Skip to main content
SpringerLink
Log in

Application of an Ion Beam Technique for the Design of Visible Light-Sensitive, Highly Efficient and Highly Selective Photocatalysts: Ion-Implantation and Ionized Cluster Beam Methods

  • Published:
Catalysis Surveys from Asia Aims and scope Submit manuscript

Abstract

As a new concept for the design of effective photocatalysts, an ion beam technology using accelerated metal ions, a metal ion implantation and an ionized cluster beam (ICB) method, have been applied to design unique photocatalysts. The metal ion implantation of TiO2 and Ti-containing zeolites with highly accelerated metal ions (V+, Cr+, etc.) is useful in designing photocatalysts that can operate efficiently under visible light irradiation. Also, an ICB method with a low acceleration energy is useful in preparing transparent TiO2 thin films on various types of substrates for the efficient photocatalytic degradation of pollutants diluted in water and air. The combination of the ICB method and metal ion implantation can develop the TiO2 thin films that are able to operate not only under UV light but also under visible light irradiation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Anpo, Photofunctional Zeolites: Synthesis, (NOVA Science Publishers Inc., New York, 2000).

    Google Scholar 

  2. M. Anpo and M. Che, Adv. Catal. 44 (1999) 169.

    Google Scholar 

  3. A. Fujishima, K. Hashimoto and T. Watanabe, TiO 2 Photocatalysis (Bkc Inc., 1998).

  4. M. Schiavello, Heterogeneous Photocatalysis (John Wiley & Sons, Chichester, 1997).

    Google Scholar 

  5. M. Anpo, Surface Photochemistry (John Wiley & Sons, Chichester, 1996).

    Google Scholar 

  6. A. Heller, Acc. Chem. Res. 28 (1995) 503.

    Google Scholar 

  7. M.R. Hoffmann, S.T. Martin, W.Y. Choi and D.W. Bahnemann, Chem. Res. 95 (1995) 69.

    Google Scholar 

  8. D.F. Ollis, H. Al-Ekabi, Photocatalytic Purification and Treatment of Water and Air (Elsevier, Amsterdam, 1993).

    Google Scholar 

  9. A. Kudo, J. Cream. Soc. Jpn. 109 (2001) S81.

    Google Scholar 

  10. Z.G. Zou, J.H. Ye, K. Sayama and H. Arakawa, Nature 414 (2001) 625.

    Google Scholar 

  11. R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki and Y. Taga, Science 293 (2001) 269.

    Google Scholar 

  12. K. Nukumizu, J. Nunoshige, T. Takata, J.N. Kondo, M. Hara, H. Kobayashi and K. Domen, Chem. Lett. (2003) 196.

  13. M. Anpo, Pure Appl. Chem. 72 (2000) 1787.

    Google Scholar 

  14. M. Anpo, Catal. Surv. Jpn. 1 (1997) 169.

    Google Scholar 

  15. H. Yamashita, M. Harada, J. Misaka, M. Takeuchi, K. Ikeue and M. Anpo, J. Photochem. Photobiol., A: Chem. 148 (2002) 257.

    Google Scholar 

  16. M. Anpo, S. Kishiguchi, Y. Ichihashi, M. Takeuchi, H. Yamashita, K. Ikeue, B. Morin, A. Davidson and M. Che, Res. Chem. Intermed. 27 (2001) 459.

    Google Scholar 

  17. H. Yamashita, M. Harada, J. Misaka, M. Takeuchi, Y. Ichihashi, F. Goto, M. Ishida, T. Sasaki and M. Anpo, J. Synchrotron Radiat. 8 (2001) 569.

    Google Scholar 

  18. M. Takeuchi, H. Yamashita, M. Matsuoka, M. Anpo, T. Hirao, N. Itoh and N. Iwamoto, Catal. Lett. 67 (2000) 135.

    Google Scholar 

  19. H. Yamashita, Y. Ichihashi, M. Takeuchi, S. Kishiguchi and M. Anpo, J. Synchrotron Radiat. 6 (1999) 451.

    Google Scholar 

  20. M. Anpo, Y. Ichihashi, M. Takeuchi and H. Yamashita, Stud. Surf. Sci. Catal. 121 (1999) 104.

    Google Scholar 

  21. H. Yamashita, M. Honda, M. Harada, Y. Ichihashi, M. Anpo and Y. Hatano, J. Phys. Chem., B 102 (1998) 10707.

    Google Scholar 

  22. M. Anpo, Y. Ichihashi, M. Takeuchi and H. Yamashita, Res. Chem. Intermed. 24 (1998) 143.

    Google Scholar 

  23. H. Yamashita, H. Nakao, M. Takeuchi, Y. Nakatani and M. Anpo, Nucl. Instrum. Methods B 206 (2003) 898.

    Google Scholar 

  24. M. Takeuchi, M. Matsuoka, H. Yamashita and M. Anpo, J. Synchrotron Radiat. 8 (2001) 643.

    Google Scholar 

  25. H. Yamashita, M. Harada, A. Tanii, M. Honda, M. Takeuchi, Y. Ichihashi, M. Anpo, N. Iwamoto, N. Itoh and T. Hirao, Catal. Today 63 (2000) 63.

    Google Scholar 

  26. H. Yamashita, M. Harada, A. Tanii, M. Honda, M. Takeuchi, Y. Ichihashi and M. Anpo, Stud. Surf. Sci. Catal. 130 (2000) 1931.

    Google Scholar 

  27. M. Takeuchi, H. Yamashita, M. Matsuoka and M. Anpo, Catal. Lett. 66 (2000) 185.

    Google Scholar 

  28. M. Harada, A. Tanii, H. Yamashita and M. Anpo, Z. Phys. Chem. 213 (1999) 59.

    Google Scholar 

  29. M. Anpo, T. Shima, S. Kodama and Y. Kubokawa, J. Phys. Chem. 91 (1985) 4305.

    Google Scholar 

  30. Furube, T. Asahi, H. Masuhara, H. Yamashita and M. Anpo, J. Phys. Chem., B 103 (1999) 3120.

    Google Scholar 

  31. H. Yamashita, S. Kawasaki, Y. Ichihashi, M. Harada, M. Anpo, G. Stewart, M.A. Fox, C. Louis and M. Che, J. Phys. Chem., B 102 (1998) 5870.

    Google Scholar 

  32. H. Yamashita, Y. Ichihashi, M. Harada, G. Stewart, M.A. Fox and M. Anpo, J. Catal. 158 (1996) 97.

    Google Scholar 

  33. M. Anpo and K. Chiba, J. Mol. Catal. 74 (1992) 207.

    Google Scholar 

  34. H. Yamashita, K. Ikeue and M. Anpo, Book on CO 2 Conversion and Utilization, ACS Symposium Series 809, K. Fujimoto and C. Song (eds) (ACS, Washington, 2002) pp. 330–343.

    Google Scholar 

  35. H. Yamashita, K. Ikeue, T. Takewaki and M. Anpo, Top. Catal. 18 (2002) 95.

    Google Scholar 

  36. K. Ikeue, H. Yamashita, T. Takewaki and M. Anpo, J. Phys. Chem., B 105 (2001) 8350.

    Google Scholar 

  37. H. Yamashita, Y. Fuji, Y. Ichihashi, S.G. Zhang, K. Ikeue, D.R. Park, K. Koyano, T. Tatsumi and M. Anpo, Catal. Today 45 (1998) 221.

    Google Scholar 

  38. M. Anpo, H. Yamashita, Y. Ichihashi, Y. Fujii and M. Honda, J. Phys. Chem., B 101 (1997) 2632.

    Google Scholar 

  39. J. Zhang, Y. Hu, M. Matsuoka, H. Yamashita, M. Minagawa, H. Hidaka and M. Anpo, J. Phys. Chem., B 105 (2001) 8395.

    Google Scholar 

  40. N.U. Zhanpeisov, M. Matsuoka, H. Mishima, H. Yamashita and M. Anpo, J. Phys. Chem., B 102 (1998) 6915.

    Google Scholar 

  41. H. Yamashita, S.G. Zhang, Y. Ichihashi, Y. Matsumura, Y. Souma, T. Tatsumi and M. Anpo, Appl. Surf. Sci. 121 (1997) 305.

    Google Scholar 

  42. H. Yamashita, Y. Ichihashi, M. Anpo, M. Hashimoto, C. Louis and M. Che, J. Phys. Chem. 100 (1996) 16041.

    Google Scholar 

  43. H. Yamashita, M. Matsuoka, K. Tsuji, Y. Shioya and M. Anpo, J. Phys. Chem. 100 (1996) 397.

    Google Scholar 

  44. H. Yamashita, K. Yoshizawa, M. Ariyuki, S. Higashimoto, M. Che and M. Anpo, Chem. Commun. 435 (2001).

  45. H. Yamashita, K. Kida, K. Ikeue, Y. Kanazawa, K. Yoshizawa and M. Anpo, Stud. Surf. Sci. Catal. 146 (2003) 597.

    Google Scholar 

  46. A. Fuerte, M.D. Hernandez-Alonso, A.J. Maria, A. Martinez-Arias, M. Fernandez-Garcia, J.C. Cornesa, J. Soria and G. Munuera, J. Catal. 212 (2002) 1.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Applied Chemistry, Osaka Prefecture University, Gakuen-cho, Sakai, Osaka, 599-8531, Japan

    Hiromi Yamashita & Masakazu Anpo

Authors
  1. Hiromi Yamashita
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Masakazu Anpo
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Masakazu Anpo.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yamashita, H., Anpo, M. Application of an Ion Beam Technique for the Design of Visible Light-Sensitive, Highly Efficient and Highly Selective Photocatalysts: Ion-Implantation and Ionized Cluster Beam Methods. Catalysis Surveys from Asia 8, 35–45 (2004). https://doi.org/10.1023/B:CATS.0000015113.75529.08

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:CATS.0000015113.75529.08

Search

Navigation