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Palladium(II, I, 0) Complexes in Catalytic Reactions of Oxidative Carbonylation

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Abstract

The mechanisms of carbonylation of alkenes, alkynes, and alcohols, including the mechanism of oxidative carbonylation of alkynes in the regime of self-oscillations catalyzed by Pd(II), Pd(I), or Pd(0) complexes, are analyzed. It is shown that the main reasons for the appearance of self-oscillations in the oxidation reactions are nonlinear and autocatalytic steps of generation and termination of active centers. The results of studying the functions of para-benzoquinone as an oxidant, ligand, and catalyst in the oxidative reactions are generalized. It is found that Pd(0) complexes with para-benzoquinone can catalyze oxidation reactions.

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    O. N. Temkin & L. G. Bruk

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Temkin, O.N., Bruk, L.G. Palladium(II, I, 0) Complexes in Catalytic Reactions of Oxidative Carbonylation. Kinetics and Catalysis 44, 601–617 (2003). https://doi.org/10.1023/A:1026161103700

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