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Enthalpies of Mixing and State of Components in Aqueous-Organic Mixtures with Nets of Hydrogen Bonds

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Abstract

The enthalpies of mixing of water with glycerol over the entire composition range were determined at 298.15 K. The partial excess enthalpies of the components of mixtures of water with glycerol, ethylene glycol, 1,2- and 1,3-propylene glycol, and formamide were estimated and used for examining solvation and the state of water and the organic components in the solutions. The composition of the solvation shells of the components of the mixtures were shown to depend on the nature and structure of the organic solvent.

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REFERENCES

  1. Batov, D.V., Zaichikov, A.M., Slyusar, V.P., and Korolev, V.P., Zh. Obshch. Khim., 1999, vol. 69, no. 12, pp. 1953-1958.

    Google Scholar 

  2. Kumeev, R.S., Luk'yanchikova, I.A., Abakshin, V.A., Abakumova, I.A., and Kessler, Yu.M., Zh. Obshch. Khim., 1992, vol. 62, no. 6, pp. 1248-1252.

    Google Scholar 

  3. Matsumoto, Y., Touhara, H., Nakanishi, K., and Watanabe, N., J. Chem. Thermodyn., 1977, vol. 9, no. 8, pp. 801-805.

    Google Scholar 

  4. Basumullick, I.N. and Kundu, K.K., Indian J. Chem., Sect. A, 1979, vol. 18, no. 1, pp. 1-6.

    Google Scholar 

  5. Monaharamurthy, N. and Subrahmanyam, S.V., Indian J. Chem., Sect. A, 1978, vol. 16, no. 7, pp. 558-560.

    Google Scholar 

  6. Egorova, I.V., Cand. (Chem.) Dissertation, Ivanovo, 1968.

  7. Chistyakov, Yu.V., Cand. (Chem.) Dissertation, Ivanovo, 1978.

  8. Kudryavtsev, A.B., Ermakov, V.I., and Zagorets, P.A., Zh. Strukt. Khim., 1974, vol. 15, no. 1, pp. 136-137.

    Google Scholar 

  9. Huemer, H., Platzer, E., and Rehak, K., Thermochim. Acta, 1991, vol. 187, no. 1, pp. 95-112.

    Google Scholar 

  10. Williamson, K.D., Proc. Workshop on Techniques for Measurement of Thermodynamic Properties, Albany, 1979; Inf. Circ. Bur. Mines. US Dep. Inter., 1981, no. 8853, pp. 425-432, Discuss., pp. 432-435.

  11. Korolev, V.P., Batov, D.V., and Krestov, G.A., Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol., 1986, vol. 29, no. 12, pp. 116-117.

    Google Scholar 

  12. Zaichikov, A.M. and Golubinskii, O.E., Zh. Fiz. Khim., 1996, vol. 70, no. 7, pp. 1175-1179.

    Google Scholar 

  13. Belousov, V.P. and Panov, M.Yu., Termodinamika vodnykh rastvorov neelektrolitov (Thermodynamics of Aqueous Nonelectrolyte Solutions), Leningrad: Khimiya, 1983.

    Google Scholar 

  14. Murakami, S., Tanaka, R., and Fujishiro, R., J. Solution Chem., 1974, vol. 3, no. 1, pp. 71-79.

    Google Scholar 

  15. Stokes, R.H., J. Chem. Thermodyn., 1987, vol. 19, no. 9, pp. 977-983.

    Google Scholar 

  16. Skold, R., Suurkuusk, J., and Wadso, I., J. Chem. Thermodyn., 1976, vol. 8, no. 11, pp. 1075-1080.

    Google Scholar 

  17. Nichols, N., Skold, R., Spink, C., and Wadso, I., J. Chem. Thermodyn., 1976, vol. 8, no. 10, pp. 993-999.

    Google Scholar 

  18. Franks, F., Reid, D.S., and Suggett, A., J. Solution Chem., 1973, vol. 2, no. 2, pp. 99-113.

    Google Scholar 

  19. Bondi, A., J. Phys. Chem., 1973, vol. 68, no. 3, pp. 441-451.

    Google Scholar 

  20. Barone, G., Castronuovo, G., Della Gatta, G., Elia, V., and Iannone, A., Fluid Phase Equilib., 1985, vol. 21, no. 1, pp. 157-164.

    Google Scholar 

  21. Lebedev, Yu.A. and Miroshnichenko, E.A., Termokhimiya paroobrazovaniya organicheskikh veshchestv (Thermochemistry of Vaporization of Organic Compounds), Moscow: Nauka, 1981.

    Google Scholar 

  22. Yastremskii, P.S., Verstakov, E.S., Kessler, Yu.M., Mishustin, A.I., Emelin, V.P., and Bobrinev, Yu.M., Zh. Fiz. Khim., 1975, vol. 49, no. 11, pp. 2950-2953.

    Google Scholar 

  23. Emelin, V.P., Kessler, Yu.M., Mishustin, A.I., and Tolubeev, Yu.G., Zh. Strukt. Khim., 1972, vol. 13, no. 1, pp. 147-148.

    Google Scholar 

  24. Batov, D.V., Zh. Obshch. Khim., 1998, vol. 68, no. 2, pp. 204-209.

    Google Scholar 

  25. Subbarangoial, K., Murthy, M.N., and Subrohmanyam, S.V., Acustica, 1985, vol. 58, no. 2, pp. 105-108.

    Google Scholar 

  26. Morenas, M. and Douheret, G., Thermochim. Acta, 1978, vol. 25, no. 2, pp. 217-224.

    Google Scholar 

  27. Nakanishi, K., Kato, N., and Maruyama, M., J. Phys. Chem., 1967, vol. 71, no. 4, pp. 814-818.

    Google Scholar 

  28. Sadek, H., Nabez, A.M., and Khlil, F.X., Electrochim. Acta, 1969, vol. 14, no. 11, pp. 1089-1096.

    Google Scholar 

  29. Neberukhin, Yu.I. and Rogov, V.A., Usp. Khim., 1971, vol. 40, no. 3, pp. 369-385.

    Google Scholar 

  30. Batov, D.V., Antonova, O.A., Slyusar, V.P., and Korolev, V.P., Zh. Obshch. Khim., 1999, vol. 69, no. 8, pp. 1258-1264.

    Google Scholar 

  31. Batov, D.V., Manin, N.G., and Zaichikov, A.M., Zh. Obshch. Khim., 2001, vol. 71, no. 6, pp. 909-915.

    Google Scholar 

  32. Klimova, V.A., Osnovnye mikrometody analiza organicheskikh soedinenii (Principal Methods of Organic Microanalysis), Moscow: Khimiya, 1967.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia

    D. V. Batov, A. M. Zaichikov, V. P. Slyusar & V. P. Korolev

  2. Ivanovo State University of Chemical Engineering, Ivanovo, Russia

    D. V. Batov, A. M. Zaichikov, V. P. Slyusar & V. P. Korolev

  3. Ivanovo State Medical Academy, Ivanovo, Russia

    D. V. Batov, A. M. Zaichikov, V. P. Slyusar & V. P. Korolev

Authors
  1. D. V. Batov
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  2. A. M. Zaichikov
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  3. V. P. Slyusar
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  4. V. P. Korolev
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Batov, D.V., Zaichikov, A.M., Slyusar, V.P. et al. Enthalpies of Mixing and State of Components in Aqueous-Organic Mixtures with Nets of Hydrogen Bonds. Russian Journal of General Chemistry 71, 1208–1214 (2001). https://doi.org/10.1023/A:1013256524865

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