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Single-step synthesis of acetic acid (methyl acetate) from methanol alone by Ru(II)-Sn(II) hetero-bimetallic catalysts

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Abstract

Single-step conversion of methanol into acetic acid (methyl acetate) has been found possible by use of Ru(II)-Sn(II) hetero-bimetallic catalysts. By analyzing the homogeneous solution reactions, reaction paths are elucidated. Applications of lacunary heteropolyanions as model oxide ligands and of Y-type zeolite as a unique support for the gas-phase reaction are presented.

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Authors
  1. Sumio Shinoda
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  2. Takeshi Ohnishi
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  3. Tetsu Yamakawa
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Shinoda, S., Ohnishi, T. & Yamakawa, T. Single-step synthesis of acetic acid (methyl acetate) from methanol alone by Ru(II)-Sn(II) hetero-bimetallic catalysts. Catalysis Surveys from Asia 1, 25–34 (1997). https://doi.org/10.1023/A:1019060526478

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