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Immobilization of new Mn(salen) complex over MCM-41 and its activity in asymmetric epoxidation of styrene

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Abstract

New tetradentate chelates of bis-Schiff bases were synthesized and then these chiral salen ligands were immobilized over mesoporous MCM-41 by using the ion-exchange method. The efficiency of the chiral catalyst was examined in the asymmetric epoxidation of styrene. Chiral Mn(salen) complexes immobilized onto mesoporous MCM-41 were stable during the reaction without any leaching and exhibited relatively high enantioselectivity for epoxidation as compared with homogeneous complexes.

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References

  1. Y. Gao, R.M. Hanson, J.M. Klunder, S.Y. Ko, H. Masamune and K. B. Sharpless, J. Am. Chem. Soc. 109 (1987) 5765.

    Article  CAS  Google Scholar 

  2. K.B. Sharpless, S.S. Woodard and M.G. Finn, Pure Appl. Chem. 55 (1984) 1823.

    Google Scholar 

  3. D.L. Linda, R.A. Johnson, M.G. Finn and K.B. Sharpless, J. Org. Chem. 49 (1984) 728.

    Article  Google Scholar 

  4. W. Zhang, J.L. Loebach, R. Scott and E.N. Jacobson, J. Am. Chem. Soc. 112 (1990) 2801.

    Article  CAS  Google Scholar 

  5. J.T. Groves and R.S. Myers, J. Am. Chem. Soc. 105 (1983) 5791.

    Article  CAS  Google Scholar 

  6. E.N. Jacobson, W. Zhang, A.R. Muci, J.R. Ecker and L. Deng, J. Am. Chem. Soc. 113 (1991) 7063.

    Article  Google Scholar 

  7. M. Palucki, P.J. Pospisil, W. Zhang and E.N. Jacobson, J. Am. Chem. Soc. 116 (1994) 9333.

    Article  CAS  Google Scholar 

  8. C. Bowers and P.K. Dutta, J. Catal. 122 (1990) 271.

    Article  CAS  Google Scholar 

  9. M.J. Sabater, A. Corma, A. Domenech, V. Fornes and H. Garcia, J. Chem. Soc. Chem. Commun. (1997) 1285.

  10. S.B. Ogunwumi and T. Bein, J. Chem. Soc. Chem. Commun. (1997) 901.

  11. L. Frunza, H. Kosslick, H. Landmesser, E. Hoft and R. Fricke, J. Mol. Catal. 123 (1997) 179.

    Article  CAS  Google Scholar 

  12. G. Casiraghi, G. Casnati, G. Puglia, G. Sartori and G. Terenghi, J. Chem. Soc. Perkin Trans. 1 (1980) 1862.

    Article  Google Scholar 

  13. W. Zhang and E.N. Jacobson, J. Org. Chem. 56 (1991) 2296.

    Article  CAS  Google Scholar 

  14. R. Ryoo, C.H. Ko and R.F. Howe, Chem. Mater. 9 (1997) 1607.

    Article  CAS  Google Scholar 

  15. K. Noda, N. Hosoya, R. Irie, Y. Yamashita and T. Katsuki, Tetrahedron 50 (1994) 9609.

    Article  CAS  Google Scholar 

  16. N. Herron, Inorg. Chem. 25 (1986) 4714.

    Article  CAS  Google Scholar 

  17. E.N. Jacobson, W. Zhang and M.L. Guler, J. Am. Chem. Soc. 112 (1990) 2801.

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemical Engineering, Inha University, Inchon, 402-751, Korea

    Geon-Joong Kim & Sang-Han Kim

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  1. Geon-Joong Kim
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  2. Sang-Han Kim
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Kim, GJ., Kim, SH. Immobilization of new Mn(salen) complex over MCM-41 and its activity in asymmetric epoxidation of styrene. Catalysis Letters 57, 139–143 (1999). https://doi.org/10.1023/A:1019039430518

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