Skip to main content
Log in

Synthesis of nanosized platinum cluster in cubic mesoporous material via a direct introduction method

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Platinum‐cluster‐containing cubic mesoporous material (Pt‐MCM‐48) has been synthesized by direct introduction of chloroplatinic acid during the synthesis of MCM‐48. In addition, we have also studied the incipient wetness impregnation and ion‐exchange method to obtain the platinum‐containing cubic mesoporous material. The nature of the platinum‐MCM‐48 catalyst has been characterized by different techniques such as XRD, N2 adsorption, TEM, XPS, and NMR. The catalyst obtained by direct introduction of platinum in the synthesis gel shows higher activity in the hydrogenation of benzene and toluene.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli and J.S. Beck, Nature 359 (1992) 710.

    Google Scholar 

  2. C.Y. Chen, S.L. Burkett, H.X. Li and M.E. Davis, Micropor. Mater. 2 (1993) 27.

    Google Scholar 

  3. A. Corma, V. Fornes, M.T. Navarro and J. Perez-Pariente, J. Catal. 148 (1994) 569.

    Google Scholar 

  4. A. Corma, M.T. Navarro and J. Perez-Pariente, J. Chem. Soc. Chem. Commun. (1994) 147.

  5. K.M. Reddy, I.L. Moudrakouski and A. Sayari, J. Chem. Soc. Chem. Commun. (1995) 973.

  6. F. Rey, G. Sankar, T. Maschmeyer, J.M. Thomas and R.G. Bell, Topics Catal. 3 (1996) 121.

    Google Scholar 

  7. A. Corma, Chem. Rev. 97 (1997) 2373.

    Google Scholar 

  8. V. Alfredsson and M.W. Anderson, Chem. Mater. 8 (1996) 1141.

    Google Scholar 

  9. W. Zhang and T.J. Pinnavia, Catal. Lett. 38 (1996) 261.

    Google Scholar 

  10. T. Inui, J.B. Kim and M. Seno, Catal. Lett. 29 (1994) 271.

    Google Scholar 

  11. J.C. Vartuli, K.D. Schnitt, C.T. Kresge, W.J. Roth, M.E. Leonowicz, S.B. McCullen, S.D. Hellring, J.S. Beck, J.L. Schlenker, D.H. Olson and E.W. Sheppard, Chem. Mater. 6 (1994) 2317.

    Google Scholar 

  12. D. Zhao and D. Goldfarb, J. Chem. Soc. Chem. Commun. (1995) 875.

  13. Q. Huo, D. Margolese and G.D. Stucky, Chem. Mater. 8 (1996) 1147.

    Google Scholar 

  14. C.A. Fyfe and G. Fu, J. Am. Chem. Soc. 117 (1995) 9709.

    Google Scholar 

  15. A.A. Romero, M.D. Alba, W. Zhuo and J. Klinowski, J. Phys. Chem. B 101 (1997) 5294.

    Google Scholar 

  16. J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins and J.L. Schlenker, J. Am. Chem. Soc. 114 (1992) 10834.

    Google Scholar 

  17. Z. Paál, M. Muhler and R. Schlögl, J. Catal. 143 (1993) 318.

    Google Scholar 

  18. P.N. Ross, K. Kinoshita and P. Stonehart, J. Catal. 32 (1974) 163.

    Google Scholar 

  19. R. Ryoo, C. Hyun Ko, J.M. Kim and R. Howe, Catal. Lett. 37 (1996) 29.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Chatterjee.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chatterjee, M., Iwasaki, T., Onodera, Y. et al. Synthesis of nanosized platinum cluster in cubic mesoporous material via a direct introduction method. Catalysis Letters 61, 199–202 (1999). https://doi.org/10.1023/A:1019097511263

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1019097511263

Navigation