Abstract
The electrochemical method involving solid electrolytes has been known as a selective and an accurate way of sensing chemical species in the environment and even in liquid metal for some time. The most successful among the electrochemical sensors are the emission control sensor (λ-sensor) for the automobile engine and the oxygen sensor used in steelmaking, both made of stabilized zirconia. This article presents an overview of basic principles of various types of electrochemical sensors including active (potentiometric) and passive (amperometric) sensors. Recent advances in oxygen (O2), carbon dioxide (CO2) and hydrogen (H2) sensors are also presented.
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References
C. Wagner Naturwissenschaften 31 (1943) 265.
G. Scatchard J. Amer. Chem. Soc. 75 (1953) 2883.
R. A. Rapp and D. A. Shores, “Techniques of Metal Research,” Vol IV, part 2 (Interscience Publisher, 1970) p. 123.
F. A. KrÖger J. Amer. Ceram. Soc. 49(4) (1966) 215.
J. W. Patterson J. Electrochem. Soc. 118 (1971) 1033.
H. NÄfe Soid State Ionics 113–115 (1998) 205.
C. Wagner, in Proc. Intern. Comm. Electrochem. Therm. Kinetics (CITCE), 7th Meeting Lindau (1955) (Butterworth Scientific Publ., London, 1957).
O. Tillement Solid State Ionics 68 (1994) 9.
C. Wagner Z. Phys. Chem. B 21 (1933) 25.
F. O. Koenig J. Phys. Chem. 44 (1940) 101.
C. Wagner, in “Advances in Electrochemistry and Electrochemical Engineering,” edited by Paul Delahay (Interscience Publishers, New York, 1966) Vol. 4, p. 1.
R. W. Ure J. Chem. Phys. 26 (1957) 1363.
J. Short and R. Roy J. Phys. Chem. 67 (1963) 1860.
R. Taylor and H. Schmalzried, ibid. 68 (1964) 2444.
E. Zintl and U. Croatto Z. Anorg. Allgem. Chem. 242 (1939) 79.
C. Tubant H. Reinhold and G. Liebold, ibid. 197 (1931) 225.
E. Barsis and A. Tayor J. Chem. Phys. 45 (1966) 1154.
L. W. Strock Z. Phys. Chem. B 25 (1934) 441; B 31 (1936) 132.
C. Wagner Z. Electrochem. 60 (1956) 4; 63 (1959) 1027.
D. RALEIGHJ. Phys. Chem. Solids. 26 (1965) 329.
R. A. Rapp, “Thermodynamics of Nuclear Materials” (IAEA, Vienna, 1968) p. 559.
C. B. Alcock, “Electromotive Force Measurements in High Temperature Systems” (Inst. of Mining and Metallurgy Publications, London, 1968).
J. W. Patterson E. C. Bogren and R. A. Rapp J. Electrochem. Soc. 114 (1967) 752.
K. O. Hever, ibid. 115 (1968) 830.
Y. Y. Yao and J. T. Kummer J. Inorg. Nucl. Chem. 29 (1967) 2453.
J. B. Goodenough H. Y. P. Hong and J. A. Kafalas Mater. Res. Bull. 11 (1976) 203.
C. Lee S. A. Akbar and C. O. Park Sensors and Actuators. B 80 (2001) 234.
H. Aono E. Sugimoto Y. Sadaoka N. Imanaka and G. Y. Adachi Solid State Ionics 40/41 (1990) 38.
T. Hibio K. Mizutani T. Yamajima and H. Iwahara, ibid. 57 (1992) 303.
D. A. Stevenson N. Jiang R. M Buchanan and F. E. G. Henn, ibid. 62 (1993) 279.
H. Iwahara T. Yamajima Hibino K. Ozaki and H. Suzuki, ibid. 61 (1993) 65.
W. L. Worrell and Q. G. Liu J. Electr. Chem. Interf. Electrochem. 168 (1984) 355.
G. Hotzel and W. Weppner, in Proc. 6th Riso-Intern. Sympo. On Transport-Structure Relations in Fast Ion and Mixed Conductor (Riso Natl. Lab., Roskilde, 1985) p. 401.
N. Miura S. Yao Y. Shimizu and N. Yamazoe Sensors and Actuators B 13/14 (1993) 387.
P. T. Mosely Meas. Sci. Technol. 8 (1997) 223.
F. H. Garzon R. Mukundan and E. L. Broska Solid State Ionics 136/137 (2000) 633.
T. H. Estell and S. N. Flengas J. Electrochem. Soc. 118(12) (1989) 1890.
C. N. Satterfield, “Mass Transfer in Heterogeneous Catalysis” (MIT Press, Cambridge, 1970) p. 30.
J. O. Hirschfielder C. F. Curtiss and R. B. Bird, “Molecular Theory of Gases and Liquids” (Wiley Publ., New York, 1967) p. 14.
H. Dietz Solid State Ionics 6 (1982) 175.
R. Jackson, “Transport in Porous Catalysts” (Elsevier, Amsterdam, 1977) p. 9.
T. Usui Y. Kurumiya K. Nuri and M. Nakazawa Sensors and Actuators 16 (1989) 345.
T. Usui A. Asada M. Nakazawa and H. Osanai J. Electrochem. Soc. 136(2) (1989) 534.
Z. Peng M. Liu ED. Balko Sensors and Actuators B 72 (2001) 35.
H. Schmalzried Z. Phys. Chem. (Frankfurt) 38 (1963) 87.
H. Schmalzried Z. Electrochem. 66 (1962) 572.
W. Weppner,“Solid State Ionics,” edited by M. Balkanski, T. Takahashi and H. L. Tuller (Elsevier Science Pub., 1992) p. 29.
A. Menne and W. Weppner, in Proc. Third Int. Meeting on Chemical Sensors (Cleveland Ohio, 1990) p. 225.
K. Nishio, “The Fundamentals of Automotive Engine Control Sensors” (Fontis Media, SA, 2001) p. 91.
F. Menil V. Coillard and C. Lucat Sensors and Actuators B 67 (2000) 1.
K. Saji H. Kondo T. Takeuchi and I. Igarashi J. Electrochem. Soc. 135(7) (1988) 1686.
J. E. Anderson and Y. B. Graves, ibid. 128(2) (1981) 294.
W. J. Fleming, ibid. 124(1) (1977) 21.
S. Oh Sensors and Actuators B 20 (1994) 33.
H. Tanaka S. Nishimura S. Suzuki M. Miki T. Harada M. Kanamaru S. Ueno and N. Ichikawa, SAE No. 890299 (1989).
B. K. Kim J. H. Lee and H. Kim Solid State Ionics 86–88 (1996) 1079.
W. C. Vassell E. M. Logothesis and R. E. Hetrick, SAE Paper No. 841250 (1984).
S. Soejima and S. Mase, SAE Paper No. 850378 (1985).
T. Sasayama T. Yamauchi R. Byers S. Suzuki and S. Ueno, SAE Paper No. 910501 (1991).
A. D. Colvin J. S. Rankin and K. R. Carduner Sensors and Actuators B 12 (1993) 83.
M. Gauthier and A. Chamberland J. Electrochem. Soc. 124 (1977) 1579.
R. Cote and C. W. Bale, ibid. 131 (1984) 63.
K. Singh P. Ambekar and S. S. Bhoga Solid State Ionics 122 (1999) 191.
J. Liu and W. Weppner, in “Solid State Ionics,” edited by M. Balkanski, T. Takahashi and H. L. Tuller (Elsevier Science Publishers B. V., 1992) p. 61.
M. Holzinger J. Maier and W. Sitte Solid State Ionics 86–88 (1996) 1055.
T. Maruyama S. Sasaki and Y. Saito, ibid. 23 (1987) 107.
T. Lang H.-D. Wiemhofer and W. GÖpel Sensors and Actuators B 34 (1996) 383.
M. A-Porta and R. V. Kumar ibid. 71 (2000) 173.
N. Miura S. Yao Y. Shimizu and N. Yamazoe ibid. 9 (1992) 165.
C. O. Park C. Lee S. A. Akbar and J. Hwang ibid. 88 (2003) 53.
G. Adachi and N. Imanaka in Proc. Symp'on Chemical Sensors II, edited by M. Butler, N. Yamazoe and A. Ricco, J. Electrochem. Soc., Vol. 93, p. 182.
R. Stevens and J. G. P. Binner J. Mater. Sci. 19 (1984) 695.
G. M. Kale and K. T. Jacob J. Mater. Res. 4(2) (1989) 417.
N. Miura S. Yao Y. Shimizu and N. Yamazoe Sensors and Actuators B 9 (1992) 165.
N. Kurita J. Electrochem. Soc. 142(5) (1995) 1552.
T. Norby Solid State Ionics 125 (1999) 1.
H. Iwahara T. Yajima T. Hibino K. Ozaki and H. Suzuki, ibid. 61 (1993) 65.
R. Slade S. D. Flint and N. Singh, ibid. 82 (1995) 135.
T. Takahashi and H. Iwahara Rev. Chim. Miner. 17 (1980) 243.
N. Fukatsu J. Alloys Comp. 231 (1995) 706.
K. D. Kreuer Solid State Ionics 97 (1997) 1.
C. E. Ransley and H. Neufeld J. Inst. Metals 74 (1948) 599.
R. Gee and D. J. Fray Metall. Trans. B 9 (1978) 427.
Y. Zhang and R. A. Rapp, The Ohio State University, Personal Communications.