol. 30, no. 11, pp. 1680-1687.

    Google Scholar 

  69. Strauss, U.P. and Schlesinger, M.S., Z. Phys. Chem., 1978, vol. 82, no. 5, pp. 571-574.

    Google Scholar 

  70. Akhmed'yanova, R.A., Kurenkov, V.F., Kuznetsov, E.V., and Myagchenkov, V.A., Vysokomol. Soedin., 1981, vol. 23, no. 6, pp. 417-421.

    Google Scholar 

  71. Kurenkov, V.F., Gerkin, R.V., Ivanov, V.S., and Luk'yanov, V.S., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1998, vol. 41, no. 2, pp. 73-77.

    Google Scholar 

  72. Kurenkov, V.F., Baiburdov, T.A., and Stupen'kova, L.L., in Khimiya i tekhnologiya elementoorganicheskikh soedinenii i polimerov (Chemistry and Technology of Organoelement Compounds and Polymers), Kazan: Kazan. Khim.-Tekhnol. Inst., 1985, pp. 47-51.

    Google Scholar 

  73. Golubev, S.V., Tikhonova, Z.A., Semchikov, Yu.D., and Trubina, I.V., Vysokomol. Soedin., Ser. A, 1987, vol. 29, no. 11, pp. 1762-1767.

    Google Scholar 

  74. Myagchenkov, V.A., Krikunenko, O.V., Yunusov, O.A., et al., Dokl. Akad. Nauk SSSR, 1992, vol. 324, no. 4, pp. 826-830.

    Google Scholar 

  75. Myagchenkov, V.A. and Krikunenko, O.V., Vysokomol. Soedin., Ser. A, 1995, vol. 37, no. 1, pp. 44-49.

    Google Scholar 

  76. Kurenkov, V.F., Orlova, I.B., and Myagchenkov, V.A., Vysokomol. Soedin., Ser. A, 1986, vol. 28, no. 6, pp. 1186-1191.

    Google Scholar 

  77. Bekturov, E.A., Myagchenkov, V.A., and Kurenkov, V.F., Polimery i sopolimery stirolsul'fokisloty (Styrenesulfonic Acid Polymers and Copolymers), Alma-Ata: Nauka, 1989.

    Google Scholar 

  78. Myagchenkov, V.A., Kurenkov, V.F., Karachev, N.A., and Frenkel', S.Ya., Dokl. Akad. Nauk SSSR, 1976, vol. 226, no. 4, pp. 869-871.

    Google Scholar 

  79. Shipova, L.M., Radical Emulsion Copolymerization of Acrylamide with Sodium 2-acrylamido-2-methylpropanesulfonate and Potassium p-Styrenesulfonate, Cand. Sci. Dissertation, Kazan, 1998.

  80. Kurenkov, V.F., Len'ko, O.A., Snigirev, S.V., and Lobanov, F.I., Zh. Prikl. Khim., 2002, vol. 75, no. 7, pp. 1164-1168.

    Google Scholar 

  81. Kabanov, V.A. and Topchiev, D.A., Polimerizatsiya ionizuyushchikhsya monomerov (Polymerization of Ionizable Monomers), Moscow: Nauka, 1975.

    Google Scholar 

  82. Kurenkov, V.F. and Myagchenkov, V.A., Zh. Prikl. Khim., 1999, vol. 72, no. 6, pp. 881-890.

    Google Scholar 

  83. Krikunenko, O.V., Ultrasonic Degradation of Random Acrylamide-Sodium Acrylate Copolymers in Aqueous and Aqueous-Salt Solutions, Cand. Sci. Dissertation, Kazan, 1996.

  84. Nikolaev, A.F. and Okhrimenko, G.I., Vodorastvorimye polimery (Water-Soluble Polymers), Leningrad: Khimiya, 1979.

    Google Scholar 

  85. Krikunenko, O.V., Galyamov, A.Sh., and Myagchenkov, V.A., Plast. Massy, 1996, no. 5, pp. 18-20.

Download references

Author information

Authors and Affiliations

  1. Kazan State Technological University, Kazan, Tatarstan, Russia

    V. F. Kurenkov, H. -G. Hartan & F. I. Lobanov

  2. Stockhausen GmbH&Co KG, Krefeld, Germany

    V. F. Kurenkov, H. -G. Hartan & F. I. Lobanov

  3. Stockhausen Eurasia Company, Moscow, Russia

    V. F. Kurenkov, H. -G. Hartan & F. I. Lobanov

Authors
  1. V. F. Kurenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. -G. Hartan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. F. I. Lobanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kurenkov, V.F., Hartan, H.G. & Lobanov, F.I. Degradation of Polyacrylamide and Its Derivatives in Aqueous Solutions. Russian Journal of Applied Chemistry 75, 1039–1050 (2002). https://doi.org/10.1023/A:1020747523268

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1020747523268

Keywords

Search

Navigation