Skip to main content
SpringerLink
Log in

A new cell for the collection of combined EXAFS/XRD data in situ during solid/liquid catalytic reactions

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

A new experimental reaction cell which enables the recording of combined EXAFS/XRD data over a wide range of temperatures of a solid that catalyses liquid reactions in the liquid state has been designed and constructed. The cell is particularly suitable for the in situ study of both short-range and long-range structural changes during solid/liquid heterogeneous catalytic reactions. It is also suitable for the study of intercalation phenomena and may be readily adapted for certain types of electrochemical investigations. The use of this cell is exemplified by the oxidation of cyclohexene over a Zn(II)Al(III)-hydrotalcite containing intercalated cobalt phthalocyaninetetrasulphonate anions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. Dooryhee, G.N. Greaves, A.T. Steel, R.P. Townsend, S.W. Carr, J.M. Thomas and C.R.A. Catlow, Faraday Discussion Chem. Soc. 89 (1990) 119.

    Google Scholar 

  2. E. Dooryhee, C.R.A. Catlow, J.W. Couves, P.J. Maddox, J.M. Thomas, G.N. Greaves, A.T. Steel and R.P. Townsend, J. Phys.Chem. 95 (1991) 4514.

    Google Scholar 

  3. J.M. Thomas, C. Williams and T. Rayment, J. Chem. Soc. Faraday Trans. I 84 (19882915; T. Rayment, R. Schlögl, J.M. Thomas and G. Ertl, Nature 315 (1985) 311.

    Google Scholar 

  4. P.J. Maddox, J. Stachurski and J.M. Thomas, Catal. Lett. 1 (1988) 191.

    Google Scholar 

  5. I.J. Pickering, D. Madill, M. Sheehy, J. Stachurski, P.J.Maddox, J.W. Couves, E. Dooryhee and J.M. Thomas, J. Chem. Soc. Faraday Trans. 87 (1991) 3063.

    Google Scholar 

  6. I.J. Pickering and J.M. Thomas, J. Chem. Soc. Faraday Trans. 87 (19913067.

    Google Scholar 

  7. J.W. Couves, J.M. Thomas, D. Waller, R.H. Jones, A.J. Dent, G.E. Derbyshire, B.R. Dobson, C.A. Ramsdale and G.N. Greaves, Nature 354 (1991) 465.

    Google Scholar 

  8. J.M. Thomas and G.N.Greaves, Catal. Lett. 20 (1993) 337.

    Google Scholar 

  9. B.S. Clausen, K. Grabaek, G. Steffensen, P.L. Hansen and H. Topsø, Catal. Lett. 20 (1993) 23.

    Google Scholar 

  10. J.M. Thomas and G.N.Greaves, Science 265 (19941675.

    Google Scholar 

  11. J.M. Thomas, G.N. Greaves and C.R.A. Catlow, Nucl. Instr. Meth. Phys. Res. B 97 (1995) 1.

    Google Scholar 

  12. S.M. Clark, A. Nield, T. Rathbone, J. Flaherty, C.C. Tang, J.S.O. Evans, R.J. Francis and D. O'Hare, Nucl. Instr. Meth. Phys.Res. B 97 (1995) 98.

    Google Scholar 

  13. J.S.O. Evans, R.J. Francis, D. O'Hare, S.J. Price, S.M. Clark, J. Flaherty, J. Gordon, A. Nield and C.C. Tang, Rev. Sci. Instrum. 66 (1995) 2442.

    Google Scholar 

  14. F. Rey, G. Sankar, J.M. Thomas, P.A. Barrett, D.W. Lewis, C.R.A. Catlow, S.M. Clark and G.N. Greaves, Chem. Mater. 7 (19951435.

    Google Scholar 

  15. R.J. Francis, S.J. Price, J.S.O. Evans, S. O'Brien, D. O'Hare and S.M. Clark, Chem. Mater. 8 (1996) 2102.

    Google Scholar 

  16. G. Sankar, J.M. Thomas, F. Rey and G.N. Greaves, J. Chem. Soc. Chem.Commun. (1995) 2549.

  17. G. Sankar and J.M. Thomas preparation.

  18. I.J. Shannon, F. Rey, G. Sankar, J.M. Thomas, T. Maschmeyer, A.E. Palomares, A. Corma, A.M. Waller, A.J. Dent and G.N.Greaves, J. Chem. Soc. Faraday Trans. 92 (1996) 4331.

    Google Scholar 

  19. G. Sankar, F. Rey, J.M. Thomas, G.N. Greaves, A. Corma, B.R. Dobson and A.J. Dent, J. Chem. Soc. Chem. Commun. (1994) 2279.

  20. D. Bogg, M. Conyngham, J.M. Corker, A.J. Dent, J. Evans, R.C. Farrow, V.L. Kambhampati, A.F. Masters, D.N. McLeod, C.A. Ramsdale and G. Salvini, Chem.Commun. (1996) 647.

  21. J.M. Corker and J. Evans, J. Chem. Soc. Chem. Commun. (1994) 1027.

  22. T. Maschmeyer, R.D. Oldroyd, G. Sankar, J.M. Thomas, I.J. Shannon, J.A. Klepetko, A.F. Masters, J.K. Beattie and C.R.A. Catlow, Angew. Chem., submitted.

  23. B.S. Clausen, G. Steffensen, B. Fabius, J. Villadsen, R. Feidenhans'l and H. Topsø, J. Catal. 132 (1991) 524.

    Google Scholar 

  24. A. Skorobogathy and T.D. Smith, J.Mol.Catal. 16 (1982) 131.

    Google Scholar 

  25. M.E. Pérez-Bernal, R. Ruano-Casero and T.J. Pinnavaia, Catal. Lett. 11 (1991) 55.

    Google Scholar 

  26. G. Sankar, P.A. Wright, S. Natarajan, J.M. Thomas, G.N. Greaves, A.J. Dent, B.R. Dobson, C.A. Ramsdale and R.H. Jones, J. Phys.Chem. 97 (1993) 9550.

    Google Scholar 

  27. N. Binsted, J.W. Campbell, S.J. Gurman and P.C. Stephenson, SERC Daresbury Laboratory Program(1991).

Download references

Authors
  1. I.J. Shannon
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. Maschmeyer
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. Sankar
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J.M. Thomas
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. R.D. Oldroyd
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. M. Sheehy
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. D. Madill
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A.M. Waller
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. R.P. Townsend
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shannon, I., Maschmeyer, T., Sankar, G. et al. A new cell for the collection of combined EXAFS/XRD data in situ during solid/liquid catalytic reactions. Catalysis Letters 44, 23–27 (1997). https://doi.org/10.1023/A:1018956520929

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1018956520929

Keywords

Search

Navigation