Abstract
Mo complexes with Mo1–Mo4 nuclearities were grafted on mesoporous silica FSM‐16, and their catalytic performances were studied in the hydroxylation of benzene. A trinuclear Mo oxo complex grafted on FSM‐16 exhibits the highest catalytic activity in the hydroxylation of benzene to phenol using hydrogen peroxide as an oxidant under the irradiation of UV‐light. The turnover numbers for phenol are over 700 at 300 K.
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References
R.A. Sheldon and R.A. van Santen, Catalytic Oxidation: Principles and Applications (World Scientific, Singapore, 1995)
G. Centi and M. Misono, Catal. Today 41 (1998) 287.
C. Walling and R.A. Johnson, J. Am. Chem. Soc. 97 (1975) 363
P.T. Tanev, M. Chibwe and T.J. Pinnavaia, Nature 368 (1994) 321
S. Ito, A. Mitarai, K. Hikino, M. Hirama and K. Sasaki, J. Org. Chem. 57 (1992) 6937
T. Tagawa, Y. Seo and S. Goto, J. Mol. Catal. 78 (1993) 201
K. Nomiya, H. Yanagibayashi, C. Nozaki, K. Kondoh, E. Hiramatsu and Y. Shimizu, J. Mol. Catal. 114 (1996) 181
X. Lu, N. Mizuno and M. Misono, Nippon Kagaku Kaishi (1998) 23
T. Miyake, M. Hamada, Y. Sasaki and M. Oguri, Appl. Catal. A 131 (1995) 33
K. Otsuka, M. Kunieda and H. Yamagata, J. Electrocatal. Soc. 139 (1992) 2381.
M. Ichikawa, in: Metal Clusters in Chemistry, eds. P. Braunstein, L.A. Oro and P.R. Raithby (Wiley/VCH, Weinheim, 1999) p. 1273
M. Ichikawa, in: Chemisorption and Reactivity on Supported Clusters and Thin Films, ed. R.M. Lambert (Kluwer, Dordrecht, 1997) p. 153
M. Ichikawa, Adv. Catal. 38 (1992) 283.
M. Ichikawa, G.J. Li, Q. Zhuang, K. Tanaka and A. Fukuoka, in: New Frontiers in Catalysis, ed. L. Guczi (Elsevier, Amsterdam, 1993) p. 529
Y. Imada, T. Shido, R. Ohnishi and M. Ichikawa, Catal. Lett. 38 (1996) 101
K. Zama, Y. Imada, A. Fukuoka and M. Ichikawa, Appl. Catal. A 194/195 (2000) 285.
A. Bino, F.A. Cotton, Z. Dori and B.W.S. Kolthammer, J. Am. Chem. Soc. 103 (1981) 5779.
Y. Hayashi, K. Toriumi and K. Isobe, J. Am. Chem. Soc. 110 (1988) 3666.
S. Inagaki, Y. Fukushima and K. Kuroda, J. Chem. Soc. Chem. Commun. (1993) 680.
M. Anpo, M. Kondo, S. Coluccia, C. Louis and M. Che, J. Am. Chem. Soc. 111 (1989) 8791.
M. Ardon, A. Bino, F.A. Cotton, Z. Dori, M. Kaftory and G. Reisner, Inorg. Chem. 21 (1982) 1912.
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Zama, K., Fukuoka, A., Sasaki, Y. et al. Selective hydroxylation of benzene to phenol by photocatalysis of molybdenum complexes grafted on mesoporous FSM‐16. Catalysis Letters 66, 251–253 (2000). https://doi.org/10.1023/A:1019080530228
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DOI: https://doi.org/10.1023/A:1019080530228