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Zinc electrowinning from acidic sulfate solutions: Part I: Effects of sodium lauryl sulfate

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Abstract

The effects of sodium lauryl sulphate(SLS) in the presence and absence of antimony(iii) on the current efficiency, power consumption and polarization behaviour of zinc were determined. The surface morphologies and deposit crystallographic orientations were also evaluated. The results were compared with glue as the addition agent. The addition of sodium lauryl sulfate to the zinc sulfate solution increased current efficiency, reduced power consumption and improved the surface morphology. Maximum current efficiency and minimum power consumption were achieved on addition of 0.02mgdm−3 Sb with 1mgdm−3 sodium lauryl sulfate.

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References

  1. G. T. Wever, J. Metals. 11 (1959) 130.

    Google Scholar 

  2. R. C. Kerby and T. R. Ingraham, Research report R 243, Department of Energy, Mines and Resources, Mines Branch, Ottawa, Canada, April (1971), p. 35.

    Google Scholar 

  3. H. H. Fukubayashi, T. J. O'Keefe and W. C. Clinton, US Bureau of Mines, Report of Investigations 7966 (1974), p. 26.

  4. U. F. Turomshina and V. V. Stender, Zh. Prikl. Khim. 28 (1955) 372.

    Google Scholar 

  5. D. J. MacKinnon and J. M. Brannen, J. Appl. Electrochem. 7 (1977) 451.

    Google Scholar 

  6. O. C. Ralston, `Electrolytic Deposition and Hydrometallurgy of Zinc', McGraw-Hill, New York (1921), Chapter 7.

    Google Scholar 

  7. D. J. Robinson and T. J. O'Keefe, J. Appl. Electrochem. 6 (1976) 1.

    Google Scholar 

  8. D. J. MacKinnon, J. M. Brannen and P. L. Fenn, ibid. 17 (1987) 1129.

    Google Scholar 

  9. D. J. MacKinnon, R. M. Morrison, J. E. Mouland and P. E. Warren, ibid. 20 (1990) 728.

    Google Scholar 

  10. R. Sato, J. Electrochem. Soc. 106 (1959) 206.

    Google Scholar 

  11. F. Mansfield and S. Gilman, ibid. 117 (1978) 1150.

    Google Scholar 

  12. J. W. Diggle and A. Demjanovic, ibid. 119 (1970) 1649.

    Google Scholar 

  13. V. V. Ramnov, Sov. Electrochem. 7 (1971) 1400.

    Google Scholar 

  14. D. L. Piron, D. Mathieu and M. D. Amboise, Can. J. Chem. Engg 65 (1981) 685.

    Google Scholar 

  15. D. J. MacKinnon, J. M. Brannen and R. M. Morrison, J. Appl. Electrochem. 18 (1988) 252.

    Google Scholar 

  16. D. J. MacKinnon and J. M. Brannen, ibid. 12 (1982) 21.

    Google Scholar 

  17. D. J. MacKinnon, J. M. Brannen and R. M. Morrison, ibid. 12 (1982) 39.

    Google Scholar 

  18. B. K. Thomas and D. J. Fray, ibid. 11 (1981) 677.

    Google Scholar 

  19. A. Hosny, Hydrometallurgy. 32 (1993) 361.

    Google Scholar 

  20. M. Karavasteva and St. Karivanov, ibid. 23 (1993) 763.

    Google Scholar 

  21. M. Karavesteva, Hydrometallurgy. 35 (1994) 391.

    Google Scholar 

  22. L. Oniciu and L. Muresan, J. Appl. Electrochem. 21 (1991) 565.

    Google Scholar 

  23. A. M. Schwartz and J. W. Perry, `Surface Active Agents' vol 1, Interscience Publishers, New York (1963), p. 53.

    Google Scholar 

  24. A. M. Schwartz and J. W. Perry, op cit., p. 287.

  25. V. H. Waite and B. P. Martin, US Patent 2 254 (1941) 161.

  26. H. Brown, US Patent 2 389 (1945) 181 and 2 524 (1950) 619.

  27. S. C. Das, G. T. Hafter and P. Singh, J. Appl. Electrochem, in press.

  28. S. E. Aiffi, A. R. Ebaid, M. M. Hegazy and A. K. Barakat, J. MetalsJan. (1992) 32–34.

  29. U. F. Turomshina and V. V. Stender, J. Appl. Chem. USSR 28 (1955) 347.

    Google Scholar 

  30. N. Mastuura and M. Kojma, Tokyo Univ. Coll. Gen. Ed. Sci. Pap-11 (1952) 47.

    Google Scholar 

  31. D. R. Fosnacht and T. J. O'Keefe, Met. Trans. 14B (1983) 645.

    Google Scholar 

  32. O. Vennesland, H. Holtan and S. Solhjell, Acta. chem. Scand. 27 (1973) 846.

    Google Scholar 

  33. A. R. Ault and E. J. Frazer, J. Appl. Electrochem. 18 (1988) 583.

    Google Scholar 

  34. C. L. Mantell, `Electrochemical Engineering' 4th. edn. McGraw-Hill, New York (1960), p. 210.

    Google Scholar 

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TRIPATHY , B.C., DAS , S.C., HEFTER , G.T. et al. Zinc electrowinning from acidic sulfate solutions: Part I: Effects of sodium lauryl sulfate. Journal of Applied Electrochemistry 27, 673–678 (1997). https://doi.org/10.1023/A:1018431619595

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