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Variable‐temperature IR spectroscopic studies of CO adsorbed on Na‐ZSM‐5 and Na‐Y zeolites

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Abstract

CO interacts with extra‐framework alkali metal cations (M+=) of zeolites to form both M+⋯CO and M+⋯OC species. By using variable‐temperature FTIR spectroscopy, these C‐bonded and O‐bonded species were found to be in a temperature‐dependent equilibrium. For the same cation, the difference in interaction energy depends upon the zeolite framework. Thus, for the equilibrium process ZNa+⋯=CO ⇌ ZNa+⋯OC, where Z represents the zeolite framework, ΔH 0 was found to take the values 3.8 and 2.4 kJ mol− for CO/Na‐ZSM‐5 and CO/Na‐Y, respectively. The C‐bonded species show always the highest cation–CO interaction energy.

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Authors and Affiliations

  1. Institute of Physics, St. Petersburg University, 198904, St. Petersburg, Russia

    A.A. Tsyganenko

  2. Departamento de Química, Universidad de las Islas Baleares, 07071, Palma de Mallorca, Spain

    E. Escalona Platero & C. Otero Areán

  3. Dipartimento di Chimica IFM, Università di Torino, 10125, Torino, Italy

    E. Garrone & A. Zecchina

Authors
  1. A.A. Tsyganenko
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  2. E. Escalona Platero
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  3. C. Otero Areán
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  4. E. Garrone
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  5. A. Zecchina
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Tsyganenko, A., Escalona Platero, E., Otero Areán, C. et al. Variable‐temperature IR spectroscopic studies of CO adsorbed on Na‐ZSM‐5 and Na‐Y zeolites. Catalysis Letters 61, 187–192 (1999). https://doi.org/10.1023/A:1019089309446

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