Abstract
Lignin represents a vastly under-utilized natural polymer co-generated during papermaking and biomass fractionation. Different types of lignin exist, and these differ with regard to isolation protocol and plant resource (i.e., wood type or agricultural harvesting residue). The incorporation of lignin into polymeric systems has been demonstrated, and this depends on solubility and reactivity characteristics. Several industrial utilization examples are presented for sulfur-free, water-insoluble lignins. These include materials for automotive brakes, wood panel products, biodispersants, polyurethane foams, and epoxy resins for printed circuit boards.
Similar content being viewed by others
REFERENCES
W. G. Glasser (1980) in J. P. Casey, (Ed), Pulp and Paper: Chemistry and Chemical Technlogy. 3rd ed., Vol. 1, John Wiley & Sons, pp. 39–111. New York.
W. G. Glasser and S. S. Kelley (1987) in Encyclopedia of Polymer Science and Engineering, Vol. 8, JohnWiley & Sons, pp. 795–852. New York.
H. L. Chum, S. K. Parker, D. A. Feinberg, J. D. Wright, P. A. Rice, S. A. Sinclair, and W. G. Glasser (1985) SERI/TR 231–488, 1–86.
J. D. Gargulak and S. E. Lebo (2000) ACS Symp. Ser. No. 742, 304–320.
W. G. Glasser (2001) in F. C. Beall (ed.) The Encyclopedia of Materials: Science and Technology, Elsevier Science Oxford, UK.
W. G. Glasser, C. A. Barnett, P. C. Muller, and K. V. Sarkanen (1983) J. Agri. Food Chem. 31, 921–930.
W. G. Glasser, C. A. Barnett, and Y. Sano (1983) Appl. Polymer Symp. 37, 441–460.
W. G. Glasser (2000) ACS Symp. Ser. No. 742, 216–238.
J. H. Lora (2002) in T. Hu, (Ed.), Chemical Modification, Propeties, and Usage of Lignin, Kluwer Academic/Plenum Publishers, New York.
J. S. Gratzl and C. L. Chen (1996) Proc. Third Int. Non-Wood Fiber Pulping and Papermaking Conf. International Academic Publishers, Beijing, Suppl. Vol., pp. 15–21.
R. S. Wright and W. G. Glasser (1998) Biomass Bioenergy 14, 219–235.
M. Ibrahim and W. G. Glasser (1999) Bioresource Technol. 70, 181–192.
W. G. Glasser and R. C. Strickland (1987) Biomass 13, 235–254.
W. G. Glasser, V. Davé, and C. E. Frazier (1993) J. Wood Chem. Technol. 13, 545–559.
W. G. Glasser and S. Sarkanen (Eds.) (1989) ACS Symp. Ser. No. 397, 546.
W. G. Glasser (1989) ACS Symp. Ser. No. 385, 43–54.
W. G. Glasser and R. K. Jain (1993) Holzforschung 47, 225–233.
R. K. Jain and W. G. Glasser (1993) Holzforschung 47(3), 325–332.
O. H.-H. Hsu and W. G. Glasser (1975) Appl. Polymer Symp. 28, 297–307.
W. G. Glasser and O. H.-H. Hsu (1977) “Polyurethane intermediates and products and methods of producing same from lignin”. U.S. Patent 4,017,474; and Canadian Patent #1,097,617 (1981).
W. G. Glasser, W. Nieh, S. S. Kelley, and W. de Oliveira (1990) “Method of producing prepolymers from hydroxyalkyl lignin derivatives”. U.S. Patent #4,918,167.
W. G. Glasser, W. de Oliveira, S. S. Kelley, and L. S. Nieh (1992) “Method of producing prepolymers from hydroxyalkyl lignin derivatives”. U.S. Patent #5,102,992.
W. G. Glasser, O. H.-H. Hsu, D. L. Reed, R. C. Forte, and L. C.-F. Wu (1981) ACS Symp. Ser. No. 172, 311–338.
W. G. Glasser, L. C.-F. Wu, and J.-F. Selin (1985) in E. J. Soltes, (Ed.), Wood and Agricultural Residues: Research on Use for Feed, Fuels, and Chemicals, Academic Press, New York, 149–166.
S. S. Kelley, W. G. Glasser, and T. C. Ward (1989) ACS Symp. Ser. No. 397, 402–413.
W. Glasser, C. Barnett, T. Rials, and S. Kelley (1983) 1983 Int. Symp. Wood Pulping Chem. 3, 89–94.
L. C.-F. Wu and W. G. Glasser (1984) J. Appl. Polymer Sci. 29, 1111–1123.
W. G. Glasser, C. A. Barnett, T. G. Rials, and V. P. Saraf (1984) J. Appl. Polymer Sci. 29, 1815–1830.
S. S. Kelley, W. G. Glasser, and T. C. Ward (1988) J. Wood Chem. Technol. 8, 341–359.
W. G. Glasser, S. S. Kelley, T. G. Rials, and S. L. Ciemniecky (1986) Proc. 1986 TAPPI Res. Dev. Conf. 157–161.
W. G. Glasser (October 1989) in Modification of Lignin with Pro pylene Oxide, Progress Report on an Industry-University Cooperative Project, Blacksburg, VA.
W. G. Glasser, R. A. Northey, and T. P. Schultz (Eds) (1999) ACS Symp. Ser. No. 742, 559.
Nehez, N. J. “Lignin-based friction material,” (1997) Canadian Patent Application 2,242,554.
J. H. Lora, A. W. Creamer, L. Wu, and J. Ash (1994) Proc. Adh. Bonded Wood Symp. Forest Prod. Soc. Madison, Wisconsin, pp. 384–394.
W. C. Senyo, A. W. Creamer, L. Wu, and J. H. Lora (1989) ACS Symp. Ser. No. 397, 546.
P. C. Muller and W. G. Glasser (1984) J. Adh. 17, 157–173.
P. C. Muller, S. S. Kelley, and W. G. Glasser (1984) J. Adh. 17, 185–206.
W. G. Glasser, V. P. Saraf, and W. H. Newman (1982) J. Adh. 14, 233–255.
W. H. Newman and W. G. Glasser (1985) Holzforschung 39, 345–353.
C. Phanopoulos and J. J. Vanden Ecker (1996) “Process for binding lignocellulosic material,” WO 96/32444.
W. G. Glasser and R. H. Leitheiser (1984) Polymer Bull. 12, 1–5.
C. A. Barnett and W. G. Glasser (1989) ACS Symp. Ser. No. 397, 435–451.
W. L.-S. Nieh and W. G. Glasser (1989) ACS Symp. Ser. No. 397, 506–514.
K. Hofmann and W. G. Glasser (1993) J. Wood Chem. Technol. 13, 73–95.
K. Hofmann and W. G. Glasser (1993) J. Adh. 40, 229–241.
K. Hofmann and W. G. Glasser (1994) Macromol. Chem. Phys. 195, 65–80.
W. G. Glasser and R. K. Jain (November 1996) “The green card: Development of a lignin-based epoxy resin for use in printed circuit boards (PCB),” Final project report to IBM.
J. M. Shaw, S. L. Buchwalter, J. C. Hedrick, S. K. Kang, L. L. Kosbar, J. D. Gelorme, D. A. Lewis, S. Purushothaman, R. Saraf, and A. Viehbeck (1996) Printed Circuit Fabrication 19, 38–44.
L. L. Kosbar, J. D. Gelorme, R. M. Japp, and W. T. Fotorny (2001) J. Indust. Ecol. 4, 93–105.
J. Oberkofler (2001) “Sulphur-free lignin and derivatives thereof for reducing the formation of slime and deposits in industrial plants,” WO 01/68530 A2.
Lignopol Polymere Stoffe GmbH, Muehlacker, Germany.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Lora, J.H., Glasser, W.G. Recent Industrial Applications of Lignin: A Sustainable Alternative to Nonrenewable Materials. Journal of Polymers and the Environment 10, 39–48 (2002). https://doi.org/10.1023/A:1021070006895
Issue Date:
DOI: https://doi.org/10.1023/A:1021070006895