Abstract
This paper describes a study of the influence of the butyl group as substituent in n-butylamine used as a mild steel corrosion inhibitor in hydrochloric acid solution. An inhibition mechanism is proposed. n-Butylamine, dibutylamine and tributylamine were studied in concentrations from 10−4 to 1 m and in the temperature range 278–308K using electrochemical, gravimetric and surface roughness techniques. The three inhibitors adsorbed on the mild steel according to a Frumkin isotherm.
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References
G. Trabanelli, in `Corrosion Mechanisms' (edited by F. Mansfeld), Marcel Dekker, New York (1987) p. 119.
J. de Damborenea, J. M. Bastidas and A. J. Vázquez, Electrochim. Acta, in press.
U. R. Evans, `The Corrosion and Oxidation of Metals, Second Supplement', E. Arnold, London (1976) p. 104.
E. E. Underwood, in `Practical Applications of Quantitative Metallography' (edited by J. L. McCall and J. H. Steele, Jr.), ASTM STP 839, Philadelphia (1984) p. 170.
B. B. Damaskin, O. A. Petrii and V. V. Batrakov, `Adsorption of Organic Compounds on Electrodes', Plenum Press, New York (1971) p. 67.
S. Muralidharan, K. L. N. Phani, S. Pitchumani, S. Ravichandran and S. V. K. Iyer, J. Electrochem. Soc. 142 (1995) 1478.
R. Zvauya and J. L. Dawson, J. Appl. Electrochem. 24 (1994) 943.
R. C. Weast (editor), `Handbook of Chemistry and Physics', 66th edn CRC press, Boca Raton, FL (1985), p. E–50.
T. Szauer and A. Brandt, Electrochim. Acta 26 (1981) 1219.
O. L. Riggs, Jr and R. M. Hurd, Corrosion 23 (1967) 252.
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BASTIDAS , J.M., DAMBORENEA , J.D. & VA´ZQUEZ , A.J. Butyl substituents in n-butylamine and their influence on mild steel corrosion inhibition in hydrochloric acid. Journal of Applied Electrochemistry 27, 345–349 (1997). https://doi.org/10.1023/A:1018441032374
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DOI: https://doi.org/10.1023/A:1018441032374