Abstract
A Mg/Al-layered double hydroxide with interlayernaphthalene-2,6-disulfonate having a basal spacing of1.68 nm was prepared by means of the coprecipitationmethod. The results of powder X-ray diffractionare compared with those of other intercalates whichhave interlayer naphthalene disulfonates. Fouriertransform infrared spectra of the LDH intercalatedcompounds reveal that the organic molecules located inthe interlayer region are stable. Coordinationfrom the oxygen atom in the –SO3 - group of the interlayer molecules to the metal cation in the layeris observed.
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Kanezaki, E. Fourier Transform Infrared Spectra of Naphthalene Disulfonates between Layers of Mg and Al double Hydroxide: Intercalation by Means of Coprecipitation and Direct Observation of Coordination from the Interlayer Anion to the Metal Cation in the Layer. Journal of Inclusion Phenomena 36, 447–453 (2000). https://doi.org/10.1023/A:1008064110578
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DOI: https://doi.org/10.1023/A:1008064110578