Skip to main content
SpringerLink
Log in

Thermal and other properties of complexes of Mn(II), Co(II) and Ni(II) with 2,2'-bipyridine and trichloroacetates

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Complexes of the general formulae Mn(2-bpy)2(CCl3COO)2, Co(2-bpy)2(CCl3COO)2·H2O and Ni(2-bpy)2(CCl3COO)2·2H2O (where: 2-bpy=2,2'-bipyridine) have been prepared and characterized by VIS and IR spectroscopy, conductivity and magnetic measurements. The thermal properties of complexes in the solid state were studied under non-isothermal conditions in air atmosphere. During heating the complexes decompose via different intermediate products to the oxides Mn3O4, CoO and NiO. A coupled TG-MS system was used to detection the principal volatile products of thermal decomposition and fragmentation processes of obtained compounds. The principal volatile products of thermal decomposition of complexes are: H2O+, CO2 +, Cl2 + and other.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. Czakis-Sulikowska, A. Czylkowska and J. Radwañska-Doczekalska, J. Therm. Anal. Cal., 63 (2001) 387.

    Article  Google Scholar 

  2. D. Czakis-Sulikowska, A. Czylkowska and A. Malinowska, ibid. 65 (2001) 505; ibid. 67 (2002) 667.

    Article  Google Scholar 

  3. I. S. Ahuja, R. Singh and C. L. Yadava, J. Mol. Struct., 74 (1981) 43.

    Article  Google Scholar 

  4. T. Bartczak, D. Czakis-Sulikowska and J. KałuŶna, J. Therm. Anal. Cal., 46 (1998) 193.

    Google Scholar 

  5. D. Czakis-Sulikowska, A. Malinowska and M. Markiewicz, J. Therm. Anal. Cal., 60 (2000) 151.

    Article  Google Scholar 

  6. D. Czakis-Sulikowska and A. Czylkowska, ibid. in press.

  7. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley and Sons, New York 1997.

    Google Scholar 

  8. B. S. Manhas and A. K. Trikha, J. Indian Chem. Soc., LIX (1982) 315.

    Google Scholar 

  9. W. Brzyska and W. Ożga, J. Therm. Anal. Cal., 60 (2000) 123; ibid., 61 (2000) 135 and references therein.

    Article  Google Scholar 

  10. W. Brzyska, Z. Rzączyńska and A. Kula, Monatsh. Chem., 120 (1989) 211.

    Article  Google Scholar 

  11. M. Melnik, Coord. Chem. Rev., 36 (1981) 1 and references therein.

    Article  Google Scholar 

  12. A. B. P. Lever and D. Ogden, J. Chem. Soc., 17 (1967) 2041.

    Google Scholar 

  13. S. Sen, S. Mitra, P. Kundu, M. K. Saha, C. Krüger and J. Bruckmann, Polyhedron, 16 (1997) 2475.

    Article  Google Scholar 

  14. U. Tupeinen, R. Hämäläinen and Reedijk, ibid. 6 (1987) 1603.

    Article  Google Scholar 

  15. J. A. Moreland and R. J. Doedens, Inorg. Chem., 17 (1978) 674.

    Article  Google Scholar 

  16. R. Grobelny, T. Głowiak and J. Mroziński, XIVth Summar School on Coordination Chemistry, Polanica Zdrój, 6-12. VI. 1999.

    Google Scholar 

  17. S. G. Shova, L. G. Turyatke, G. V. Novitsky, M. D. Mazus and A. P. Gulya, Koord. Khim., 22 (1996) 517.

    Google Scholar 

  18. S. G. Shova, G. V. Novitsky, M. D. Mazus and A. P. Gulya, Dokl. Akad. Nauk. SSSR, 337 (1994) 348.

    Google Scholar 

  19. Pasder Diffraction File. International Center of Diffraction. JCTDS-JCDD. 1990.

  20. D. Czakis-Sulikowska, J. Kałużna, J. Therm. Anal. Cal., 58 (1999) 51.

    Article  Google Scholar 

  21. E. Konig, Magnetic Properties of Coordination and Organometallic Transition Metal Compounds, Springer, Berlin 1966.

    Google Scholar 

  22. W. I. Geary, Coord. Chem. Rev., 7 (1971) 81.

    Article  Google Scholar 

  23. N. M. Karayannis, A. N. Speca, D. E. Chasan and L. L. Pytlewski, ibid., 20 (1976) 37.

    Article  Google Scholar 

  24. Saiyid Aftab Ahmad Zaodi, Shahjahan and Khwaja Saluhuddin Siddiguin, Trans. Met. Chem., 18 (1993) 51.

    Article  Google Scholar 

  25. Indra Rani, K. B. Pandeya and R. P. Singh, J. Indian Chem. Soc., 59 (1982) 235.

    Google Scholar 

  26. A. B. P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1984.

    Google Scholar 

  27. J. S. Strukl and J. L. Walter, Spectrochim. Acta, 2717 (1971) 299; ibid., 27 (1971) 223.

    Google Scholar 

  28. W. R. Mc Whinnd and J. D. Miller, Advances in Inorg. Chem. Radiochem., 12 (1965) 137.

    Google Scholar 

  29. E. Spinner, J. Chem. Soc., (1964) 4217.

  30. L. E. Erdey and G. Liptay, Periodica Polytechnica (Budapest), 7 (1963) 223.

    Google Scholar 

  31. D. Czakis-Sulikowska and A. Czylkowska, Thermal decomposition of complexes of Co(II) with 4,4'-bipyridine and halogenoacetates in argon atmosphere, VIII-th Conference 'Prof. St. Bertsznajdera', Płock 2002, p. 267.

Download references

Author information

Authors and Affiliations

  1. Institute of General and Ecological Chemistry, Technical University Lódź, Poland

    D. Czakis-Sulikowska & A. Czylkowska

Authors
  1. D. Czakis-Sulikowska
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Czylkowska
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Czakis-Sulikowska, D., Czylkowska, A. Thermal and other properties of complexes of Mn(II), Co(II) and Ni(II) with 2,2'-bipyridine and trichloroacetates. Journal of Thermal Analysis and Calorimetry 74, 349–360 (2003). https://doi.org/10.1023/A:1026371029185

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1026371029185

Search

Navigation