Abstract
A new heterodinuclear cryptate [AgCuL](ClO4 −)2 was synthesized by transmetallation via its precursor [Ag2L](ClO4 −)2 (L = ligand). The electrospray mass spectrum (ES-MS) showed that the heterodinuclear entity exists in the solution. The X-Ray structure analysis shows that the AgI ion has tetrahedral geometry while CuI lies in a three-coordinate environment.
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Hu, XL., Luo, QH., Wang, ZL. et al. Synthesis, spectroscopy and crystal structure of a new heterodinuclear silver(I)—copper(I) cryptate. Transition Metal Chemistry 28, 640–643 (2003). https://doi.org/10.1023/A:1025428711201
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DOI: https://doi.org/10.1023/A:1025428711201