Abstract
The composition and chemical state of elements on the surface of solid oxygen-conducting electrolyte La0.88Sr0.12Ga0.82Mg0.18O3 – α is studied by x-ray photoelectron spectroscopy before and after annealing it at 973 K in a CO2 atmosphere. Products of interaction between doped lanthanum gallate and CO2 are localized in a surface layer 8–10 nm thick. The annealing does not lead to the formation of chemical carbon compounds with metals on the electrolyte surface. Surface layers of the electrolyte both in the initial state and after the annealing are rich in strontium oxide and contain some lanthanum hydroxide.
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Ishihara, T., Matsuda, H., and Takita, Y., J. Am. Ceram. Soc., 1994, vol. 116, p. 3801.
Feng, M. and Goodenough, J.B., J. Solid State Inorg. Chem., 1994, vol. 31, p. 663.
Ishihara, T., Minami, H., Matsuda, H., and Takita, Y., Proc. 4th Int. Symp. on Solid Oxide Fuel Cells 1995, p. 344.
Ishihara, T., Hiei, Y., and Takita, Y., Solid State Ionics, 1995, vol. 79, p. 371.
Akikusa, J., Adachi, K., Hoshino, K., Ishihara, T., and Takita, Y., J. Electrochem. Soc., 2001, vol. 148, p. A1275.
Shkerin, S.N., Bronin, D.I., Khlupin, Yu.S., Kalashnikova, N.A., and Beresnev, S.M., Abstracts of Papers, 6e soveshchanie “Fundamental'nye problemy ioniki tverdogo tela” (6th Meet. on Fundamental Problems of the Ionics of Solids), Chernogolovka (Russia), 2002, p. 93.
Gorelov, V., Bronin, D., Sokolova, Ju., Nafe, H., and Aldinger, F., J. Eur. Ceram. Soc., 2001, vol. 21, p. 2311.
Nefedov, V.I., Rentgenoelektronnaya spektroskopiya khimicheskikh soedinenii (X-ray Electron Spectroscopy of Chemical Compounds), Moscow: Khimiya, 1984.
Scofield, J.H., J. Electron Spectrosc. Relat. Phenom., 1976, vol. 8, p. 129.
Onishi, H., Egawa, C., Aruga, T., and Iwasawa, Y., Surf. Sci., 1987, vol. 191, p. 479.
Barr, T.L., J.Phys.Chem, 1978, vol. 82, p. 1801.
Uwamino, Y., Ishizuka, Y., and Yamatera, H., J. Electron Spectrosc. Relat. Phenom., 1984, vol. 34, p. 69.
Tatsumi, K., Tsutsui, M., Beall, G.W., Mullica, D.F., and Milligan, W.O., J. Electron Spectrosc. Relat. Phenom., 1979, vol. 16, p. 113.
Schoen, G., J. Electron Spectrosc. Relat. Phenom., 1973, vol. 2, p. 75.
Battistoni, C., Dormann, J.L., Fiorani, D., Paparazzo, E., and Viticoli, S., Solid State Commun., 1981, vol. 39, p. 581.
Vasquez, R.P., J. Electron Spectrosc. Relat. Phenom., 1991, vol. 56, p. 217.
Van Doveren, H. and Verhoven, J.A.Th., J. Electron Spectrosc. Relat. Phenom., 1980, vol. 21, p. 265.
Seyama, H. and Soma, M., J. Chem. Soc., Faraday Trans. I, 1984, vol. 80, p. 237.
Haycock, D.E., Kasrai, M., Nicholls, C.J., and Urch, D.S., J. Chem. Soc., Dalton Trans., 1978, p. 1791.
Franzen, H.F., J. Electron Spectrosc. Relat. Phenom., 1977, vol. 11, p. 439.
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Shkerin, S.N., Kuznetsov, M.V. & Kalashnikova, N.A. X-ray Photoelectron Spectroscopy of the Surface of Solid Electrolyte La0.88Sr0.12Ga0.82Mg0.18O3 – α . Russian Journal of Electrochemistry 39, 591–599 (2003). https://doi.org/10.1023/A:1024140924902
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DOI: https://doi.org/10.1023/A:1024140924902