Skip to main content
SpringerLink
Log in

A Highly Efficient Catalyst Au/MCM-41 for Selective Oxidation Cyclohexane Using Oxygen

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

The liquid-phase highly efficient selective oxidation cyclohexane to cyclohexanol and cyclohexanone over Au/MCM-41 catalyst was carried out in a solvent-free system, which oxygen as the only oxidant and the reaction conditions are very moderate. The Au/MCM-41 was characterized by XRD, N2adsorption/desorption, UV-Vis, XPS, and ICP-AES.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. M. Thomas and R. Raja,Chem. Commun. (2001)675.

  2. W. L. Faith, D. B. Keyes and R. L. Clark,Industrial Chemicals, 2nd ed. (Wiley, New York,1957).

    Google Scholar 

  3. V. Berezin, E. T. Denisov and N. M. Emanue,Oxidation of Cyclohexane (Pergamon, New York,1968).

    Google Scholar 

  4. S. B. Chandalia,Oxidation of Hydrocarbons,1st ed. (Sevak, Bombay,1977).

  5. M. T. Musser,in:Encyclocarbons of Industrial Chemistry,W. Gerhartz (ed. )(VCH, Weinheim,1987)p. 217.

    Google Scholar 

  6. R. L. Marcell,US Patent 3,317,614,(1967);J. L. Russel,US Patent 3,665,028 (1972).

  7. U. Schuchardt, D. Caroso,R. Sercheli, R. Perira, R. S. Cruz, M. C. Guerreiro, D. Mandelli, E. V. Spimace and E. L. Pires,Appl. Catal. 211 (2001)1.

    Article  Google Scholar 

  8. U. Schuchardt, W. A. Carvalho and E. V. Spinace,Syn. Lett. 10 (1993)713.

    Google Scholar 

  9. N. Mizuno, C. Nozaki, I. Kiyoto and M. Misono,J. Am. Chem. Soc. 120 (1998)9267.

    Article  Google Scholar 

  10. S. Goldstein, R. H. Beer and R. S. Drago,J. Am. Chem. Soc. 116 (1994)2424.

    Google Scholar 

  11. A. Onopchenko and J. D. D. Schulz,J. Org. Chem. 40 (1975)3338.

    Google Scholar 

  12. J. F. Black,J. Am. Chem. Soc,100 (1978)527.

    Google Scholar 

  13. N. M. Emanuel, Z. K. Maizus and I. P. Skibida,Angew. Chem. Int. Edit. 8 (1969)2.

    Google Scholar 

  14. E. P. Talsi, V. D. Chinakov, V. P. Sidelnikov and K. I. Zamaraev, J. Mol. Catal. 81 (1993)215.

    Article  Google Scholar 

  15. R. A. Scheldon and J. K. Kochi,Metal-Catalyzed Oxidations of Organic Compound (Academic Press, New York,1981).

    Google Scholar 

  16. G. Cainelli and G. Gardillon,Chromium Oxidations in Organic Chemistry (Springer-Verlag, New York,1984).

    Google Scholar 

  17. S. I. Murahashi and T. J. Naota,J. Am. Chem. Soc,114 (1999) 7913.

    Google Scholar 

  18. T. Tatsumi, M. Nakamura and H. Tominaga,J. Chem. Soc. Chem. Chem. Commun. (1990)476.

  19. J. S. Reddy and S. Sivasanker,Catal. Lett. 11 (1991)241.

    Google Scholar 

  20. P. Concepcion, A. Corma, J. M. L. Nieto and J. Perz-Pariente, Appl. Catal. 143 (1996) 17.

    Article  Google Scholar 

  21. F. J. Luna, S. E. Ukawa, M. Wallau and U. Schuchardt,J. Mol. Catal. 117 (1997)405.

    Article  Google Scholar 

  22. W. A. Carvalho, P. B. Varaldo, M. Wallau and U. Schuchardt, Zeolites 18 (1997)408.

    Article  Google Scholar 

  23. I. Belkhir, A. Germain, F. Fajula and E. Fache,J. Chem. Soc. Faraday Trans. 94 (1998)1761.

    Article  Google Scholar 

  24. N. Perkas, Y. Kottypin, O. Palchik, A. Gednken and S. Chandrasekaran,Appl. Catal. 209 (2001)125.

    Article  Google Scholar 

  25. E. L. Pires, J. C. Magalhaes and U. Schuchardt,Appl. Catal. 203 (2000)231.

    Article  Google Scholar 

  26. R. S. Da Cruz, J. M. deSouza e Ailva and U. Schuchardt,J. Mol. Catal. 171 (2001)251.

    Article  Google Scholar 

  27. I. W. C. E. Arends, R. A. Sheldon, M. Wallau and U. Schuchardt, Angew. Chem. Int. Edit. Engl. 36 (1997)1144.

    Article  Google Scholar 

  28. R. A. Sheldon and J. K. Kochi,Metal-catalyzed Oxidation of Organic Compounds (Academic Press, New York,1981).

    Google Scholar 

  29. A. E. Shilov and G. B. Shul 'pin,Chem. Rev. 97 (1997)2879.

    Article  PubMed  Google Scholar 

  30. (a)E. V. Spinacé, H. O. Pastore and U. Schuchardt, J. Catal. 157 (1995) 631;(b)M. H. Zahedi-Niaki,M. P. Kapoor and S. Kaliaguine,J. Catal. 177 (1998)2319.

  31. W. A. Carvalho, P. B. Varaldo, M. Wallau and U. Schuchardt, Zeolites 18 (1997) 408.

    Article  Google Scholar 

  32. (a)R. Raja, G. Sankar and J. M. Thomas, J. Am. Chem. Soc. 121 (1999) 11926;(b)R. P. Unnikrishnan and S. -D. Endalkachew, Chem. Commu. (2002)2142.

  33. R. A. Sheldon, I. W. C. E. Arends,and H. E. B. lempers Collect. Czech. Chem. Commun. 63 (1998) 1742.

    Google Scholar 

  34. N. Mizumo, C. Nozaki, I. Kiyoto and M. Misono, J. Am. Chem. Soc. 120 (1998) 9267.

    Article  Google Scholar 

  35. E. L. Pires, J. C. Magalhaes and U. Schuchardt,Appl. Catal. A: Gen. 203 (2000)231.

    Article  Google Scholar 

  36. M. Haruta, Catal. Surv. Jpn. 1 (1997) 61.

    Article  Google Scholar 

  37. M. Haruta, Catal. Today 36 (1997) 115.

    Article  Google Scholar 

  38. D. Andreeva, V. Idakiev, T. Tabakova and A. Andreev, J. Catal. 158 (1996) 354.

    Article  Google Scholar 

  39. D. Andreeva, V. Idakiev, T. Tabakova, A. Andreev and R. Giovanoli,Appl. Catal. A:Gen. 34 (1996)275.

    Article  Google Scholar 

  40. D. Andreeva, V. Idakiev, T. Tabakova and R. Giovanoli,Bulg. Chem. Commun. 30 (1998)64.

    Google Scholar 

  41. S. Link and M. A. El-Soyed,J. Phys. Chem. B 103 (1999)4212.

    Article  Google Scholar 

  42. P. Mulvaey, Langmuir 12 (1996) 788.

    Article  Google Scholar 

  43. S. Deki, Y. Aoi, H. Yanagimoto, K. Ishii, K. Akamatsu, M. Mizuhata and A. Kajinami, J. Mater. Chem. Chem. 6 (1996) 1879.

    Article  Google Scholar 

  44. F. Bocuzzi, G. Cerrato, F. Pinna and G. Strukui, J. Phys. Chem. B 102 (1998) 5733.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Lanzhou Institute of Chemical physics, National Engineering Research Center for Fine Petrochemical Intermediates, Lanzhou, 730000, China

    Gaomeng Lü, Rui Zhao, Guang Qian, Yanxing Qi, Xiaolai Wang & Jishuan Suo

Authors
  1. Gaomeng Lü
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Rui Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Guang Qian
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yanxing Qi
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Xiaolai Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Jishuan Suo
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lü, G., Zhao, R., Qian, G. et al. A Highly Efficient Catalyst Au/MCM-41 for Selective Oxidation Cyclohexane Using Oxygen. Catalysis Letters 97, 115–118 (2004). https://doi.org/10.1023/B:CATL.0000038571.97121.b7

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:CATL.0000038571.97121.b7

Search

Navigation